美国FDA农残分析手册（第一巻英文）：appndx1

Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–1 APPENDIX I: PESTDATA Caution: Use this table only as a quick reference for tentative identification of residues found in samples analyzed by the most com- monly used PAM I multiresidue methods. Always compare the residue to a standard chromatographed in your own gas chromatograph. Apply appropriate confirmatory tests to verify tentative identification. Note that PESTDATA cannot and does not contain all details; consult PAM I tables that accompany each method for more definitive information about the behavior of the compound through the steps of the methods. NOTATIONS AND ABBREVIATIONS USED IN PESTDATA (In all categories a hyphen indicates absence of data) Name Preferred name for each chemical. “*” indicates chemicals with multiple GLC peaks. Chlordane, Strobane, toxaphene and all Aroclors are listed only in the table ordered by name and do not appear in the tables ordered by relative retention times. Molecular Formula Numbers are not subscripted. Averages are used for multicomponent chemicals. RRT/c Columns list retention times (relative to chlorpyrifos) on GLC column indicated. Conditions under which these data were gathered are described in these Section 302 DG modules: GLC Column Section 302 DG modules OV-101 DG1-DG5 OV-17 DG13-DG17 OV-225 DG18, DG19 Note that headers in these tables refer to GLC columns by the names used for packed columns, despite DG1-DG19’s descriptions of wide bore capillary column systems, because so many of these rrts were developed using packed columns. Rrt data for equivalent packed and capillary columns are expected to be essentially identical and are combined in PESTDATA. Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–2 Responses Data specify column and detector used. Numbers refer to weight (ng) that causes detector response of approximately 50% full scale deflection (FSD) on the recording device. Response values collected when the detector was combined with a wide bore capillary column include the notation “(WB).” Codes refer to detectors and operating conditions described in these Section 302 DG modules, except that all response values are based on detector sensitivity of 50% FSD to 1.5 ng chlorpyrifos: Code Detector Section 302 DG modules TR tritium electron capture none - obsolete detector TI thermionic (KCl) none - obsolete detector FP flame photometric, phosphorus DG2, DG14, DG19 FS flame photometric, sulfur DG15 NI 63 Ni electron capture DG1, DG13, DG18 NP nitrogen/phosphorus DG5, DG17 HX electroconductivity (halogen mode) DG3, DG16 HN electroconductivity (nitrogen mode) DG4 MC microcoulometric none - obsolete detector NOTES: Response values are approximate and can vary dramatically on different chromatographs. Most response values represent rounded-off or averaged values; some were collected under conditions different from those suggested in references. Recoveries Data on the recovery of the compound through several PAM I methods are listed in columns with the following headings. See the appropriate PAM I table(s) for more details, such as partial recoveries through Florisil. Heading Common Name PAM I Section PAM I Table 302 Luke (Los Angeles) 302 E1-E3, no cleanup 302-a 303 Mills, Onley, Gaither 303 E1-E5 + C1 or C2 303-a 304 Mills fatty food 304 E1-E5 + C1-C4 304-a Ethers Florisil elution system 303 C1, 304 C1 and C3 303-a, 304-a CH 2 Cl 2 alternative Florisil elution 303 C2, 304 C2 and C4 303-a, 304-a Recovery codes have the following meanings: C: complete (>80%); P: partial (50-80%); S: small (<50%); V: variable; R: recovered but no quantitative information available; NR: not recovered. Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–3 Appendix I: PESTDATA Chemicals in Order by Chemical Name Recoveries * Multipeak chemical. # Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a. 1,1'-(2,2-dichloroethylidene)bis(2- C16H16Cl2O2 2.9 - 3.7 - R - - - methoxybenzene) Responses: 1,2,3,4-tetrachlorobenzene C6H2Cl4 - - 0.09 - - - - - Responses: OV-17: NI0.2 1,2,3,5-tetrachlorobenzene C6H2Cl4 - - 0.07 - P # - 6 1 Responses: OV-17: NI0.1 1,2,3-trichlorobenzene C6H3Cl3 0.08 - - - C P 6 1 Responses: OV-101: TR2 1,2,4,5-tetrachloro-3-(methylthio)= C7H4Cl4S 0.49 0.35 0.48 R C - 6 1 benzene Responses: OV-101: NI0.3 OV-17: HX(WB)0.3 OV-225: NI0.3 1,2,4,5-tetrachlorobenzene C6H2Cl4 - - 0.07 - - - - - Responses: OV-17: NI0.2 1,2,4-triazole C2H3N3 0.2 - 0.27 V NR NR 6-15-50 1-2-3 Responses: DEGS: NP3 1-hydroxychlordene C10H6Cl6O 0.99 1.63 1.07 - R - 15 - Responses: OV-101: NI(WB)7 OV-17: NI1 OV-225: NI1 1-methyl cyromazine C7H13N6 - - 0.72 - - - - - Responses: OV-17: NP1000 10,10-dihydromirex C10H2Cl10 2.67 - - - C - 6 - Responses: OV-101: NI7 10-monohydromirex C10HCl11 4.26 - - - C - 6 - Responses: OV-101: NI7 2,3,5,6-tetrachloroanisidine C7H5Cl4NO 0.59 0.73 0.66 - C - 6 2 Responses: OV-101: NI0.5 OV-17: HX(WB)0.6 OV-225: NI0.5 2,3,5,6-tetrachloroanisole C7H4Cl4O 0.24 0.15 0.22 - C - 6 1 Responses: OV-101: NI0.2 OV-17: HX(WB)0.3 OV-225: NI0.2 2,3,5,6-tetrachloronitroanisole C7H3Cl4NO3 0.56 0.63 0.56 - C - 6 1+2 Responses: OV-101: NI0.4 OV-17: HX(WB)0.5 OV-225: NI0.4 2,3,5,6-tetrafluoro-4-hydroxymethyl= C8H4OF4 - - - - - - - - benzoic acid Responses: Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–4 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 2,3,5-trimethacarb C11H15NO2 0.35 0.6 0.38 C S # NR 50 1-2-3 Responses: OV-101: NP8 OV-17: NP4 OV-225: NP10 2,3-dihydro-3,3-methyl-2-oxo-5- C11H12O5S 0.68 2.89 0.93 - - - - - benzofuranyl methyl sulfonate Responses: OV-101: FS25/NI4 OV-17: FS54/NI4.5 OV-225: FS63/NI10 2,4,5-T BEP ester* C17H23Cl3O3 0.16 0.14 - - - - - - 0.68 0.66 - 1.08 0.91 - 2.85 1.19 - 3.3 2.78 - 5.3 3.28 - 7 7.7 - Responses: OV-101: TR35 2,4,5-T butoxyethyl ester* C14H17Cl3O4 - 2.66 - - - - - - 2.91 3.3 - Responses: OV-101: TR4 2,4,5-T butyl esters* C12H13Cl3O3 - - 1.05 - - - - - - - 0.86 Responses: 2,4,5-T ethylhexyl ester C16H21Cl3O3 3.38 - 2.62 - - - - - Responses: OV-101: NI5 2,4,5-T isobutyl ester C12H13Cl3O3 0.94 - - - - - - - Responses: OV-101: TR1 2,4,5-T isooctyl ester* C16H21Cl3O3 - 2.69 - - - - - - 2.56 3.1 - 2.96 3.4 - 3.25 3.8 - Responses: OV-101: TR20 2,4,5-T isopropyl ester C11H11Cl3O3 0.67 0.65 - - - - - - Responses: OV-101: TR2 2,4,5-T methyl ester C9H7Cl3O3 0.49 0.63 0.47 - - - - - Responses: OV-101: TR1 2,4,5-T n-butyl ester C12H13Cl3O3 1.1 - - - - - - - Responses: OV-101: TR1 2,4,5-T propylene glycol butyl C15H19Cl3O4 2.37 - - - - - - - ether esters Responses: Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–5 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 2,4,5-trichloro-alpha-methylbenzene= C8H7OCl3 0.34 - 0.25 R R - 15 - methanol Responses: 2,4-D BEP ester* C17H24Cl2O4 - 0.08 - - - - - - 0.69 0.74 - 1.66 1.18 - 2 1.79 - 3.22 2.09 - 4.1 5.1 - 10.2 13 - Responses: OV-101: TR60 2,4-D butoxyethyl ester* C14H18Cl2O4 - 1.67 1.44 - - - - - 1.82 2.08 1.79 Responses: OV-101: TR12 OV-17: NI5 2,4-D ethyl hexyl ester* C16H22Cl2O3 - 1.51 - - - - - - 2.1 1.78 1.68 Responses: OV-101: NI5 2,4-D isobutyl ester C12H14Cl2O3 0.62 0.62 0.49 - - - - - Responses: OV-101: TR5 2,4-D isooctyl ester* C16H22Cl2O3 - - 1.48 - - - - - 2.04 1.78 1.78 Responses: OV-101: TR50 OV-17: NI5 2,4-D isopropyl ester* C11H12Cl2O3 - 0.62 - - - - - - 0.42 0.74 0.33 Responses: OV-101: TR10 2,4-D methyl ester C9H8Cl2O3 0.3 0.38 0.25 - - - - - Responses: OV-101: TR6 2,4-D n-butyl ester C12H14Cl2O3 0.72 - - - - - - - Responses: OV-101: TR40 2,4-D propylene glycol butyl ether C15H2OCl2O4 - 1.42 - - - - - - ester* 1.54 3.6 - Responses: OV-101: TR20 2,4-DB methyl ester C11H12Cl2O3 0.62 0.72 - - - - - - Responses: OV-101: TR28 2,4-dichloro-6-nitrobenzenamine C6H4Cl2N2O2 0.3 - - - R - 15 2 Responses: OV-101: HX2/NI0.4/NP8 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–6 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 2,6-dichlorobenzamide C7H5NOCl2 0.39 1.3 0.52 C NR NR 6-15-50 1-2-3 Responses: 2,8-dihydromirex C10H2Cl10 2.41 - - - C - 6 - Responses: OV-101: NI4 2-chloroethyl caprate C8H15ClO2 0.32 - - - C C 15 2 Responses: OV-101: HX2 2-chloroethyl laurate C14H27ClO2 0.59 - - - C C 15 2 Responses: OV-101: HX2 2-chloroethyl linoleate C20H35ClO2 4.1 - - - V P 15 2 Responses: OV-101: HX15 2-chloroethyl myristate C16H31ClO2 1.17 - - C V V 15 2 Responses: OV-101: HX4 2-chloroethyl palmitate C18H35ClO2 2.35 - - - V P 15 2 Responses: OV-101: HX10 2-hydroxy-2,3-dihydro-3,3-methyl-5- C11H14O5S 1 6.6 1.46 - - - - - benzofuranyl methyl sulfonate Responses: OV-101: FS48/NI135 OV-17: FS88/NI96 OV-225: FS175/NI400 2-methoxy-3,5,6-trichloropyridine C6H4Cl3NO 0.19 0.08 0.1 C P # C 6+15 1+2 Responses: OV-101: NI0.5/NI(WB)0.4/NP(WB)9 OV-17: HX1.5 3, 5, 6-trichloro-2-pyridinol methyl C6H4Cl3NO 0.32 0.44 0.36 - - - - - ester Responses: OV-101: NI(WB)0.6/NP(WB)5 3,4,5-trimethacarb C11H15NO2 0.45 0.78 0.5 C NR NR 50 1-2-3 Responses: OV-101: NP25 OV-17: NP10 OV-225: NP200 3,4-dichloroaniline C6H5Cl2N 0.2 0.32 0.16 V S - 15 - Responses: OV-101: HX0.6/NI16/NP1 OV-17: NI13/NP8 OV-225: NI30 3,4-dichlorophenylurea C7H6Cl2N2O 0.22 0.14 0.1 - NR NR 6-15-50 - Responses: OV-101: HX9/NI18/NP60 OV-17: NI4 OV-225: NI6 3,5-dichloroaniline C6H5Cl2N 0.18 0.27 0.14 S S S 6+15 1+2 Responses: OV-101: HN(WB)1/HX0.5/NI9/NI(WB)16/NP0.9/NP(WB)1 OV-17: HN(WB)0.3/HX(WB)2/NI8/NI(WB)14/NP8/ NP(WB)0.4 OV-225: NI20/NI(WB)25 3-(3,4-dichlorophenyl)-1- C8H8Cl2N2O2 0.21 - 1.36 R NR NR 6-15-50 - methoxyurea Responses: OV-101: HX9/NI25 OV-17: NP250 3-aminophenol C6H7NO - - - - - - - - Responses: Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–7 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 3-carboxy-5-ethoxy-1,2,4-thiadiazole C3H2N2O3S 0.22 0.25 0.2 NR - - - - Responses: OV-101: NI170/NP40 OV-17: NI160/NP30 OV-225: NI100 DEGS: NI200/NP40 3-chloro-5-methyl-4-nitro-1H- C4H4ClN3O2 1.07 - - C - - - - pyrazole Responses: 3-desmethyl sulfentrazone C10H8Cl2F2N4O3S 3.3 - 7.5 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)0.1/NP(WB)37 OV-17: FS(WB)1500/NI(WB)0.1/NP(WB)73 3-hydroxycarbofuran C12H15NO4 - - - - - - - - Responses: 3-hydroxymethyl-2,5-dimethylphenyl C11H15NO3 0.8 - 1.03 - NR NR 6-15-50 1-2-3 methylcarbamate Responses: OV-101: NP200 OV-17: NP600 3-ketocarbofuran C12H12NO4 0.55 1.41 0.9 S NR NR 6 1 Responses: OV-101: HN(WB)17/NI(WB)15/NP(WB)9 OV-17: HN(WB)15/NI(WB)80/NP(WB)30 OV-225: NI(WB)80 3-methyl-4-nitrophenol C7H7O3N 0.38 0.63 0.26 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI13/NP50 OV-17: NI5/NP20 OV-225: NI250 3-methyl-4-nitrophenol methyl ether C8H9O3N 0.17 0.22 0.13 - - - - - Responses: OV-101: NI3/NP7 OV-17: NI1/NP2 OV-225: NI2 3-phenoxybenzenemethanol C13H12O2 1.28 - 1.6 - - - - - Responses: OV-101: NI1000 OV-17: NI1000 3-tert-butyl-5-chloro-6-hydroxy= C9H13ClN2O3 1.35 2.27 2.55 - NR NR 6-15-50 1-2-3 methyluracil Responses: OV-101: HN(WB)4/HX(WB)40/NI(WB)67/NP(WB)39 OV-17: HN(WB)13/HX(WB)99/NI(WB)35/NP(WB)290 OV-225: NI(WB)630 4,4'-dichlorobiphenyl C12H8Cl2 - - 0.51 - - - - - Responses: 4-(2,4-dichlorophenoxy)= C12H9Cl2NO 1.44 - - - - - - - benzenamine Responses: OV-101: TR60 4-(dichloroacetyl)-1-oxa-4-azapiro= C10H15Cl2NO2 0.5 0.69 0.48 C P - 50 3 [4.5]decane Responses: OV-101: NI1.4/NP34 OV-17: NI1.1/NP1.2 OV-225: NI1.6 4-chloro-6-methoxyindole C9H8NOCl 0.54 - 0.66 - R - 15 - Responses: OV-101: HX2.5/NI1000 OV-17: HX0 4-chlorobenzeneamine C6H6ClN - - 0.07 S NR NR 6-15-50 1-2-3 Responses:OV-17:NP(WB)1.5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–8 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries 4-chlorobenzylmethyl sulfone C8H9ClO2S 0.41 1.91 0.66 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)0.4 OV-17: NI(WB)0.8 OV-225: NI(WB)2 4-chlorobenzylmethyl sulfoxide C8H9ClOS 0.39 1.16 0.54 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)20 OV-17: NI(WB)16 OV-225: NI(WB)55 4-chlorobiphenyl C12H9Cl - - 0.2 - - - - - Responses: 4-chlorophenoxyaniline* C12H10ClNO 0.87 - 1.07 S - - - - 1.28 - 1.31 Responses: OV-101: HX7/NI1100 4-chlorophenylurea C7H7ClN2O 0.54 - 1.07 NR NR NR 6-15-50 1-2-3 Responses:OV-101:NI(WB)15 OV-17:NI(WB)40 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 0.18 - 0.22 - NR NR 15-50 1-2-3 methylcarbamate* 0.27 - 0.31 Responses: OV-101: NI200 OV-17: NI150 6-chloro-2,3-dihydro-3,3,7-methyl- C9H13ClN2O2 0.43 1.34 0.6 - NR NR 6-15-50 1-2-3 5H-oxazolo(3,2-a)pyrimidin-5-one Responses: OV-101: HN(WB)0.4/NI(WB)26/NP(WB)3 OV-17: HN(WB)0.4/HX(WB)4/NI(WB)36/NP(WB)2 OV-225: NI(WB)51 6-chloro-2,3-dihydro-7-hydroxy= C9H13ClN2O3 0.86 - 1.55 - NR NR 6-15-50 1-2-3 methyl-3,3-methyl-5H-oxazolo= Responses: OV-101: HN(WB)4/HX(WB)11/NI(WB)28/NP(WB)17 OV-17: HN(WB)3/HX(WB)17/NI(WB)19/NP(WB)12 (3,2-a)pyrimidin-5-one 6-chloronicotinic acid* C6H4NO2Cl - - - - NR NR 6-15-50 1-2-3 -- Responses: DEGS: HX40/NI11/NP66 8-monohydromirex C10HCl11 3.74 - - - C - 6 - Responses: OV-101: NI5 acephate C4H10NO3PS 0.15 0.64 0.19 C - - - - Responses: OV-101: FP(WB)0.9/NP3 OV-17: FP(WB)0.6 OV-225: FP5 acetochlor C14H20NO2Cl 0.75 0.88 0.67 C C # P 50 3 Responses: OV-101: HX5/NI9/NP5 OV-17: NI5 OV-225: NI5 acifluorfen C14H7ClF3NO3 1.05 1.47 0.88 - NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)170/HX(WB)980/NI(WB)40/NP(WB)270 OV-17: HN(WB)48/HX(WB)390/NI(WB)27/NP(WB)1000 OV-225: NI(WB)300 acrinathrin C26H21F6NO5 10.4 12.8 8.9 V V V # 15 2 Responses: OV-101: NI15/NP125 OV-17: NI25/NP100 OV-225: NI40 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–9 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries alachlor C14H2OClNO2 0.8 1 0.72 C C C # 50 3 Responses: OV-101: NI(WB)7 OV-17: NI6 OV-225: NI6 aldrin C12H8Cl6 1.05 0.58 0.76 C C C 6 1 Responses: OV-101: TR0.8 OV-17: NI1 allethrin C19H26O3 1.36 1.22 - - C C # 50 3 Responses: OV-101: NI8 allidochlor C8H12ClNO 0.09 - - C NR - 6-15 1-2-3 Responses: OV-101: TR5 alpha-cypermethrin C22H19Cl2O3N 14 - - C C - - 2 Responses: OV-101: HX9/NI22 ametryn C9H17N5S 0.77 1.1 - C - - - - Responses: aminocarb C11H16N2O2 0.56 - - C - - - - Responses: OV-101: NP10 amitraz C19H23N3 - - - S - - - - Responses: anilazine C9H5Cl3N4 1.24 1.88 1.47 V S P 15+50 2+3 Responses: OV-101: HX(WB)8/NI4 OV-17: NP20 aramite* C15H23ClO4S 2 2.77 - C P NR 15 - 2.14 3.05 - Responses: OV-101: FP600/TR10000 Aroclor 1016* CHCl (mix) 0.2 0.24 - - C C 6 1 0.3 0.3 - 0.39 0.4 - 0.44 0.46 - 0.52 0.51 - 0.59 0.54 - 0.68 0.61 - 0.73 0.68 - 0.87 0.85 - 1 0.9 - 1.07 0.98 - 1.3 1.09 - Responses: Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–10 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Aroclor 1221* C12H8.8Cl1.2 0.21 - - - C C 6 1 0.27 - - 0.32 - - 0.37 - - 0.4 - - 0.53 - - 0.6 0.15 - 0.65 0.21 - 0.7 0.24 - 0.77 0.3 - 0.9 0.4 - 1.01 0.43 - 1.3 0.46 - 1.45 0.5 - 1.55 0.54 - 1.8 0.61 - 1.9 0.68 - 2.12 0.92 - 2.26 1.04 - 2.7 1.16 - 3.16 1.24 - Responses: OV-101: TR40 Aroclor 1242* C12H7Cl3 0.4 0.24 - - C C 6 1 0.52 0.3 - 0.58 0.4 - 0.68 0.46 - 0.73 0.54 - 0.88 0.61 - 0.98 0.68 - 1.05 0.85 - 1.24 0.9 - 1.42 0.98 - 1.52 1.1 - 1.77 1.36 - 1.87 1.59 - 2.24 1.75 - 2.61 2.01 - Responses: OV-101: TR50 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–11 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Aroclor 1248* C12H6.1Cl3.9 0.52 0.4 - - C C 6 1 0.58 0.47 - 0.68 0.54 - 0.82 0.61 - 0.87 0.68 - 0.98 0.85 - 1.05 0.9 - 1.25 0.98 - 1.42 1.1 - 1.52 1.18 - 1.77 1.37 - 1.88 1.6 - 2.24 1.75 - 2.59 2.01 - 3.1 2.72 - Responses: OV-101: TR50 Aroclor 1254* C12H5Cl5 - - 0.35 - C C 6 1 0.89 0.68 0.48 1 0.85 0.63 1.07 0.9 0.81 1.3 0.99 0.97 1.55 1.1 1.3 1.82 1.17 1.43 1.92 1.39 1.84 2.24 1.48 1.98 2.68 1.6 2.26 3.14 1.75 2.55 3.7 2.03 2.91 4.2 2.46 3.3 4.4 2.79 4.3 5 3.8 4.8 5.9 4.3 5.2 Responses: OV-101: TR30 Aroclor 1260* C12H3.7Cl6.3 - 1.09 - - C C 6 1 1.31 1.17 - 1.53 1.61 - 1.9 1.81 - 2.11 2.06 - 2.25 2.18 - 2.68 2.45 - 2.9 2.76 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–12 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Aroclor 1260* (cont’d) 3.2 3.12 - 3.6 3.48 - 4.2 3.7 - 5 4.3 - 5.9 5.2 - 6.6 5.8 - 8 7.2 - 9.3 8.8 - Responses: OV-101: TR20 Aroclor 1262* C12H3.3Cl6.7 1.29 - - - C C 6 1 1.53 - - 1.89 - - 2.11 - - 2.26 - - 2.66 - - 2.88 - - 3.12 - - 3.6 - - 4.2 - - 5- 5.9 - - 6.5 - - 6.7 - - 8- 9.3 - - Responses: OV-101: TR20 Aroclor 1268* C12H1Cl9 3.8 - - - C - 6 - 4.7 - - 5.4 - - 7.3 - - 8.7 - - 10 - - 13 - - 16.2 - - Responses: OV-101: NI40 Aroclor 4465* CHCl (MIX) 2.08 - - - C C 6 1 2.22 - - 2.67 - - 2.88 - - 3.11 - - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–13 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Aroclor 4465* (cont’d) 3.6 - - 4.2 - - 4.5 - - 5- 5.4 - - 5.9 - - 6.5 - - 6.6 - - 8- 9.3 - - 12.1 - - Responses: OV-101: TR40 atrazine C8H14ClN5 0.43 0.74 0.44 C S # NR 50 1-2-3 Responses: OV-101: TI58/TR200 OV-17: NI20 azafenidin C15H13Cl2N3O2 14 - - V - - - - Responses: OV-101:NI(WB)90 azinphos-ethyl C12H16N3O3PS2 6.9 - 14.8 C P S 50 3 Responses: OV-101: TI58/TR200 OV-17: FP(WB)26/NI20 azinphos-methyl C10H12N3O3PS2 5.2 - 11.8 C NR NR 6-15-50 1-2-3 Responses: OV-101: TI30/TR50 azinphos-methyl oxygen analog C10H12N3O4PS 3.7 - 10.1 C - - - - Responses: OV-101: FP20 OV-17: FP(WB)42 benazolin methyl ester C9H6O3SNCl 0.99 - - - - - - - Responses: OV-101: NI1 bendiocarb C11H13NO4 0.32 - - C - - - - Responses: DEGS: NP13 benfluralin C13H16F3N3O4 0.37 0.28 0.18 C C C 6 2 Responses: OV-101: HX(WB)1.5/NI(WB)2 OV-17: HX(WB)1 OV-225: NI2 benodanil C13H10INO 2.43 - 4.5 C - - - - Responses: OV-101: NP60 benoxacor C11H11Cl2NO2 0.64 1.06 0.7 C P C 15+50 2+3 Responses: OV-101: NI1/NP6 OV-17: NI1/NP7 OV-225: NI2 bensulide C14H24NO4PS3 9.5 - 20.2 C P C 50 3 Responses: OV-101: FP100/NI(WB)9/TI190 OV-17: FP100 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–14 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries benzoylprop-ethyl C18H17Cl2NO3 4.3 8.4 6 P NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)3 OV-17: NI8 OV-225: NI6 BHC, alpha- C6H6Cl6 0.4 0.48 0.35 C C C 6 1 Responses: OV-101: TR0.4 OV-17: NI0.3 BHC, beta- C6H6Cl6 0.43 1.62 0.56 C C C 6 1 Responses: OV-101: TR2 OV-17: NI1 BHC, delta- C6H6Cl6 0.5 1.71 0.67 C C C 6+15 1 Responses: OV-101: HX0.5/TR0.4 OV-17: NI0.5 bifenox C12H9Cl2NO5 5 14.9 8.8 C C P 15+50 2+3 Responses: OV-101: HX16/NI4 bifenthrin C23H22ClF3O2 4.9 3.8 4.5 V C - 6+15 2 Responses: OV-101: NI8 OV-17: HX5/HX(WB)20 binapacryl C15H18N2O6 2.19 4.2 2.38 C P P 15 - Responses: OV-101: NI(WB)1 OV-17: NI22/NP(WB)100 bis(2-ethylhexyl) phthalate C24H38O4 6.4 4.5 6.1 - C C 15+50 - Responses: OV-101: NI(V)200 bis(trichloromethyl)disulfide C2Cl6S2 0.19 - - - R - 6 - Responses: bitertanol* C20H23N3O2 9.4 - 11.8 C - - - - 9.7 - 12.5 Responses: OV-17: NP(WB)200 bromacil C9H13BrN2O2 0.8 4.8 1.36 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)2/NI(WB)2/NP(WB)17 OV-17: HN(WB)1/HX(WB)8/NI(WB)6/NP(WB)5 OV-225: NI(WB)12 bromacil methyl ether C10H16BrN2O2 0.8 2.1 - - - - - - Responses: OV-101: HN(WB)1.2/HX(WB)90/NI(WB)1.5/NP(WB)10 OV-225: NI(WB)3.8 bromofenoxim methyl ether C14H9Br2O6N3 0.3 - - - - - - - Responses: OV-101: HN(WB)6/NI1 bromophos C8H8BrCl2O3PS 1.11 1.29 1.16 C C C 6 - Responses: OV-101: FP3/NI(WB)1/TI3 OV-17: FP3/NI2 OV-225: NI6 bromophos-ethyl C10H12BrCl2O3PS 1.51 1.42 1.45 C C P 6 - Responses: OV-101: FP3/NI3/TI4 OV-17: FP(WB)0.3 bromopropylate C17H16Br2O3 4.4 6.5 - C C # C # 15+50 1-2-3 Responses: OV-101: TR12 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–15 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries bromoxynil butyrate C11H9Br2NO2 0.78 - - - V - 15+50 2 Responses: OV-101: NI0.5/NP7.5 bromoxynil methyl ether C8H5BR2ON 0.3 - - - - - - - Responses: OV-101: NI0.4 bromoxynil octanoate C15H17Br2NO2 3.14 - - - V # - 15+50 2 Responses: OV-101: NI4/NP40 BTS 27271-HCl C10H14N2?HCl - - - - - - - - Responses: BTS 27919 C9H11NO - - - C - - - - Responses: bufencarb* C13H19NO2 - - - - - - - - -- - -- - Responses: Bulan C16H15Cl2NO2 3.06 7.5 4.4 C P P 15 2 Responses: OV-101: NI(WB)1 OV-17: NI5 OV-225: NI6 bupirimate C13H24N4SO3 2 3.7 2.6 C - - - - Responses: OV-101: FS(WB)20/NI(WB)8 OV-17: NP(WB)300 butachlor C17H26ClNO2 1.73 1.83 1.46 C C - 50 - Responses: OV-101: HX9 OV-17: HX9 OV-225: NI14 butralin C14H21N3O4 1.15 1.22 0.93 V C - 6+15+50 - Responses: OV-101: NI7/NP3 OV-17: NI6/NP15 OV-225: NI8 butyl benzyl phthalate C19H20O4 3.06 5.1 4.5 - C P 15+50 - Responses: OV-101: NI35 butylate C11H23NOS 0.22 - - - - - - - Responses: butylisodecyl phthalate C22H34O4 - - 0.82 - - - - - Responses: cadusafos C10H23O2PS2 0.37 0.27 0.29 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP(WB)0.5 OV-17: FP(WB)0.4/NI(WB)12/NP(WB)0.5 OV-225: FP(WB)1 captafol C10H9Cl4NO2S 3.11 - 5.4 C P - 50 3 Responses: OV-101: NI3 OV-17: NI5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–16 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries captan C9H8Cl3NO2S 1.2 3.49 1.85 C P C 50 3 Responses: OV-101: TR2 OV-17: NI2 carbaryl C12H11NO2 0.75 - 1.05 C - - - - Responses: OV-101: NP60 carbetamide C12H16N2O3 0.96 - 1.32 - - - - - Responses: carbofuran C12H15NO3 0.39 - - C - - - - Responses: carbofuran-3-keto-7-phenol C10H10O3 - 0.24 - - - - - - Responses: carbofuran-7-phenol-DNP ether C16H14N2O6 - 18.1 - - - - - - Responses: carbophenothion C11H16ClO2PS3 2.94 4.2 3.7 C C P 6 2 Responses: OV-101: TI15/TR4 OV-17: FP8 carbophenothion oxygen analog C11H16ClO3PS2 2.17 4.2 3.06 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI6/TI15 OV-17: FP15 carbophenothion oxygen analog C11H16ClO5PS2 3.8 - 7.1 - - - - - sulfone Responses: OV-101: NI36/TI35 OV-17: FP(WB)24 carbophenothion oxygen analog C11H16ClO4PS2 4.2 - 2.87 - - - - - sulfoxide Responses: OV-101: TI250 OV-17: FP15 carbophenothion sulfone C11H16ClO4PS3 5.1 - 9.2 C C P 6 1 Responses: OV-101: FP3/TI20 OV-17: FP30 carbophenothion sulfoxide C11H16ClO3PS3 5.4 - 4 - - - - - Responses: OV-101: FP3/TI35 OV-17: FP20 carbosulfan C20H32N2O3S 5.4 - 5.3 P - - - - Responses: OV-101: NP20 carboxin C12H13NO2S 1.87 - - C NR NR 6-15-50 - Responses: OV-101: FS50 carboxin sulfoxide C12H13NO3S 0.13 0.23 0.11 - NR NR 6-15-50 1-2-3 Responses: OV-101: FS10 OV-17: FS30 OV-225: FS25 CGA 100255 C15H12NO5 1.8 - 2.96 S - - - - Responses: OV-101: NP100 OV-17: NI1000/NP150 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–17 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries CGA 118244 C15H13Cl2N3O3 7 - 11.4 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI40 CGA 120844 C8H9NSO3 0.6 2.65 0.9 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI200/NP200 OV-17: NI100/NP300 OV-225: NI300 CGA 14128 C12H21N2O4PS 0.75 0.8 0.68 C - 50 1-2-3 Responses: OV-101: NI2/NP2 OV-17: NI0.6/NP2 OV-225: NI2 D CGA 150829 C5H14N4O 0.22 - 0.14 V - - - - Responses: OV-101: NP0.5 OV-17: NP1 CGA 171683 C6H5F4N3O2 0.06 0.08 0.04 C - 15+50 3 Responses: OV-101: NI30 OV-17: NI10 OV-225: NI40 CGA 189138 C13H8O3Cl2 1.39 1.89 1.54 - - - - - Responses: OV-101: NI1000 OV-17: NI1000 OV-225: NI1000 CGA 205374 C16H11N3O2Cl2 12 8.9 6.1 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI50 OV-17: NI200 OV-225: NI500 CGA 205375 C16H13N3O2Cl2 6.7 - 1.59 - - - - - Responses: OV-101: NI1000 OV-17: NI1000 CGA 236431 C8H7F3N2O2 0.17 - 0.11 - - - - - Responses: OV-101: NP200 OV-17: NP20 CGA 236432 C9H9F3N2O2 0.26 - 0.13 - - - - - Responses: OV-101: NP20 OV-17: NP8 CGA 27092 C8H7F3N2O - - 0.62 - - - - - Responses: OV-17: NP50 CGA 37734 C10H13NO2 0.4 - 0.47 C NR NR 6-15-50 1-2-3 Responses: OV-101: NP(V)20 OV-17: NP100 CGA 51702 C9H9F3N2O 0.46 - 0.49 - - - - - Responses: OV-101: NP2 OV-17: NP3 CGA 72903 C7H6F3N 0.22 - 0.14 - - - - - Responses: OV-101: NP100 OV-17: NP50 CGA 91305 C10H8Cl2N3O 1.15 4.3 1.54 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI3 CGA 94689A C15H21NO5 1.53 6.5 2.41 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI5/NP150 OV-17: NI5/NP38 OV-225: NI5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–18 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries CGA 94689B C15H21NO5 1.54 6.6 2.45 S NR NR 6-15-50 1-2-3 Responses: OV-101: NI12/NP150 OV-17: NI10/NP75 OV-225: NI8 chloramben methyl ester C8H7Cl2NO2 0.44 1.03 - - - - - - Responses: OV-101: HX0.8/NI0.8 chlorbenside C13H10Cl2S 1.39 1.62 1.54 C S P 6 1 Responses: OV-101: NI6 OV-17: HX3/NI1 chlorbromuron C9H10BrClN2O2 1.27 3.39 1.42 V V V 50 3 Responses: OV-101: HX12/NI19 chlorbufam C11H10ClNO2 0.42 0.75 0.45 C - 15 2+3 Responses: OV-101: HX4 OV-17: HN(WB)0.4 chlordane* C10H6Cl8 0.45 0.16 - C C C 6 1 0.63 0.5 - 0.73 0.52 - 0.81 0.85 0.23 0.97 0.9 0.53 1.16 1.45 0.61 1.45 1.54 0.88 1.62 2.69 1.33 2.61 3.33 1.47 Responses: OV-101: NI(WB)5 OV-17: NI11 OV-225: NI4 chlordane, cis- C10H6Cl8 1.66 1.54 1.48 C C C 6 1 Responses: OV-101: TR1 OV-17: NI0.8 chlordane, trans- C10H6Cl8 1.49 1.46 1.34 C C C 6 1 Responses: OV-101: TR1 OV-17: NI0.6 chlordecone C10H8Cl10O5 2.75 1.67 2.38 - S # P # 15+50 1-2-3 Responses: OV-101: NI(WB)2 OV-17: HX2/NI5 OV-225: NI6 chlordene C10H6Cl6 0.56 0.4 0.32 - C C 6 1 Responses: OV-101: NI(WB)1 OV-17: NI0.4 OV-225: NI0.3 chlordene epoxide C10H6Cl6O 0.84 0.65 - - C - 15 - Responses: OV-101: NI0.6 chlordene, alpha- C10H6Cl6 0.82 0.64 0.67 - - - - - Responses: OV-101: TR2 OV-17: NI0.6 chlordene, beta- C10H6Cl6 0.98 0.84 0.89 - - - - - Responses: OV-101: TR1 OV-17: NI1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–19 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries chlordene, gamma- C10H6Cl6 0.98 0.89 0.88 - - - - - Responses: OV-101: TR2 OV-17: NI1 OV-225: NI1 chlorethoxyfos C6H11Cl4O3PS 0.33 0.23 0.24 V C - 6 1 Responses: OV-101: FP0.5/HX0.3/NI0.5 OV-17: FP0.5/HX0.3/NI0.3 OV-225: FP0.5/NI0.3 chlorfenapyr (prop) C15H11BrClF3N2O 2.21 - 2.34 P - S 50 2 Responses: OV-101: NI2/NP50 OV-17: NI2/NP50 DEGS: NI4/NP190 chlorfenvinphos, alpha- C12H14Cl3O4P 1.21 1.58 1.29 C - NR 6-15-50 - Responses: OV-101: FP10/FP(WB)1.7/NI(WB)2/TI4 OV-17: FP(WB)2/NI3 OV-225: NI5 chlorfenvinphos, beta- C12H14Cl3O4P 1.29 2 1.52 C S # - 50 1-2-3 Responses: OV-101: FP2/FP(WB)1.8/HX3/NI(WB)2/TI4 OV-17: FP4/FP(WB)2/NI3 OV-225: FP4/NI5 chlorflurecol methyl ester C15H11ClO3 1.73 - 1.88 C - - - - Responses: OV-101: HX8/NI3 chlorimuron ethyl ester C15H15ClN4O6S 0.13 0.15 0.1 P NR - - - Responses: OV-101: NI14/NI(WB)24/NP35 OV-17: NI(WB)1.4/NP23 chlormephos C5H12ClO2PS2 - - 0.11 C - - - - Responses: OV-17: FP0.4 chlornitrofen C12H6Cl3NO3 2.85 4.7 - C C C 6+15 2 Responses: OV-101: TR5 chlorobenzilate C16H14Cl2O3 2.31 3.26 2.61 C C # P # 15+50 3 Responses: OV-101: TR70 OV-17: NI15 chloroneb C8H8Cl2O2 0.19 0.19 - C C - 6 2 Responses: OV-101: NI3.5 chloropropylate C17H16Cl2O3 2.33 2.9 2.41 P C C 15+50 3 Responses: OV-101: TR80 OV-17: NI15 chlorothalonil C8Cl4N2 0.55 1.44 0.74 S C # C # 6-15-50 2+3 Responses: OV-101: HX1/NI0.6 OV-17: HX1/NI2 chlorothalonil trichloro impurity C8HCl3N2 0.32 - - R R # NR 6-15-50 2+3 Responses: chloroxuron C15H15ClN2O2 0.81 0.85 - C NR NR 6-15-50 1-2-3 Responses: OV-101: HX16/NI300 chlorpropham C10H12ClNO2 0.32 0.43 0.25 C C C 15 2 Responses: OV-101: HX2 OV-17: NI80 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–20 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries chlorpyrifos C9H11Cl3NO3PS 1 1 1 C C P 6 2 Responses: OV-101: NI1.5/TI3 OV-17: FP2/NI2 chlorpyrifos oxygen analog C9H11Cl3NO4P 0.95 1.51 1.08 C NR - 6-15-50 - Responses: OV-101: FP27/NI6/TI8 chlorpyrifos-methyl C7H7Cl3NO3PS 0.72 0.86 0.79 C C - 6 2 Responses: OV-101: FP1/FP(WB)1.3/HX1.5/NI1/NP1 OV-17: FP(WB)1.5 chlorsulfuron C12H12ClN5O4S 1.3 8.9 - - NR NR 6-15-50 - Responses: OV-101: NI50 chlorthiamid C7H5Cl2NS 0.69 - - - - - - - Responses: chlorthiophos oxygen analog C11H15Cl2O4PS 2.22 4.1 2.99 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX9/NI6 OV-17: FP10/HX11 OV-225: FP6 chlorthiophos sulfone C11H15Cl2O5PS2 5.3 18.8 9.1 C C - 50 3 Responses: OV-101: HX20/NI9 OV-17: FP100/HX22 OV-225: FP39 chlorthiophos sulfoxide C11H15Cl2O4PS2 4.7 10.3 6.9 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX20/NI6 OV-17: FP25/HX17 OV-225: FP15 chlorthiophos* C11H15Cl2O3PS2 2.24 - 2.58 C C C 6 2 2.36 - 2.77 2.56 - 3.16 Responses: OV-101: FP8 OV-17: FP5 CL 202,347 C13H19N3O5 2.96 11.5 4.1 - - - - - Responses: OV-101: NI15/NP50 OV-17: NI20/NP100 OV-225: NI60 clodinafop-propargyl C17H13ClFNO4 3.26 5.8 4.67 V V - 50 3 Responses: OV-101:NP(WB)30 OV-17:NI(WB)20 OV-225:NI(WB)5 clofentezine C14H8Cl2N4 5.9 - 9.8 R S - 15 2 Responses: OV-101: HN(WB)10.5/HX20/NI100 OV-17: NP165 clomazone C12H14ClNO2 0.45 0.59 0.46 C - 50 3 Responses: OV-101: HX1.5/HX2/NI110 OV-17: HX2/NP11 OV-225: NI150 clopyralid methyl ester C7H4Cl2NO2 0.18 - - - - 50 - Responses: OV-101: NI0.25 cloquintocet-mexyl C18H22ClNO3 4.8 6.6 6.3 V NR - 6-15-50 1-2-3 Responses: OV-101:NP(WB)40 OV-17:NI(WB)20 OV-225:NI(WB)5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–21 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Compound K* C10H6Cl8 0.83 - - - C - - 1 2.53 2.66 - Responses: OV-101: TR5 coumaphos C14H16ClO5PS 9 40 18 C NR C # 6-15-50 3 Responses: OV-101: NI39/NP38 OV-17: FP50/FP(WB)26/NI38/NP34 OV-225: NI100 coumaphos oxygen analog C14H16ClO6P 8 45 16 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI200/NP130 OV-17: FP75/NI50/NP40 OV-225: NI150 CP 108064, methylated C15H21NO4 0.73 - 0.67 - - - - - Responses: OV-101: NP6 OV-17: NP6 CP 51214 C14H21NO3 0.7 - 0.58 C NR NR 6-15-50 1-2-3 Responses: OV-101: NP13 OV-17: NP24 crotoxyphos C14H19O6P 1.37 2.85 1.9 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI60/TI10 OV-17: FP10/FP(WB)3 crufomate C12H19ClNO3P 1.08 2.33 1.3 C NR NR 6-15-50 - Responses: OV-101: TI6 OV-17: FP2/NI3 cyanazine C9H13ClN6 0.89 4.9 1.48 C NR - 6-15-50 - Responses: OV-101: NI4/TI26 OV-17: HX6 cyanofenphos C15H14NO2PS 3.1 8.2 4.6 C - - - - Responses: OV-101: FP3.5/NI3/NP(WB)3 cyanophos C9H10O3NSP 0.47 - 0.59 C - - - - Responses: OV-101: FP(WB)0.7/NI(WB)2/NP1 OV-17: FP(WB)0.7/NP(WB)1 cyclanilide methyl ester C12H11Cl2NO3 1.57 1.84 1.64 - - - - - Responses: OV-101: NI5/NP30 OV-17: NI6/NP30 OV-225: NI6 cycloate C11H21NOS 0.3 - - C V # S 15+50 3 Responses: OV-101: FS2/NP15 cyfluthrin* C22H18Cl2FNO3 11.7 - - C P - 15 - 12.5 - - 12.8 - - Responses: OV-101: HX30/NI30 cymiazole C12H14N2S 0.73 - 0.89 - - - - - Responses: OV-101: NP2 OV-17: NP(WB)2 cymoxanil C7H10N4O3 0.25 0.5 0.16 V NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)1/NI(WB)23/NP(WB)10 OV-17: HN(WB)3/NI(WB)120/NP(WB)7 OV-225: NI(WB)70 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–22 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries cypermethrin* C22H19Cl2NO3 - 29 - C C C 15 2 14.1 33 23 15.1 36 25 Responses: OV-101: NI90 cyprazine C9H14ClN5 0.64 1.22 0.74 C - - - - Responses: OV-101: HX1.5/NI13 cyproconazole C15H18ClN3O 2.04 1.61 2.69 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)182/HX(WB)73/NI(WB)72/NP(WB)12 cyprodinil C14H15N3 1.18 - 1.39 C NR NR 6-15-50 1-2-3 Responses: OV-101: NP(WB)2 OV-17: NP(WB)10 cyromazine C6H10N6 0.58 - 0.68 S - - - - Responses: OV-101: NP10 OV-17: NP2 dazomet C5H10N2S2 0.4 - 0.71 S NR - 6-15-50 1-2-3 Responses: OV-101: HX500/NI300 OV-17: FS(WB)80/HN(WB)0.4/HX500/NI300 DCPA C10H6Cl4O4 1.06 1.13 1 C C C 15 2 Responses: OV-101: NI1 OV-17: NI1 OV-225: NI1 DDE, o,p'- C14H8Cl4 1.55 1.28 1.51 C C C 6 1 Responses: OV-101: TR2 OV-17: NI1 DDE, p,p'- C14H8Cl4 1.92 1.59 1.86 C C C 6 1 Responses: OV-101: NI1.5 OV-17: NI1 DDM C13H10Cl2 0.72 - - - - - - - Responses: DDMS C14H11Cl3 1.65 - 1.65 - R - 6 - Responses: DDMU C14H9Cl3 1.47 - - - - - - - Responses: DDNS C14H12Cl2 0.83 - - - - - - - Responses: DDNU C14H10Cl2 0.83 - - - - - - - Responses: DDT, o,p'- C14H9Cl5 2.55 2.27 2.7 C C C 6 1 Responses: OV-101: TR4 OV-17: NI2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–23 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries DDT, p,p'- C14H9Cl5 3.13 3.6 3.5 C C C 6 1 Responses: OV-101: TR4 OV-17: NI2 deltamethrin* C22H19Br2NO3 17.1 - 21 C S # P 15 2 27 - 35 29 19.9 38 Responses: OV-101: NI1300 deltamethrin, trans-* C22H19Br2NO3 17 - 6.2 - P # NR 15 2 29 - 20 31 19.7 38 Responses: OV-101: NI200 demeton-O oxygen analog C8H19O4PS 0.22 0.32 0.21 - - - - - Responses: OV-101: TI6 OV-17: FP25 demeton-O sulfone* C8H19O5PS2 - - 0.28 C - - - - 0.71 2.95 0.96 Responses: OV-101: FP5/TI12 OV-17: FP3 demeton-O sulfoxide C8H15O4PS2 0.87 - 1.05 C - - - - Responses: OV-101: FP4 demeton-O* C8H19O3PS2 - - 0.2 C NR - 6-15 - 0.28 - 0.36 Responses: OV-101: FP(WB)2 OV-17: FP2 demeton-S C8H19O3PS2 0.41 0.56 0.41 C NR - 6-15-50 - Responses: OV-101: FP(WB)0.8/TI2 OV-17: FP0.8/FP(WB)0.8 demeton-S sulfone C8H19O5PS2 1.15 5.8 1.75 C - - - - Responses: OV-101: FP40/TI20 OV-17: FP5 OV-225: FP60 demeton-S sulfoxide C8H19O4PS2 - - - C - - - - Responses: DEGS: FP30 des N-isopropyl isofenphos C12H18NO4PS 1.21 2.73 1.5 C S - 50 - Responses: OV-101: FP2 OV-17: FP3 des N-isopropyl isofenphos oxygen C12H18NO5P 0.93 - 1.43 - - - - - analog Responses: OV-101: FP(WB)5 OV-17: FP(WB)12 desdiethyl simazine C3H4ClN5 0.2 0.86 0.61 - NR NR 6-15-50 1-2-3 Responses: OV-101: HX25/NI20 OV-17: HN(WB)0.1/HX25 OV-225: NI20 desethyl simazine C5H8ClN5 0.3 0.8 0.53 - NR NR 50 1-2-3 Responses: OV-101: HX12/NI20 OV-17: HN(WB)0.1/HX12 OV-225: NI80 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–24 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries desisopropyl iprodione C10H6Cl2N3O3 2.31 15 3.93 P - 50 1-2-3 Responses: OV-101: NI20/NP50 desmedipham C16H16N2O4 0.44 0.29 0.45 - - - - - Responses: OV-101: NI1000/NP300 OV-17: NI1000/NP218 OV-225: NI1000 desmethyl diphenamid C15H15NO 0.98 - - - - - - - Responses: OV-101: TI340 desmethyl norflurazon C11H7ClF3N3O 3.38 1.41 4.9 V NR NR 6-15-50 1-2-3 Responses: OV-101: HX(WB)3/NI27 OV-17: HX(WB)3 OV-225: NI200 di-allate C10H17ClNOS 0.42 0.26 0.33 C C - 6 - Responses: di-n-octyl phthalate C24H38O4 12 - - - C C 15+50 - Responses: OV-101: NI(V)330 dialifor C14H17ClNO4PS2 6.5 - 14.3 C C P 15 2 Responses: OV-101: TI30/TR28 OV-17: FP25/FP(WB)31 diazinon C12H21N2O3PS 0.51 0.4 0.44 C C C 15 3 Responses: OV-101: FP(WB)1/NI3/NP0.4 OV-17: FP0.7/FP(WB)0.9/NI4/NP0.25 OV-225: FP6/NI4.5 diazinon oxygen analog C12H21N2O4P 0.5 0.53 0.47 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI18/NP0.6 OV-17: NI30/NP0.6 OV-225: NI60 dibromochloropropane C3H5Br2Cl 0.04 - 0.03 - - - - - Responses: OV-101: TR0.6 OV-17: NI0.2 dibutyl phthalate C16H22O4 0.88 0.92 0.84 - C C 15+50 - Responses: OV-101: NI30 dicamba methyl ester C8H6Cl2O3 0.19 0.18 - - - - - - Responses: OV-101: HX(WB)1.6/NI0.6 dichlobenil C7H3Cl2N 0.11 - 0.1 C P C 15 2 Responses: OV-101: TR0.5 OV-17: NI0.6 dichlofenthion C10H13Cl2O3PS 0.67 0.64 0.56 C C V 6 2 Responses: OV-101: FP1/FP(WB)3.5/NI1.9/TI2 OV-17: FP0.8/HX(WB)2 dichlofluanid C9H11Cl2FN2O2S2 0.9 1.71 1.01 C C # - 15+50 2+3 Responses: OV-101: NI1/NP44 dichlone C10H4Cl2O2 0.55 0.92 - P S # S # 6-15-50 2+3 Responses: OV-101: NI2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–25 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries dichlorobenzene, p- C6H4Cl2 0.03 - 0.02 - C C 6 1 Responses: OV-101: TR37 OV-17: NI4 dichlorobenzophenone, o,p'- C13H8Cl2O 0.82 1.07 0.92 - C C 15 2 Responses: OV-101: TR4 OV-17: NI2 dichlorobenzophenone, p,p'- C13H8Cl2O 0.99 1.25 1.08 - C C 15 2 Responses: OV-101: TR3 OV-17: NI2 dichlorprop methyl ester C10H10Cl2O3 0.28 - - - - - - - Responses: OV-101: HX(WB)1.6/NI2 dichlorvos C4H7Cl2O4P 0.07 0.08 0.08 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP9/NI1/TI0.5 OV-17: FP2.5 OV-225: FP(WB)0.7 diclobutrazol C15H19Cl2N3O 2.02 3.4 2.03 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX7/NI7/NP(WB)8 OV-17: HN(WB)1.3/HX7/HX4/HX(WB)2/NI(WB)4/NP(WB)8 OV-225: NI7 diclofop-methyl C16H14Cl2O4 3.57 4.9 4.7 C C C 15 2 Responses: OV-101: HX8/NI10 OV-17: HX10 OV-225: NI12 dicloran C6H4Cl2N2O2 0.42 0.96 0.45 C S P 15+50 2+3 Responses: OV-101: TR0.5 OV-17: NI0.4 dicofol, o,p'-* C14H9Cl5O 0.86 - - C V S 6+15 2 4.1 1.08 0.91 Responses: OV-101: NI5 OV-17: HX2 dicofol, p,p'-* C14H9Cl5O 1.04 - - C V P # 6+15 1+2 4.4 1.28 1.08 Responses: OV-101: NI5 OV-17: HX3 dicrotophos C8H16NO5P 0.31 0.96 0.43 C NR - 6-15-50 - Responses: OV-101: FP(WB)0.6/TI10 OV-17: FP1/FP(WB)0.8 dieldrin C12H8Cl6O 1.91 1.87 1.84 C C C 15 2 Responses: OV-101: HX1/NI1.5 OV-17: HX1.5/NI1 diethatyl-ethyl C16H22ClNO3 1.78 3.14 2 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX11/NI10/NP180 OV-17: NI11/NP200 OV-225: NI14 diethyl phthalate C12H14O4 0.26 - - - P P 15+50 - Responses: OV-101: NI3500 difenoxuron C16H18N2O3 0.97 - 0.96 - - - - - Responses: OV-101: HN(WB)5 OV-17: NP16 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–26 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries diisobutyl phthalate C16H2204 0.65 0.61 0.56 - P - 15+50 - Responses: OV-101: NI20 diisohexyl phthalate* C20H30O4 2.45 - - - C - 15+50 - 2.66 - - 2.9 - - 3.27 - - Responses: OV-101: TR340 diisooctyl phthalate* C24H38O4 0.91 - - - C C 15+50 - 5.5 - - 6.2 - - 6.7 - - 7.5 - - 9- 10.5 - - Responses: OV-101: TR850 Dilan* C15.5H14Cl2NO2 - 5.3 - - P P 15 - - 4.8 - 2.33 5.8 - 2.81 7.5 - 3.39 8.2 - Responses: OV-101: TR8 dimethachlor C13H18ClNO2 0.71 1.11 0.71 C - - - - Responses: OV-101: NI30 OV-17: NI10 OV-225: NI20 dimethametryn C11H21N5S - - - C - - - - Responses: dimethenamid C12H18ClNO2S 0.72 0.98 - - NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)19/NP(WB)14 dimethipin C6H10O4S2 0.41 2.71 0.81 C NR NR 6-15-50 1-2-3 Responses: OV-101: FS0.5 OV-17: FS1.5 OV-225: FS2 dimethoate C5H12NO3PS2 0.4 1.6 0.62 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP(WB)0.7/NI(WB)6/NP1 OV-17: FP0.8/FP(WB)0.8/NI5 dimethyl phthalate C10H10O4 0.15 0.15 0.14 - P - 6+15+50 - Responses: OV-101: NI300 dinitramine C11H13F3N4O4 0.52 0.93 0.44 C - P 15 - Responses: OV-101: NI(WB)1/TI166 OV-17: NI1 OV-225: NI1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–27 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries dinobuton C14H18N2O7 1.4 - 1.32 C - - - - Responses: OV-101: HN(WB)1.5 OV-17: HN(WB)1/NP(WB)50 dinocap* C18H24N2O6 - - 3.5 C P P 15 2 4 - 3.9 4.3 6.9 4.4 4.8 7.7 4.8 5.1 9.5 5.6 Responses: OV-101: NI(WB)6 OV-17: NI150 dinoseb methyl ether C11H14N2O5 0.63 - - - - - - - Responses: OV-101: HN1/NI1.2 dioxabenzofos C8H9O3PS 0.34 - 0.36 C P - 15 - Responses: OV-17: FP0.7 dioxacarb C11H13NO4 - - - C - - - - Responses: dioxathion C12H26O6P2S4 0.47 - 0.5 V NR - 6-15-50 2 Responses: OV-101: NI100/TI10 OV-17: FP7/FP(WB)13 diphenamid C16H17NO 1.1 - 1.55 V NR - 6-15 - Responses: OV-17: NP(WB)25 diphenylamine C12H11N 0.29 - 0.25 C S - 6+15 - Responses: disul-Na C8H7Cl2O5S?Na 0.23 - - - - - - - Responses: OV-101: NI3 disulfoton C8H19O2PS3 0.54 0.6 0.46 C P # NR 6 1-2-3 Responses: OV-101: TI2 OV-17: FP1 disulfoton sulfone C8H19O4PS3 1.5 6.7 2.39 C NR - 6-15-50 - Responses: OV-101: TI7 OV-17: FP7 disulfoton sulfoxide C8H1903PS3 - - - C - - - - Responses: dithianon C14H4O2N2S2 4.7 53 11.3 NR - - - - Responses: OV-101: NI(WB)12 OV-17: NP(WB)120 diuron C9H10Cl2N2O 0.11 0.09 0.11 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)9 OV-17: NI12 OV-225: NI27 DNOC methyl ether C8H8N2O5 0.35 - - - - - - - Responses: OV-101: HN(WB)30 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–28 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries edifenphos C14H15O2PS2 2.87 6.3 5.3 C - - - - Responses: OV-101: FP(WB)4/NI(WB)4 OV-17: FP(WB)8 endosulfan I C9H6Cl6O3S 1.64 1.38 1.47 C C C 15 2 Responses: OV-101: HX1/NI1.3 OV-17: HX1/NI2 endosulfan II C9H6Cl6O3S 2.21 3.9 2.77 C C C 15+50 2 Responses: OV-101: HX2/NI2 OV-17: HX3/NI2 endosulfan sulfate C9H6Cl6O4S 2.83 8.3 4 C C C 50 2 Responses: OV-101: HX4/TR5 OV-17: HX6/NI6 endrin C12H8Cl6O 2.13 2.22 2.29 C C # C # 15 2 Responses: OV-101: TR2 OV-17: NI2 endrin alcohol C12H8Cl6O 2.55 - - - P C 15+50 2+3 Responses: OV-101: TR4 endrin aldehyde C12H8Cl6O 2.35 - - C P C 15+50 - Responses: OV-101: TR4 endrin ketone C12H8Cl6O 3.6 10.3 - - C C 50 2 Responses: OV-101: TR5 EPN C14H14NO4PS 4.5 10.6 6.9 C C C 15 2 Responses: OV-101: NI0.5/TI16 OV-17: FP50/NI9 epoxyhexachloronorbornene C7H2Cl6O - - 0.2 - - - - - Responses: EPTC C9H19NOS 0.12 - - - P - 15 - Responses: OV-101: TI30 esfenvalerate C25H22ClNO3 22.5 - - C C C 15 2 Responses: OV-101: NI90 etaconazole* C14H15Cl2N3O2 2.36 - - C - - - - 2.43 - 3.17 Responses: OV-101: NP(WB)12 OV-17: HX7 ethalfluralin C13H14F3N3O4 0.34 0.27 0.19 C C C 6 2 Responses: OV-101: HX4/HX(WB)7/NI1 OV-17: HX6 OV-225: NI0.4 ethametsulfuron methyl ester* C15H18N6O6S 0.35 2.85 0.4 - NR NR 6-15-50 1-2-3 0.55 3.6 0.95 Responses: OV-101: HN(WB)17/NI(WB)34/NP(WB)600 OV-17: HN(WB)30 OV-225: NI(WB)780 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–29 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries ethephon C2H6ClO3P 3.03 2.74 2.88 NR - 6+15+50 1+2+3 Responses: OV-101: NI170 ethiofencarb C10H15NO2S 0.6 1.4 0.78 C NR NR 6-15-50 - Responses: OV-101: FP20/FP400/FS1.5/HN(WB)3.5/NI950/NP(WB)4 OV-17: NP133 ethiolate C7H15NOS 0.06 - - C - - - - Responses: OV-101: FS9 ethion C9H22O4P2S4 2.56 3.93 3.36 C C C 6 2 Responses: OV-101: FP(WB)1.9/NI(WB)3/NP2 OV-17: FP4/FP(WB)2.3/NI8 OV-225: FP2/NI8 ethion oxygen analog C9H22O5P2S3 1.88 4.1 - C - - - - Responses: OV-101: NP1 ethofumesate C13H18O5S 0.86 1.93 1.02 C - - - - Responses: OV-101: FS32/NI315 OV-17: FS65/NI333 OV-225: FS56/NI638 ethoprop C8H19O2PS2 0.33 0.31 0.25 C P # S # 50 1-2-3 Responses: OV-101: FP0.7/TI0.8 OV-17: FP1 ethoxyquin C14H19N0 0.6 1.64 0.7 C NR NR 6-15-50 - Responses: OV-101: NI20/NP15 OV-17: NI12/NP15 OV-225: NI30 ethyl p-toluene sulfonamide C9H13NO2S - - - C - - - - Responses: ethylenethiourea C3H6N2S 0.5 2.33 0.66 S NR NR 6-15-50 1-2-3 Responses: OV-101: NI2200/NP23 OV-17: NI4500/NP64 OV-225: NI6250 etridiazole C5H5Cl3N2OS 0.18 0.12 0.21 C C P 6 2 Responses: OV-101: NI0.3/NP0.6 OV-17: HX(WB)0.8/NI0.4/NP0.5 OV-225: NI0.2 etrimfos C10H17N2O4PS 0.58 0.59 0.51 C C C 15 2+3 Responses: OV-101: FP2/NI50 OV-17: NI50 OV-225: NI30 etrimfos oxygen analog C10H17N2O5P 0.51 0.8 0.63 C - - - - Responses: OV-101: FP7/NI1000/NP(WB)3.5 famphur C10H16NO5PS2 2.65 14 5 C NR - 6-15-50 - Responses: OV-101: FP8/TI40 OV-17: FP50/FP(WB)7 famphur oxygen analog C10H16NO6PS 2.26 - 4.4 C - - - - Responses: OV-101: FP54 OV-17: FP(WB)12 fenac C8H5Cl3O2 1.42 3.7 - - NR NR 6-15-50 - Responses: OV-101: NI2800 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–30 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries fenac methyl ester C9H7Cl3O2 0.32 - - - - - - - Responses: OV-101: NI0.4 fenamiphos C13H22NO3PS 1.66 3.7 2.41 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP8/NP8 OV-17: FP10/NP3 OV-225: NP6 fenamiphos sulfone C13H22NO5PS 4.5 - 8.4 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP50/NP20 OV-17: FP(WB)20/NP60 fenamiphos sulfoxide C13H22N04PS 5.2 - 8.1 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP50/NP55 OV-17: FP(WB)28/NP45 fenarimol C17H12Cl2N2O 6.6 - 10.1 C P # C # 50 3 Responses: OV-101: HX10/NI5 fenarimol metabolite B C17H14N2OCl2 4.6 - - NR NR NR 6-15-50 - Responses: OV-101: HX19 fenarimol metabolite C C17H14N2OCl2 4.6 - - S - 6 - Responses: OV-101: HX8 fenbuconazole C19H17ClN4 9.8 - - C NR NR 6-15-50 1-2-3 Responses: OV-101: NI1000/NP70 fenfuram C12H11NO2 0.54 1.47 0.62 C - - - - Responses: OV-101: NP5/NP(WB)6 fenhexamid C14H17Cl2NO2 3.1 - 3.7 NR NR NR 6-15-50 1-2-3 Responses:OV-101:NI(WB)2/NP(WB)220 OV-17:NI(WB)5 fenitrothion C9H12NO5PS 0.84 1.82 1.05 C C C 15 2 Responses: OV-101: FP(WB)1/NP1 OV-17: FP3/FP(WB)1.1 fenitrothion oxygen analog C9H12NO6P 0.72 - 0.83 C - - - - Responses: OV-101: FP3 OV-17: FP10 fenoxaprop ethyl ester C18H16NO5Cl 8.1 11.3 10.5 S V V 50 3 Responses: OV-101: NI250 fenoxycarb C17H19NO4 5 - 7.3 C - - - - Responses: OV-101: NP50 OV-17: NP50 fenpropathrin C22H23NO3 4.8 7 5.7 - V # V 15 2 Responses: OV-101: NI7/NI(WB)0.2/NP30 OV-17: NI13 OV-225: NI10 fenpropimorph C20H33NO 1.09 - 0.62 C - 50 1-2-3 Responses: OV-101: NP33 OV-17: NP14 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–31 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries fenson C12H10O3ClS - 2.03 - - - - - - Responses: OV-225: NI1.5 fensulfothion C11H17O4PS2 2.4 - 3.8 C NR NR 6-15-50 1-2-3 Responses: OV-101: TI12 OV-17: FP6/FP(WB)7 fensulfothion oxygen analog C11H17O5PS 2.49 - 5 C NR - 6-15-50 - Responses: OV-101: TI10 OV-17: FP5 fensulfothion oxygen analog sulfone C11H17O7PS2 1.99 - 3.8 - - - - - Responses: OV-101: TI45 OV-17: FP6 fensulfothion sulfone C11H17O5PS2 2.8 - 3.6 C NR - 6-15-50 - Responses: OV-101: NI9/NP7 OV-17: FP100 fenthion C10H15O3PS2 0.96 1.46 1.18 C S # NR 6+15 1-2-3 Responses: OV-101: FP2/TI4 OV-17: FP3 fenthion oxygen analog C10H15O4PS 0.78 - 1.12 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP7 OV-17: FP9 fenthion oxygen analog sulfone* C10H15O6PS2 1.77 - - - - - - - 2.29 - 4.1 Responses: OV-101: FP(WB)4 OV-17: FP(WB)8 fenthion oxygen analog sulfoxide C10H15O5PS 0.43 - 0.62 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP100 OV-17: FP135 fenthion sulfone C10H15O5PS2 2.39 - 4.7 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP22 OV-17: FP20 fenvalerate* C25H22ClNO3 20.3 44 35 C C C 15 2 22.5 51 40 Responses: OV-101: NI90 fipronil C12H4Cl2F6N4OS 1.35 8.7 1.16 S S V 50 3 Responses: OV-101: NI2/NP10 OV-17: NI1/NP5 OV-225: NI10 flamprop-M-isopropyl C19H19ClFNO3 2.46 - 2.81 C - - - - Responses: OV-101: HX9/NI9 flamprop-methyl C17H15ClFNO3 1.94 - 2.45 C - - - - Responses: OV-101: HX8/NI7 fluazifop butyl ester C19H20F3NO4 2.3 2.36 2.31 C C V 15 3 Responses: OV-101: HX19/HX(WB)18/NI125 OV-17: HX40 OV-225: NI3000 fluchloralin C12H13ClF3N3O4 0.53 0.76 0.37 C C - 6 2 Responses: OV-101: HX3/NI1.5 OV-17: HX3/NI0.5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–32 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries flucythrinate* C26H23F2NO4 14.7 36.9 21.4 C C - 15 2+3 16.1 42 24 Responses: OV-101: NI40/NI(WB)15 flumetsulam, methylated C13H11F2N5O2S 12.4 - - - - - - - Responses: OV-101: NP(WB)14 fluometuron C10H11F3N2O - - 0.14 - - - - - Responses: OV-17: NP2 fluridone C19H14F3NO 16.3 24 - - NR NR 6-15-50 - Responses: OV-101: HX400/NI1500 fluroxypyr, methylated* C8H7O3N2Cl2F 0.61 - - - - - - - 0.79 - - Responses: OV-101: NI2 flusilazole C16H15F2N3Si 1.97 - 2.33 C - - - - Responses: OV-101: NP(WB)5 OV-17: HX24/HX(WB)5/NP(WB)6 fluvalinate* C26H22ClF3N2O3 - 56 35 C C - 15 2 25 59 38 Responses: FMTU C10H9F3N2O2 - - - - - - - - Responses: folpet C9H4Cl3O2NS 1.23 3.01 1.94 C C P 15+50 2+3 Responses: OV-101: NI(WB)1 OV-17: NI9 fonofos C10H15OPS2 0.52 0.56 0.44 C C C 6 2+3 Responses: OV-101: TI2 OV-17: FP0.7 fonofos oxygen analog C10H15O2PS 0.39 0.53 0.38 V NR NR 6-15-50 1-2-3 Responses: OV-101: NP1 OV-17: FP4/FP(WB)1 formetanate hydrochloride C11H16ClN3O2 0.9 - 0.45 - - - - - Responses: OV-101: NP400 OV-17: NP430 formothion C6H12NO4PS2 - - 0.91 C NR NR 6-15-50 1-2-3 Responses: OV-17: FP(WB)10 fosthiazate C9H18NO3PS2 1.08 3 1.66 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP100/NI1000/NP40 OV-17: FP10/NI120/NP7 OV-225: FP15/NI300 fuberidazole C11H8N2O 0.71 - 0.95 C - - - - Responses: OV-101: HN(WB)0.5/NP(WB)3 OV-17: NP5.5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–33 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries furilazole C11H13Cl2NO3 0.46 0.6 0.39 C S - 50 3 Responses: OV-101: NI1.5/NP50 OV-17: NI1/NP1.8 OV-225: NI1.6 G-27550 C8H12N2O 0.28 - 0.29 C - - - - Responses: OV-101: NP3 OV-17: NP3 Gardona C10H9Cl4O4P 1.58 2.72 1.97 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP9/TI8 OV-17: FP10/FP(WB)3 GS-31144 C8H12N2O2 - - - - NR NR 6-15-50 1-2-3 Responses: OV-101: NI220/NP100 OV-17: NI750/NP100 haloxyfop methyl ester C16H13ClF3NO4 1.55 - 1.4 - - - - - Responses: OV-101: HX(WB)9/NI5 OV-17: HX(WB)6/NI4.5 heptachlor C10H5Cl7 0.83 0.52 0.6 C C C 6 1 Responses: OV-101: NI0.6 OV-17: NI0.4 heptachlor epoxide C10H5Cl7O 1.29 1.22 1.15 C C C 6 2 Responses: OV-101: HX0.7/TR1 OV-17: HX0.9/NI2 heptachloronorbornene C7H3Cl7 - - 0.23 - - - - - Responses: OV-17: NI0.2 heptenophos C9H12ClO4P - - - C - - - - Responses: hexachlorobenzene C6Cl6 0.45 0.25 0.33 C C P 6 1 Responses: OV-101: HX0.5/NI0.25 OV-17: HX0.3/NI0.3 OV-225: NI0.3 hexachlorobutadiene C4Cl6 - - 0.04 - V # P 6 1 Responses: OV-17: NI0.1 hexachlorocyclopentadiene C5Cl6 0.12 - 0.06 - - - - - Responses: OV-101: TR0.4 OV-17: NI0.8 hexachloroethane C2Cl6 - - 0.02 - - - - - Responses: OV-17: NI0.1 hexachloronorbornadiene C7H2Cl6 - - 0.12 - - - - - Responses: OV-17: NI0.2 hexachlorophene C13H6Cl6O2 13 13 16 - NR NR 6-15-50 - Responses: OV-101: NI(WB)2 OV-17: NI400 OV-225: NI1200 hexachlorophene dimethyl ether C15H10Cl6O2 9.7 - - - NR NR 6-15 - Responses: OV-101: TR7 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–34 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries hexaconazole C14H17Cl2N3O 1.86 2.91 1.79 C - - - - Responses: OV-101: HX6/NI3 OV-17: NP(WB)23 hexazinone C12H20N4O2 2.91 - - P NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)3/NP(WB)15 hexythiazox C17H21ClN2O2S 1.28 - 2.41 - S # NR 50 2+3 Responses: OV-101: NI(WB)70/NP(WB)90 OV-17: FS(WB)90/NI(WB)80/NP(WB)80 HOE-030291 C17H16Cl2O5 7.9 10.8 12.6 - - - - - Responses: OV-101: NI20 OV-17: NI70 OV-225: NI20 hydramethylnon* C25H24F6N4 2.55 - - - - - - - 32 4.5 - 44 53 - Responses: OV-101: NI(V)250 hydroxy chloroneb C7H6Cl2O2 0.15 0.24 - - NR - 6-15 - Responses: OV-101: TR7 imazalil C14H14Cl2N2O 1.76 4 2.08 C NR NR 6-15-50 - Responses: OV-101: NI30/NP(WB)12 OV-17: HX19/HX(WB)2/NI(WB)5/NP(WB)10 imazamethabenz methyl ester* C16H20N2O3 - - 2.44 C - - - - 1.79 3.5 2.76 Responses: OV-101: HX540/HX(WB)50/NI45/NP(WB)40 OV-17: HX60 imazethapyr ammonium salt methyl C16H21N3O3 2.4 4.3 3 - - - - - ester Responses: OV-101: NI120/NP50 OV-17: NI120/NP70 OV-225: NI160 imidacloprid C9H10ClN5O2 1.84 - - - NR NR 6-15-50 1-2-3 Responses: OV-101: NI200/NP50 IN-A3928 C11H18N4O2 3.06 - - S NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)1.4/NP(WB)29 IN-B2838 C10H15N3O3 0.7 - 0.8 P NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)0.6/NP(WB)23 OV-17: HN(WB)0.2/NP(WB)13 IN-T3935 C11H18N4O3 4.7 - - S - - - - Responses: OV-101: HN(WB)73/NI(WB)230 IN-T3936 C10H15N3O4 1.41 - 2.55 S NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)1.6/NP(WB)51 OV-17: HN(WB)1.2/NP(WB)53 IN-T3937 C12H20N4O3 4.7 - - S - - - - Responses: OV-101: HN(WB)390/NI(WB)400 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–35 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries ioxynil methyl ether C8H5I2NO 0.71 - - - - - - - Responses: OV-101: HN(WB)5/NI1 iprobenfos C13H21O3PS 0.6 - 0.54 C - - - - Responses: OV-101: FP(WB)1 OV-17: FP2 iprodione metabolite isomer C13H13Cl2N3O3 5.3 - 7.5 C S - 50 - Responses: OV-101: HX(WB)20/NI1000 OV-17: HX80 iprodione* C13H13Cl2N3O3 - - 5.2 C S # NR 50 1-2-3 4.2 18 6.3 Responses: OV-101: HX13/NI15/NP15 OV-17: HX20/NI35/NP200 OV-225: NI75 isazofos C9H17ClN3O3PS 0.55 0.8 0.63 C C # - 50 2+3 Responses: OV-101: NI30/NP0.4 OV-17: FP(WB)1/NI10/NP0.2 OV-225: NI20 isocarbamid C8H15N3O2 0.44 - 0.82 C - - - - Responses: OV-101: HN(WB)0.2/NP(WB)0.5 OV-17: NP7 isofenphos C15H24NO4PS 1.36 1.73 1.38 C C - 15+50 - Responses: OV-101: FP2/NI20 OV-17: FP2 isofenphos oxygen analog C15H24NO5P 1.17 1.74 1.24 C - - - - Responses: OV-101: FP10 OV-17: FP7 OV-225: FP5 isopropalin C15H23N3O4 1.14 1.24 1.01 C C - 6 - Responses: OV-101: NI2/NP3 OV-17: NI3/NP15 OV-225: NI2 isoprothiolane C12H18O4S2 1.6 4.1 3.17 C - - - - Responses: OV-101: FS(WB)10/NI(WB)3 isoproturon C12H18N2O - - 0.89 S - - - - Responses: OV-17: NP(WB)10 isoxaflutole (prop) C15H12SNO4F3 1.11 4.7 1.33 NR V # S # 50 3 Responses: OV-101: NI40/NP100 OV-17: NI40/NP200 OV-225: NI40 jodfenphos C8H8Cl2IO3PS - - 2.11 C - - - - Responses: OV-17: FP7 kresoxim-methyl C18H19NO4 2 3.02 3.38 P C C 15+50 3 Responses: OV-101: NI(WB)10/NP(WB)50 OV-17: NI(WB)15/NP(WB)40 OV-225: NI(WB)10 KWG 1323 C14H16ClN3O3 0.99 1.91 0.96 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI3/NP35 OV-17: NI1/NP5 OV-225: NI3/NP65 KWG 1342 C14H18ClN3O3 4 15 4.2 - - - - - Responses: OV-101: NI1000/NP1000 OV-17: NI200/NP50 OV-225: NP1000 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–36 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries lactofen C19H15ClF3NO7 7.3 - - - - C 50 2+3 Responses: OV-101: NI10 lambda-cyhalothrin C23H19ClF3NO3 7.4 - 8 C - - - - Responses: OV-101: NI10 OV-17: HX30 leptophos C13H10BrCl2O2PS 5.8 7.7 8.5 C C C 6 2 Responses: OV-101: FP14/TI20/TR11 OV-17: FP(WB)15/NI12 leptophos oxygen analog C13H10BrCl2O3P 4.2 7.6 6.5 C - - - - Responses: OV-101: FP60/TI65 leptophos photoproduct C13H11Cl2O2PS 2.38 3.24 3.14 C - - - - Responses: OV-101: NI(WB)2/TI5 OV-17: NI5 OV-225: NI5 lindane C6H6Cl6 0.48 0.69 0.47 C C C 6 1 Responses: OV-101: HX0.6/TR0.5 OV-17: NI0.4 linuron C9H10Cl2N2O2 0.85 2.13 0.95 V V # V 50 3 Responses: OV-101: TR28 malathion C10H19O6PS2 0.91 1.49 1.05 C C C 15+50 3 Responses: OV-101: NI(WB)7/NP1 OV-17: FP3/NI7 OV-225: NI44 malathion oxygen analog C10H19O7PS 0.68 1.55 0.87 C NR NR 6-15-50 1-2-3 Responses: OV-101: TI7 OV-17: FP5 MB45950 C12H4SN4F6Cl2 1.25 8 1.09 S P V 15+50 2+3 Responses: OV-101: NI2/NP8 OV-17: NI1/NP6 OV-225: NI6 MB46136 C12H4SO2N4F6Cl2 2.06 31 1.98 S S V 50 2+3 Responses: OV-101: NI2/NP30 OV-17: NI2/NP10 OV-225: NI30 MCPA methyl ester C10H11ClO3 0.19 - - - - - - - Responses: OV-101: HX(WB)2/NI600 mecarbam C10H20NO5PS2 1.28 2.67 1.58 C - 50 - Responses: OV-101: FP(WB)1.7/NI5 OV-17: FP3/FP(WB)1.9 OV-225: HN4 mecoprop methyl ester C11H13ClO3 0.19 - - - - - - - Responses: OV-101: HX(WB)2/NI30 melamine C3H6N6 0.42 - 0.42 NR - - - - Responses: OV-101: NP100 OV-17: NP9 mephosfolan C8H16NO3PS2 - - 2.51 C - - - - Responses: OV-17: FP3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–37 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries merphos* C12H27PS3 1.34 0.65 1.43 - C C 6+15+50 3 1.95 1.64 1.88 Responses: OV-101: FP3/TI5 OV-17: FP25 metalaxyl C15H21NO4 0.81 - 0.9 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX1000/NI1000/NP7 OV-17: NI1000/NP50 metamitron C10H10N4O 2.24 - - - - - - - Responses: OV-101: NI20 metasystox thiol C6H15O3PS2 0.28 0.49 0.32 C - - - - Responses: OV-101: FP(WB)8 OV-17: FP(WB)0.8 metasystox thiono* C6H15O3PS2 - - 0.18 - - - - - 0.31 0.49 0.32 Responses: OV-101: FP6 OV-17: FP(WB)2 metazachlor C14H16ClN3O 1.5 - 1.46 C - - - - Responses: OV-101: NI34 OV-17: HX5/NP4 methabenzthiazuron C10H11N3OS 0.35 0.7 0.41 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)0.5/NI320/NP15 OV-17: NP24 OV-225: NI2550 methamidophos C2H8NO2PS 0.07 0.25 0.09 V - - - - Responses: OV-101: FP(WB)0.7 OV-17: FP1/FP(WB)0.6 OV-225: FP4 methazole C9H6Cl2N2O3 0.97 1.46 - - - - - - Responses: OV-101: HX13/NI40 methidathion C6H11N2O4PS3 1.4 3.33 2.28 C S P # 50 3 Responses: OV-101: FP5/FP(WB)1.6/NP3 OV-17: FP(WB)2.4/NI10 OV-225: NI50 methidathion oxygen analog C6H11N2O5PS2 1.07 - 1.8 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI100/NP40 OV-17: FP125/NI200/NP40 methidathion sulfone C5H8N2O3S2 0.56 2.29 0.82 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI150/NP100 OV-17: NI200/NP35 OV-225: NI400 methidathion sulfoxide C5H8N2O4S2 0.45 2.25 0.71 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI8/NP35 OV-17: NI8/NP10 OV-225: NI30 methiocarb C11H15NO2S 0.88 - - C - - - - Responses: methiocarb sulfone C11H15NO4S 0.8 - 1.17 S NR NR 6-15-50 1-2-3 Responses: OV-101: NI200/NP200 methomyl C5H10N202S 0.1 - - - NR NR 6-15-50 1-2-3 Responses: OV-101: NI220 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–38 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries methoprotryne C11H21N5OS 2.07 - 2.92 C - - - - Responses: OV-101: NP189 OV-17: NP(WB)8 methoxychlor olefin C16H14Cl2O2 2.97 3.7 4.2 C C C 6 2 Responses: OV-101: NI(WB)8 OV-17: NI10 OV-225: NI9 methoxychlor, o, p'- C16H15Cl3O2 3.3 4.5 5 - C - 6 - Responses: OV-101: NI(WB)2 OV-17: NI9 OV-225: NI23 methoxychlor, p, p'- C16H15Cl3O2 4.7 7.2 7.2 C C C 6 2 Responses: OV-101: TR9 OV-17: NI7 methyl 2,3,5-triiodobenzoate C8H5I3O2 2.28 - - - - - - - Responses: OV-101: NI1.5 methyl 2,3,6-trichlorobenzoate C8H5Cl3O2 0.23 0.21 0.18 - - - - - Responses: OV-101: TR0.6 OV-17: NI0.3 methyl 3,5-dibromo-4-methoxy= C9H8Br2O3 0.56 0.49 0.47 - - - - - benzoate Responses: OV-101: NI(WB)2 OV-17: NI(WB)1 OV-225: NI(WB)1.5 methyl 4-chloro-1H-indole-3-acetate C11H10ClNO2 1.17 - - R R # NR 50 1-2-3 Responses: OV-101: MC25/NI200 metobromuron C9H11BrN2O2 0.67 1.44 0.69 C NR NR 6-15-50 1-2-3 Responses: OV-101: HX8/NI5 OV-17: HX10 metolachlor C15H22ClNO2 1.03 1.21 0.93 C S # NR 50 1-2-3 Responses: OV-101: HX5/NI12 OV-17: HX7 OV-225: NI9 metolcarb C9H11NO2 0.17 - - C - - - - Responses: metoxuron C10H13ClN2O2 - - 0.18 V NR NR 6-15-50 1-2-3 Responses: OV-17: HX25 metribuzin C8H14N4OS 0.57 1.47 0.91 V NR NR 50 1-2-3 Responses: OV-101: NI0.5/NP2 OV-17: NI0.4/NP11 OV-225: NI0.7 metribuzin, deaminated diketo C7H11N3O2 0.5 0.79 0.44 NR NR NR 6-15-50 1-2-3 metabolite* 0.73 1.29 0.52 Responses: OV-101: NI75 OV-17: NI150 OV-225: NI160 metribuzin, deaminated metabolite C8H13N3OS 0.83 3.77 1.06 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI60/NP45 OV-17: NI10/NP125 OV-225: NI60 metribuzin, diketo metabolite C7H12N4O2 0.56 1.41 0.55 NR NR NR 6-15-50 1-2-3 Responses: OV-101: NI35/NP40 OV-17: NI6/NP20 OV-225: NI15 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–39 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries mevinphos, (E)- C7H13O6P 0.16 - 0.13 C NR NR 6-15-50 - Responses: OV-101: FP2 OV-17: FP2 mevinphos, (Z)- C7H13O6P 0.13 - 0.15 C NR - 6-15-50 - Responses: OV-101: FP2/FP(WB)1 OV-17: FP2/FP(WB)0.6 MGK 264 C17H25NO2 1.6 - - - - - - - Responses: mirex C10Cl12 5.8 2.95 5.6 P C P 6 1 Responses: OV-101: NI7 OV-17: NI4 mirex, 5,10-dihydro-* C10H2Cl10 2.14 - - - - - - - 2.47 - - 3.21 - - 4.3 - - Responses: OV-101: NI100 molinate C9H17NOS - 0.19 - - - - - - Responses: monocrotophos C7H14NO5P 0.31 1.6 0.5 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP(WB)0.7/TI15 OV-17: FP2/FP(WB)0.8 OV-225: FP3 monolinuron C9H11ClN2O2 0.48 0.91 0.48 C - - - - Responses: OV-101: HX4 OV-17: HX18 OV-225: NI180 monuron C9H11ClN2O 0.1 - - - NR NR 6-15-50 1-2-3 Responses: OV-101: TR175 myclobutanil C15H17ClN4 1.9 7.2 2.6 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)0.7/NI25/NP(WB)7 OV-17: HX10/HX(WB)4/NI(WB)21/NP75/NP(WB)6 myclobutanil alcohol metabolite C15H17ClN40 3.6 37.1 7.5 S NR NR 6-15-50 1-2-3 Responses: OV-101: NI60 OV-17: NP375 myclobutanil dihydroxy metabolite C15H17N4O2Cl 6.5 - 11.5 NR NR NR 6-15-50 1-2-3 Responses: OV-17: NI1000/NP1000 N, N-diallyl dichloroacetamide C8H11Cl2NO 0.19 0.22 0.14 C S S 15+50 2+3 Responses: OV-101: HX1/NI1/NP1 OV-17: NI1 OV-225: NI1 N-(3,4-dichlorophenyl)-N'-methyl= C8H8Cl2N2O 0.17 0.14 0.1 - NR NR 6-15-50 - urea Responses: OV-101: HX20/NI9 OV-17: NI5 OV-225: NI12 n-acetyl nitrofen C14H11Cl2NO2 6.6 - - - - - - - Responses: OV-101: TR500 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–40 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries naled C4H7Br2Cl2O4P 0.34 - 0.32 C NR NR 6-15-50 1-2-3 Responses: OV-101: NP11 OV-17: FP20/NI8 napropamide C17H20NO2 1.7 - 2.12 C - - - - Responses: OV-101: NP40 neburon C12H16Cl2N2O 0.11 - - C NR NR 6-15-50 1-2-3 Responses: OV-101: TR25 nitralin C13H19N3O6S 3.8 24 6.3 C P P 50 3 Responses: OV-101: NI(WB)1 OV-17: NI7 OV-225: NI21 nitrapyrin C6H3Cl4N 0.2 0.18 0.2 C C V 6 2 Responses: OV-101: HX2/NI(WB)0.8/NP(WB)4 OV-17: HX(WB)0.6 OV-225: NI0.9 nitrofen C12H7Cl2NO3 2.03 3.8 2.71 C C C 15 2 Responses: OV-101: NI(WB)1 OV-17: NI3 OV-225: NI3 nitrofluorfen C13H7ClF3NO3 0.96 1.45 0.86 C C C 15 2 Responses: OV-101: HX5/NI1 OV-17: HX3 OV-225: NI1.5 nitrothal-isopropyl C14H17O6N 1.1 - 0.68 C - - - - Responses: OV-101: NI(WB)2 OV-17: NP(WB)65 nonachlor, cis- C10H5Cl9 2.52 3.33 2.61 C C C 6 1 Responses: OV-101: HX1/NI2 OV-17: NI2 OV-225: NI3 nonachlor, trans- C10H5Cl9 1.75 1.45 1.42 C C C 6 1 Responses: OV-101: TR2 OV-17: HX0.4/NI0.8 norea C13H15N2O - - 1.05 C - - - - Responses: OV-17: NP(WB)8 norflurazon C12H9ClF3N3O 4.5 - 5.01 V NR NR 6-15-50 - Responses: OV-101: HX50 OV-17: NP(WB)10 NTN33823 C9H11N4Cl 3 - 1.18 - NR NR 6-15-50 1-2-3 Responses: OV-101: NP300 OV-17: NP1000 NTN35884* C9H9N5O2Cl 1.59 - - - NR NR 6-15-50 1-2-3 5- Responses: OV-101: NI550/NP210 nuarimol C17H12ClFN2O 3.36 7.3 4.8 C NR C # 50 1-2-3 Responses: OV-101: NI5 OV-17: HX4 octachlor epoxide C10H4Cl8O 1.33 0.94 1.05 C C C 6 1 Responses: OV-101: TR1 OV-17: NI0.6 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–41 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries octachlorocyclopentane C5Cl8 - - 0.22 - - - - - Responses: OV-17: NI0.2 octhilinone C11H19NOS 0.66 - 0.64 C - - - - Responses: OV-101: FS4 ofurace C14H16NO3Cl 2.62 18.6 5.4 C - - - - Responses: OV-101: HX17 OV-17: HX51 OV-225: NI44 omethoate C5H12NO4PS 0.25 1.11 0.39 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP(WB)0.9/TI25 OV-17: FP5/FP(WB)1.1 OV-225: FP5 oryzalin C12H8N4O6S 4.7 - - - NR NR 6-15-50 - Responses: OV-101: NI8800 ovex C12H8Cl2O3S 1.61 3.04 2.2 C C C 15 2 Responses: OV-101: HX4/TR3 OV-17: HX5 OV-225: NI3 oxadiazon C15H18Cl2N2O3 1.97 2.48 1.96 C C P 15 - Responses: OV-101: HX4/NI4 OV-17: NI2 oxadixyl C14H18N2O4 2.5 14 5 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI1700/NP8 OV-17: NP14 OV-225: NI4500 oxamyl C7H13N3O3S - - - - - - - - Responses: oxamyl oxime metabolite C5H10N2O2S 0.25 0.92 0.28 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)0.5/NI(WB)4/NP(WB)4 OV-17: HN(WB)0.4/NI(WB)3/NP(WB)3 OV-225: NI(WB)13 oxycarboxin C12H13NO4S 3.28 - 9.4 R - - - - Responses: OV-101: FS(WB)17/HN(WB)3/NP(WB)130 OV-17: HN(WB)4 oxydemeton-methyl C6H15O4PS2 0.46 0.49 0.31 C - - - - Responses: OV-17: FP(WB)4 oxydemeton-methyl sulfone C6H15O5PS2 0.72 - 1.48 C - - - - Responses: OV-101: FP(WB)2 OV-17: FP(WB)3 oxydeprofos C7H17O4SP - - - - - - - - Responses: oxyfluorfen C15H11ClF3NO4 2 4 2.16 C C C 15 2 Responses: OV-101: NI5 OV-17: HX9/NI2/NP350 oxythioquinox C10H6N2OS2 1.57 - 1.85 C - - - - Responses: OV-101: NI(WB)1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–42 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries paclobutrazol C15H20ClN3O 1.52 - 1.59 C - - - - Responses: OV-101: NP(WB)6 OV-17: HX7/HX(WB)3/NI(WB)85/NP(WB)5 parathion C10H14NO5PS 0.98 1.91 1.07 C C C 15 2 Responses: OV-101: NI(WB)4/NP2 OV-17: FP2/NI4 OV-225: FP2/NI6 parathion oxygen analog C10H14NO6P 0.8 - 0.86 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)5/NP3 OV-17: FP4/NI15 parathion-methyl C8H10NO5PS 0.71 1.64 0.87 C C C 15 2 Responses: OV-101: FP(WB)0.9/NI(WB)3/NP1.5 OV-17: FP2/FP(WB)1/NI3 OV-225: FP1/NI11 parathion-methyl oxygen analog C8H10NO6P 0.55 1.71 0.66 - NR NR 6-15-50 1-2-3 Responses: OV-101: TI5/TR11 OV-17: FP10 PB-7, methylated C20H25ClN2O3S 23 57 43 - - - - - Responses: OV-101: NI150/NP300 OV-17: NI200/NP500 OV-225: NI300 PB-9 C19H25ClN2O2S 25 87 46 V NR NR 6-15-50 1-2-3 Responses: OV-101: NI300/NP500 OV-17: NI250/NP750 OV-225: NI500 pebulate C10H21NOS 0.17 - 0.1 C P - 15 - Responses: OV-101: HN(WB)0.4/NP7 OV-17: NP6 penconazole C13H15Cl2N3 1.24 - 1.32 C - - - - Responses: OV-101: NP(WB)3 OV-17: HX3/HX(WB)2/NI(WB)2/NP(WB)3 pendimethalin C13H19N3O4 1.22 1.48 1.21 C C P 15 2 Responses: OV-101: NI3/NP5 OV-17: NI1.5/NP6 OV-225: NI3 pentachloroaniline C6H2Cl5N 0.67 0.79 0.66 C C C 6 1 Responses: OV-101: HX0.5/NI0.4/NP10 OV-17: NI0.6/NP10 OV-225: NI0.5 pentachlorobenzene C6HCl5 0.24 0.13 0.16 C C C 6 1 Responses: OV-101: HX0.3/NI0.25 OV-17: NI0.3 OV-225: NI0.25 pentachlorobenzonitrile C7Cl5N 0.5 0.59 0.45 C C P 15 2 Responses: OV-101: NI0.5 OV-17: NI3 pentachlorophenyl methyl ether C7H3Cl5O 0.46 0.3 0.34 C C C 6 1 Responses: OV-101: HX0.4/TR0.4 OV-17: NI0.3 pentachlorophenyl methyl sulfide C7H3Cl5S 0.94 0.69 0.87 C C C 6 1 Responses: OV-101: HX0.7/NI0.4 OV-17: NI3 OV-225: NI0.5 permethrin, cis- C21H20Cl2O3 9.4 11.1 13.8 C V # C 6+15 2 Responses: OV-101: NI75 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–43 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries permethrin, trans- C21H20Cl2O3 10.2 13 15 C V # C 6+15 2 Responses: OV-101: NI100 Perthane C18H2OCl2 2.23 2.01 2.42 C C C 6 1 Responses: OV-101: TR150 OV-17: NI25 Perthane olefin C18H19Cl 1.53 0.95 - - C C 6 1 Responses: OV-101: TR40 phenmedipham C16H16N2O4 0.32 - 0.41 - - - - - Responses: OV-101: HN(WB)1.5 OV-17: NP40 phenothiazine C12H9NS 1.16 - 1.56 - - - - - Responses: OV-101: HN(WB)1.4 OV-17: NP4 phenothrin* C23H26O3 5.4 4.8 6.5 - - - - - 11.5 10.9 15 Responses: OV-101: NI500/NI(WB)40 phenthoate C12H17O4PS2 1.31 2.05 1.83 C C - 15+50 - Responses: OV-101: FP(WB)2/NI5/TI3 OV-17: FP2/FP(WB)2.6/NI5 phorate C7H17O2PS3 0.37 0.38 0.32 C V # V # 6 1 Responses: OV-101: FP1/NI(WB)24/TI1 OV-17: FP0.5/NI14 OV-225: FP0.5/NI17 phorate oxygen analog C7H17O3PS2 0.3 0.37 0.29 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI400/TI2 OV-17: FP1 OV-225: FP0.5 phorate oxygen analog sulfone C7H17O5PS2 0.66 - 1.02 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP1/TI10 OV-17: FP6 phorate oxygen analog sulfoxide C7H17O4PS2 0.78 - 1.06 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI300 OV-17: FP40 phorate sulfone C7H17O4PS3 0.97 3.26 1.3 C S # S # 6-15-50 3 Responses: OV-101: NI4/TI4 OV-17: FP2 phorate sulfoxide C7H17O3PS3 0.89 2.55 1.26 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP5/NI8/NP4 OV-17: FP6 phosalone C12H15ClNO4PS2 5.5 5.5 9.1 C C C 50 2+3 Responses: OV-101: NP10/TR15 OV-17: NI12 phosalone oxygen analog C12H15ClNO5PS 3.8 - 6.2 C - - - - Responses: OV-101: FP600/FP(WB)8/NI160 OV-17: FP(WB)12 phosfolan C7H14NO3PS2 - - 2.69 C - - - - Responses: OV-17: FP5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–44 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries phosmet C11H12O4NPS2 4 14.9 8.4 C NR - 6-15-50 3 Responses: OV-101: NI(WB)2/NP19 OV-17: FP50/NI78 OV-225: FP50 phosmet oxygen analog* C11H12NO5PS 0.5 0.53 0.24 - NR NR 6-15-50 - 2 0.93 0.44 3.1 14.8 7.1 Responses: OV-101: NI900/NP100 OV-17: FP150 OV-225: NI600 phosphamidon* C10H19ClNO5P 0.53 - 0.57 C NR NR 6-15-50 1-2-3 0.67 - 0.76 Responses: OV-101: FP10 OV-17: FP2 photodieldrin C12H8Cl6O 4.4 15.5 8.5 - C C 15+50 2 Responses: OV-101: TR6 OV-17: NI5 photodieldrin B C13H9Cl5O 1.43 - - - - - - - Responses: OV-101: TR2 phoxim oxygen analog C12H15N204P 0.86 - - C - - - - Responses: OV-101: FP5 picloram methyl ester C7H5Cl3N2O2 0.75 2.67 - - - - - - Responses: OV-101: HX(WB)1.2/NI1.5/TR1 picloram* C6H3Cl3N2O2 0.25 - - - - - - - 0.67 - - Responses: OV-101: NI100 piperophos C14H28NO3PS2 4.8 9.7 6.8 C - - - - Responses: OV-101: FP15 pirimicarb C11H18N4O2 0.61 - 0.73 C - - - - Responses: OV-17: FP(WB)2 pirimiphos-ethyl C13H24N3O3PS 1.14 1.03 1.14 C C C 15+50 3 Responses: OV-101: FP2/TI4/TR150 OV-17: FP3/NI4 pirimiphos-ethyl oxygen analog C13H24N3O4P 1.01 - 1.14 C - - - - Responses: OV-101: FP4/FP(WB)1.6 OV-17: FP(WB)2.4 pirimiphos-methyl C11H20N3O3PS 0.87 - 0.92 C C C 15 3 Responses: OV-101: FP2/FP(WB)1.2/NI100/NP2 OV-17: FP2/FP(WB)1.2 PP 890 C9H10O2ClF3 1.05 1 - - - - - - Responses: OV-101: NI220 OV-225: NI150 PPG-1576 C19H17ClF3NO5 6.7 - - - - P 50 2+3 Responses: OV-101: NI13 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–45 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries PPG-2597 C20H17ClF3NO6 1.9 3.16 1.86 - NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)58/HX(WB)110/NI(WB)85/NP(WB)150 OV-17: HN(WB)120/HX(WB)66/NI(WB)78 OV-225: NI(WB)120 PPG-847, methylated C15H9ClF3NO3 2.15 5 2.4 - - - - - Responses: OV-101: HN(WB)3/HX(WB)10/NI(WB)3/NP(WB)34 OV-17: HN(WB)4/HX(WB)6.5/NI(WB)3/NP(WB)210 OV-225: NI(WB)4 PPG-947 C17H11ClF3NO7 1.04 - 1.13 - NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)620/NI(WB)1000 OV-17: NI(WB)600 PPG-947, methylated* C18H13ClF3NO7 0.42 0.97 0.49 - - - - - 2.14 5 2.4 Responses: OV-101: HN(WB)5/NI(WB)5/NP(WB)65 OV-17: HN(WB)5 OV-225: NI(WB)6 pretilachlor C17H26ClNO2 1.88 - 1.99 C - - - - Responses: OV-101: NI25 OV-17: HX10 probenazole C10H9NO3S - - - C - - - - Responses: prochloraz C15H16Cl3N3O2 10.4 - 15.4 C - - - - Responses: OV-101: HX50/NI12 procyazine C10H13ClN6 1.5 7.9 - C - - - - Responses: procymidone C13H11Cl2NO2 1.37 3.04 1.49 C C P 15 - Responses: OV-101: NI12 OV-17: HX1 OV-225: NI7 prodiamine C13H17F3N4O4 0.94 0.97 0.66 C - - - - Responses: OV-17: NP(WB)50 OV-225: NP50 profenofos C11H15BrClO3PS 1.8 2.34 2.13 C P P 50 3 Responses: OV-101: FP7/FP(WB)2.6/NI3 OV-17: FP5/FP(WB)2.9 profluralin C14H16F3N3O4 0.53 0.46 0.3 V V - 6 - Responses: OV-101: HX5/NI1/NP1 OV-17: NI0.8/NP9 OV-225: NI1 Prolan C15H13Cl2NO2 2.81 7.5 3.9 P S S 15 2 Responses: OV-101: NI(WB)1 OV-17: NI6 OV-225: NI10 promecarb C12H17NO2 1.58 - - V - - - - Responses: OV-101: TI400 prometryn C10H19N5S 0.77 - 0.74 C P # P # 50 1-2-3 Responses: OV-101: FP200/NI40/TI50 OV-17: FP20 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–46 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries pronamide C12H11Cl2NO 0.51 0.84 0.4 C P - 15+50 - Responses: OV-101: HX1/NI2/NP7 OV-17: NI1/NP85 OV-225: NI3 propachlor C11H14ClNO 0.34 0.37 0.26 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI(WB)16/NP(WB)13 OV-17: NI5/NI(WB)5 OV-225: NI9/NI(WB)5 propanil C9H9Cl2NO 0.66 2.82 0.78 C NR NR 6-15 3 Responses: OV-101: HX6/NI3/NI(WB)5 OV-17: NI4 OV-225: NI8 propargite C19H26O4S 3.8 4.8 4.3 C C - 15 2 Responses: OV-101: FS45/NI(WB)230 OV-17: NI2600 OV-225: NI1300 propazine C9H16ClN5 0.53 0.65 0.41 C S NR 15+50 3 Responses: OV-101: NI(WB)110/TI30 OV-17: NI43 OV-225: NI37 propetamphos C10H20NO4PS 0.48 - 0.42 C C # - 15+50 2+3 Responses: OV-101: FP1.5 OV-17: FP0.5 propham C10H13NO2 0.13 - 0.12 C P P 15 - Responses: OV-101: NP(WB)2 OV-17: NP16 propiconazole* C15H17Cl2N3O2 3.06 - - C NR NR 6-15-50 1-2-3 3.21 5.6 4 Responses: OV-101: NI10/NI(WB)17 OV-17: HX9 propoxur C11H15NO3 - - - C - - - - Responses: prosulfuron* C15H16F3N5O4S 0.18 - - - NR NR 6-15-50 1-2-3 0.44 2.49 0.64 Responses: OV-101: NP8 OV-17: NI120 OV-225: NI20 prothiofos C11H15Cl2PO2S2 1.85 1.74 1.82 C C C 6 2 Responses: OV-101: FP4/NI3/NP3 OV-17: NI3 OV-225: NI1 prothoate C9H20NO3PS2 0.75 1.55 0.79 C - - - - Responses: OV-101: FP1/NI5 pyracarbolid C13H15NO2 1.05 - 1.43 - - - - - Responses: OV-101: HN(WB)1.4 OV-17: NP6 pyrazon C10H8ClN3O 2.67 13 8 C NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)8/HX(WB)30/NI(WB)26/NP(WB)56 OV-17: HX(WB)50 OV-225: NI3700 pyrazon metabolite A C16H18ClN3O6 2.62 - - - - - - - Responses: OV-101: HX(WB)260 pyrazon metabolite B C6H4ClN3O 0.42 - 0.9 - NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)3/HX(WB)42/NI(WB)35/NP(WB)14 OV-17: HN(WB)3/HX(WB)23/NI(WB)23/NP(WB)44 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–47 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries pyrazophos C14H20N3O5PS 8.1 - 13 C - - - - Responses: OV-101: FP(WB)12 OV-17: FP25 pyrethrins* C21H27O4 2.12 1.76 1.76 - C C 50 - 2.95 2.84 2.7 Responses: OV-101: NI25 pyridaphenthion C14H17O4N2SP 4.2 14 8.7 C - - - - Responses: OV-101: NI(WB)16 pyrimethanil C12H13N3 0.67 - - C S S # 50 3 Responses: OV-101: NP(WB)0.5 pyrithiobac-sodium methyl ester C14H13ClN2O4 2.51 4 4.2 - - - - - Responses: OV-101: HN(WB)1/HX(WB)12/NI(WB)9/NP(WB)90 OV-17: HN(WB)2/HX(WB)13/NI(WB)18/NP(WB)85 OV-225: NI(WB)13 quinalphos C12H15N2O3PS 1.32 2 1.64 C C - 15 - Responses: OV-101: FP5/FP(WB)2.7 OV-17: FP3/FP(WB)3 quintozene C6Cl5NO2 0.51 0.46 0.46 C C C 6 1 Responses: OV-101: TR0.3 OV-17: NI0.5 quizalofop ethyl ester C19H17ClN2O4 13.6 - 25 C - - - - Responses: OV-101: HX70/NI80 RH-6467* C19H15N4ClO 7.9 - - S NR NR 6-15-50 1-2-3 10.4 - - 15 - - Responses: OV-101: NI90/NP300 RH-9129 C19H16N3ClO2 14 - - V NR NR 6-15-50 1-2-3 Responses: OV-101: NI40/NP190 RH-9130 C19H16N3ClO2 12 - - P NR NR 6-15-50 1-2-3 Responses: OV-101: NI50/NP170 ronnel C8H8Cl3O3PS 0.81 0.86 0.76 C C C 6 2 Responses: OV-101: NI(WB)1/TI3 OV-17: FP1/NI1 OV-225: NI2 ronnel oxygen analog C8H8Cl3O4P 0.64 1.02 0.62 C NR - 6-15-50 - Responses: OV-101: NP3 OV-17: FP5/FP(WB)1 RPA 203328, methylated C10H9F3O4S 0.26 0.51 0.23 - - - - - Responses: OV-101: NI0.5 OV-17: NI0.4 OV-225: NI0.5 5 RPA202248 C15H12SNO4F3 1.13 4.7 1.38 NR NR NR 6-15-50 1-2-3 Responses: OV-101: NI40/NP120 OV-17: NI40/NP250 OV-225: NI60 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–48 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries S-bioallethrin C19H26O3 1.37 1.22 1.12 - C - 50 - Responses: OV-101: NI2 OV-17: NI2 OV-225: NI2 schradan C8H24N4O3P2 0.58 - 0.52 C NR - 6-15-50 - Responses: OV-101: FP4/TI5 OV-17: FP1 sethoxydim C17H29NO3S 3.34 - - - NR NR 6-15-50 3 Responses: OV-101: NI50 sethoxydim sulfoxide C17H29NO4S 0.84 - - - NR NR 6-15-50 3 Responses: OV-101: NI50 silvex C9H7Cl3O3 0.48 - - - - - - - Responses: OV-101: NI40 silvex methyl ester C10H9Cl3O3 0.45 0.44 - - - - - - Responses: OV-101: HX(WB)0.8/NI0.6 simazine C7H12ClN5 0.41 0.83 0.5 C NR NR 50 1-2-3 Responses: OV-101: NI(WB)90 OV-17: NI56/NP(WB)1.5 OV-225: NI130 simetryn C8H15N5S 2.02 1.21 - C - - - - Responses: OV-101: NP7 Strobane* C10H11Cl7 1.09 - - - C C 6 1 1.32 - - 1.53 - - 1.8 - - 1.94 - - 2.09 - - 2.33 - - 2.69 - - 3.1 - - 3.7 - - Responses: OV-101: TR40 sulfallate C8H14ClNS2 0.38 0.44 0.36 C C C 6+15 2 Responses: OV-101: NI(WB)1 OV-17: NI1 OV-225: NI1 sulfanilamide C6H8O2N2S - - 2.11 NR NR NR 6-15-50 1-2-3 Responses: OV-17: NP200 sulfotep C8H20O5P2S2 0.34 - 0.29 C C P 6+15 2 Responses: OV-101: TI0.8 OV-17: FP0.5 Sulphenone C12H9ClO2S 1.26 3.5 1.92 C - 50 3 Responses: OV-101: TR4 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–49 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries sulprofos C12H19O2PS3 2.79 - 3.5 C - - - - Responses: OV-101: FP(WB)47 OV-17: FP3 sulprofos oxygen analog sulfone C12H19O5PS2 5.1 - 10.6 C - - - - Responses: OV-101: FP(WB)80 OV-17: FP40/FP(WB)28/NI20/NP40 sulprofos sulfone C12H19O4PS3 7.2 - 13.1 C - - - - Responses: OV-101: FP(WB)16 OV-17: FP(WB)26 sulprofos sulfoxide* C12H19O3PS3 2.78 - 3.6 C - - - - 6.1 - 11.7 Responses: OV-101: FP(WB)14 OV-17: FP(WB)29 TCMTB C9H6N2S3 1.5 4.3 2.67 C P P 15 - Responses: OV-101: NI3/NP22 OV-17: NP36 OV-225: NI12 TDE, o,p'- C14H10Cl4 1.9 2.46 2.19 - C C 6 1 Responses: OV-101: TR2 OV-17: NI2 TDE, o,p'-, olefin C14H9Cl3 1.19 1.15 1.2 - - - - - Responses: OV-101: TR12 OV-17: NI2 TDE, p,p'- C14H10Cl4 2.41 3.8 2.87 C C C 6 1 Responses: OV-101: TR4 OV-17: NI2 TDE, p,p'-, olefin C14H9Cl3 1.45 1.36 1.45 C C C 6 1 Responses: OV-101: NI(WB)4 OV-17: NI4 OV-225: NI3 tebuconazole C16H22ClN3O 3.38 - 4.2 C - - - - Responses: OV-101: HX(WB)1 OV-17: HX(WB)3 tebufenozide C22H28N2O2 7 - 11 - NR NR 6-15-50 1-2-3 Responses: OV-101: NI30/NP4000 tebupirimfos C13H23N2O3PS 0.63 - - - V V 6+15 2+3 Responses: OV-101: NI16/NP1 tebupirimfos oxygen analog C13H23O4N2P 0.51 - - - NR NR 6-15-50 1-2-3 Responses: OV-101: NI100/NP1 tebuthiuron C9H16N4OS 0.26 - 0.21 - - - - - Responses: OV-101: NI1000/NP(WB)0.5 OV-17: FP20 tecnazene C6HCl4NO2 0.29 0.26 0.24 C C C 6 1 Responses: OV-101: TR0.5 OV-17: NI0.3 teflubenzuron* C14H6Cl2F4N2O2 - 0.11 0.09 - NR NR 6-15-50 1-2-3 0.14 0.23 0.14 Responses: OV-101: NI(WB)1.5 OV-17: NP(WB)5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–50 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries TEPP C8H20O7P2 0.21 0.27 0.24 C - - - - Responses: OV-101: FP(WB)46/NI(WB)4000 OV-17: FP(WB)70/NI10000/NP(WB)70 OV-225: NI13700 terbacil C9H13ClN2O2 0.54 2.1 0.72 C NR NR 6-15 2+3 Responses: OV-101: HN(WB)1/HX5/NI(WB)6/NP(WB)8 OV-17: HN(WB)0.6/HX(WB)5/NI(WB)2/NP(WB)8 OV-225: NI(WB)7 terbufos C9H21O2PS3 0.5 0.44 0.41 C P S 6 - Responses: OV-101: FP2/NI40/TI2 OV-17: FP0.5/FP(WB)1.6/NI20 terbufos oxygen analog C9H21O3PS2 0.42 - 0.39 C - NR 6-15-50 1-2-3 Responses: OV-101: FP0.5/NI1000 OV-17: FP1/NI2500 terbufos oxygen analog sulfone C9H21O5PS2 0.92 2.9 1.28 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP7/NI40 OV-17: FP2/NI60 OV-225: FP5/NI1500 terbufos sulfone C9H21O4PS3 1.2 - 1.58 C C # C # 6-15-50 2+3 Responses: OV-101: FP2/NI5 OV-17: FP2/NI10 terbumeton C10H19N5O 0.47 0.42 0.53 C - - - - Responses: OV-17: NP(WB)25 OV-225: NP20 terbuthylazine C9H16N5Cl 0.47 0.71 0.48 C P - 15+50 - Responses: OV-101: NI(WB)87/NP(WB)6 OV-17: NI250 OV-225: NI43 terbutryn C10H19N5S 0.84 1.08 - C - - - - Responses: tetradifon C12H6Cl4O2S 5.2 - 8.3 C C C 15 2 Responses: OV-101: TR6 OV-17: NI5 tetraiodoethylene C2I4 0.55 0.86 1.04 - P P 6 - Responses: OV-101: NI(WB)3 OV-17: NI4 tetramethrin* C19H25NO4 4.3 - - C NR NR 6-15-50 1-2-3 4.5 8.5 7.2 Responses: OV-101: NI50 tetrasul C12H6Cl4S 2.64 2.33 2.8 C C C 6 1 Responses: OV-101: NI(WB)1 OV-17: NI5 OV-225: NI3 tetrasul sulfoxide C12H6Cl4OS 4.7 8.6 7.2 - - - - - Responses: OV-101: NI(WB)1 OV-17: NI8 OV-225: NI7 thiabendazole C10H7N3S 1.48 - 2.04 C NR - 6-15-50 - Responses: OV-101: NP90 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–51 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries thiobencarb C12H16ClNOS 0.94 1 0.98 C V 15 2+3 Responses: OV-101: NI73 OV-17: HX3 thiometon C6H15O2PS3 0.41 0.51 0.4 C NR NR 6-15-50 - Responses: OV-101: NI10/NI(WB)3/TI1 OV-17: FP0.4/NP(WB)1 thionazin C8H13N2O3PS 0.26 - 0.26 C P NR 15+50 - Responses: OV-101: FP0.5/TI1 OV-17: FP0.5 thionazin oxygen analog C8H13N2O4P - - - - - - - - Responses: thiophanate-methyl C12H14N4O4S2 - - - - - - - - Responses: THPI C8H9NO2 0.21 - - C NR NR 6-15-50 - Responses: tolylfluanid C10H13ClFNOS 1.25 - 1.41 C - - - - Responses: OV-101: NI3/NP70 toxaphene* C10H10Cl8 - 2.6 - C C C 6 1 - 2.35 - - 2.14 - - 1.75 - 1.2 2.74 - 1.54 3.05 - 1.8 3.9 - 2.39 4.3 - 2.68 4.5 - 3.12 5.2 - 3.7 5.6 - 4.4 6 - 4.6 6.4 - 5.1 7 - Responses: OV-101: TR30 tralkoxydim* C20H27NO3 3.32 - - V NR NR 50 1-2-3 6.1 1.48 4.5 Responses: OV-101: NI100/NP10 OV-17: NI100 OV-225: NI100 tralomethrin C22H19Br4NO3 27 64 44 C V S 15 2 Responses: OV-101: NI30/NI(WB)1 tri-allate C10H16Cl3NOS 0.6 - 0.45 C C C 6 2 Responses: OV-101: HX1/NI1.5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–52 Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries triadimefon C14H16ClN3O2 1.05 1.64 1 C S # S # 50 1-2-3 Responses: OV-101: HX3/NI2/NP20/NP(WB)2 OV-17: HX5/HX5/HX(WB)3/NI(WB)2/NP2/NP(WB)3 OV-225: NI3/NP20 triadimenol C14H18ClN3O2 1.36 - 1.44 C NR NR 6-15-50 - Responses: OV-101: HX10/NI90/NP30/NP(WB)5 OV-17: HX7/HX(WB)4/NI(WB)50/NP(WB)6 triazamate C13H22N4O3S 1.58 2.46 2.1 C NR NR 6-15-50 1-2-3 Responses: OV-101: NI15/NP25 triazophos C12H16N3O3PS 2.62 - 5.2 C - - - - Responses: OV-101: FP(WB)3 OV-17: FP5/FP(WB)5 tribufos C12H27OPS3 1.95 1.65 1.88 C C P 15+50 3 Responses: OV-101: FP3/NP3/TR4 OV-17: FP3/NI3 tributyl phosphate C12H27O4P 0.3 - 0.23 - R - 50 - Responses: trichlorfon C4H8Cl3O4P 0.16 - 0.13 C NR NR 6-15-50 1-2-3 Responses: OV-101: NP3 OV-17: FP4 trichloronat C10H12Cl3O2PS 1.13 - 0.97 C C - 6 - Responses: OV-101: FP3/HX2/NI2/NP3 triclopyr methyl ester C8H6Cl3NO3 0.36 0.36 0.39 - - - - - Responses: OV-101: NI0.5/NI(WB)0.7/NP(WB)7 tricyclazole C9H7N3S 1.59 - 3.9 C - - - - Responses: OV-101: NP500/NP(WB)8 OV-17: NP500/NP(WB)8 tridiphane C10H7Cl5O 0.81 0.85 0.75 C C - 6 1+2 Responses: OV-101: HX(WB)1/NI0.8 OV-17: HX0.8/HX(WB)0.4 OV-225: NI1 triflumizole C15H15ClF3N3O 1.44 2.23 1.19 C - - - - Responses: OV-101: NP(WB)4 OV-17: HX13/HX(WB)2/NI(WB)3/NP(WB)3 trifluralin C13H16F3N3O4 0.34 0.27 0.17 C C C 6 2 Responses: OV-101: TR1 OV-17: NI0.7 triflusulfuron methyl ester C17H19F3N6O6S 0.3 - 0.2 V NR NR 6-15-50 1-2-3 Responses: OV-101: HN(WB)1/HX(WB)20/NI(WB)500/NP(WB)13 OV-17: HN(WB)1/HX(WB)35/NP(WB)11 tris(beta-chloroethyl) phosphate C6H12Cl3O4P 0.45 - - C - - - - Responses: OV-101: FP1 tris(chloropropyl) phosphate C9H18Cl3O4P 0.5 2.02 0.5 C NR NR 6-15-50 1-2-3 Responses: OV-101: FP1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Molecular RRT/c RRT/c RRT/c Name Formula OV-101 OV-225 OV-17 302 303 304 Ethers CH 2 Cl 2 Appendix I–53 Appendix I: PESTDATA Chemicals in Order by Chemical Name (continued) Recoveries Tycor C9H16N4OS 0.77 1.62 0.99 C S S 50 3 Responses: OV-101: NI1/NP2 OV-17: NI1/NP9 OV-225: NI1 vamidothion sulfone C8H18NO6PS2 2.19 - - C - - - - Responses: vernolate C10H21NOS 0.15 - 0.09 - P - 15 - Responses: OV-101: TI50 OV-17: FP11 vinclozolin C12H9Cl2NO3 0.69 1.15 0.64 C C C 15 2 Responses: OV-101: HX1.5/NI1 OV-17: HX1/NI2 vinclozolin metabolite B C12H11Cl2NO4 0.74 1.2 0.66 C P # C 6+15 2 Responses: OV-101: HN(WB)5/HX(WB)18/NI(WB)5/NP(WB)84 OV-17: HN(WB)6/HX(WB)9/NI(WB)10/NP(WB)19 OV-225: NI(WB)8 vinclozolin metabolite E C11H11Cl2NO2 0.89 3.02 0.93 C S NR 15+50 - Responses: OV-101: HN(WB)3/HX(WB)3/NI(WB)3/NP(WB)15 OV-17: HN(WB)3/HX(WB)3/NI(WB)4/NP(WB)7 OV-225: NI(WB)9 vinclozolin metabolite F C11H13Cl2NO4 2.87 - 4.6 R NR NR 6-15-50 1-2-3 Responses: OV-101: HX(WB)160/NI(WB)57/NP(WB)140 OV-17: HN(WB)100/HX(WB)14/NI(WB)85/NP(WB)210 vinclozolin metabolite S C10H7Cl2NO3 0.69 2.01 0.79 V P V # 15 2 Responses: OV-101: HN(WB)1/HX(WB)2/NI(WB)1/NP(WB)19 OV-17: HN(WB)1/HX(WB)2/NI(WB)1/NP(WB)7 OV-225: NI(WB)2 zoxamide* C14H16NO2Cl3 1.44 - - C C - 50 3 3.9 Responses: OV-101:NI(WB)0.8/NP(WB)18/HX(WB)5 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–54 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–55 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time Recoveries * Multipeak chemical. # Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a. 0.03 TR37 - 0.02 dichlorobenzene, p- C6H4Cl2 - C C 6 1 0.04 TR0.6 - 0.03 dibromochloropropane C3H5Br2Cl - ---- 0.06 NI30 0.08 0.04 CGA 171683 C6H5F4N3O2 C - 15+50 3 0.06 FS9 - - ethiolate C7H15NOS C ---- 0.07 FP(WB)0.7 0.25 0.09 methamidophos C2H8NO2PS V ---- 0.07 FP9/NI1/TI0.5 0.08 0.08 dichlorvos C4H7Cl2O4P C NR NR 6-15-50 1-2-3 0.08 TR2 - - 1,2,3-trichlorobenzene C6H3Cl3 - C P 6 1 0.09 TR5 - - allidochlor C8H12ClNO C NR - 6-15 1-2-3 0.1 NI220 - - methomyl C5H10N202S - NR NR 6-15-50 1-2-3 0.1 TR175 - - monuron C9H11ClN2O - NR NR 6-15-50 1-2-3 0.11 TR0.5 - 0.1 dichlobenil C7H3Cl2N C P C 15 2 0.11 TR25 - - neburon C12H16Cl2N2O C NR NR 6-15-50 1-2-3 0.11 NI(WB)9 0.09 0.11 diuron C9H10Cl2N2O C NR NR 6-15-50 1-2-3 0.12 TI30 - - EPTC C9H19NOS - P - 15 - 0.12 TR0.4 - 0.06 hexachlorocyclopentadiene C5Cl6 - ---- 0.13 NI14/NI(WB)24/NP35 0.15 0.1 chlorimuron ethyl ester C15H15ClN4O6S P NR - - - 0.13 FS10 0.23 0.11 carboxin sulfoxide C12H13NO3S - NR NR 6-15-50 1-2-3 0.13 FP2/FP(WB)1 - 0.15 mevinphos, (Z)- C7H13O6P C NR - 6-15-50 - 0.13 NP(WB)2 - 0.12 propham C10H13NO2 C P P 15 - 0.14 NI(WB)1.5 0.23 0.14 teflubenzuron* C14H6Cl2F4N2O2 - NR NR 6-15-50 1-2-3 0.15 FP(WB)0.9/NP3 0.64 0.19 acephate C4H10NO3PS C ---- 0.15 TR7 0.24 - hydroxy chloroneb C7H6Cl2O2 - NR - 6-15 - 0.15 TI50 - 0.09 vernolate C10H21NOS - P - 15 - 0.15 NI300 0.15 0.14 dimethyl phthalate C10H10O4 - P - 6+15+50 - 0.16 TR35 0.14 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 0.16 FP2 - 0.13 mevinphos, (E)- C7H13O6P C NR NR 6-15-50 - 0.16 NP3 - 0.13 trichlorfon C4H8Cl3O4P C NR NR 6-15-50 1-2-3 0.17 NP200 - 0.11 CGA 236431 C8H7F3N2O2 - ---- 0.17 NI3/NP7 0.22 0.13 3-methyl-4-nitrophenol methyl ether C8H9O3N - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–56 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.17 HX20/NI9 0.14 0.1 N-(3,4-dichlorophenyl)-N'-methylurea C8H8Cl2N2O - NR NR 6-15-50 - 0.17 - - metolcarb C9H11NO2 C ---- 0.17 HN(WB)0.4/NP7 - 0.1 pebulate C10H21NOS C P - 15 - 0.18 NP8 - - prosulfuron* C15H16F3N5O4S - NR NR 6-15-50 1-2-3 0.18 NI200 - 0.22 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 - NR NR 15-50 1-2-3 methylcarbamate* 0.18 NI0.25 - - clopyralid methyl ester C7H4Cl2NO2 - - 50 - 0.18 NI0.3/NP0.6 0.12 0.21 etridiazole C5H5Cl3N2OS C C P 6 2 0.18 HN(WB)1/HX0.5/NI9/ 0.27 0.14 3,5-dichloroaniline C6H5Cl2N S S S 6+15 1+2 NI(WB)16/NP0.9/NP(WB)1 0.19 HX(WB)1.6/NI0.6 0.18 - dicamba methyl ester C8H6Cl2O3 - ---- 0.19 HX(WB)2/NI600 - - MCPA methyl ester C10H11ClO3 - ---- 0.19 HX(WB)2/NI30 - - mecoprop methyl ester C11H13ClO3 - ---- 0.19 HX1/NI1/NP1 0.22 0.14 N, N-diallyl dichloroacetamide C8H11Cl2NO C S S 15+50 2+3 0.19 NI0.5/NI(WB)0.4/NP(WB)9 0.08 0.1 2-methoxy-3,5,6-trichloropyridine C6H4Cl3NO C P# C 6+15 1+2 0.19 - - bis(trichloromethyl)disulfide C2Cl6S2 - R - 6 - 0.19 NI3.5 0.19 - chloroneb C8H8Cl2O2 C C - 6 2 0.2 HX25/NI20 0.86 0.61 desdiethyl simazine C3H4ClN5 - NR NR 6-15-50 1-2-3 0.2 HX2/NI(WB)0.8/NP(WB)4 0.18 0.2 nitrapyrin C6H3Cl4N C C V 6 2 0.2 - 0.27 1,2,4-triazole C2H3N3 V NR NR 6-15-50 1-2-3 0.2 HX0.6/NI16/NP1 0.32 0.16 3,4-dichloroaniline C6H5Cl2N V S - 15 - 0.21 HX9/NI25 - 1.36 3-(3,4-dichlorophenyl)-1-methoxyurea C8H8Cl2N2O2 R NR NR 6-15-50 - 0.21 - - THPI C8H9NO2 C NR NR 6-15-50 - 0.21 FP(WB)46/NI(WB)4000 0.27 0.24 TEPP C8H20O7P2 C ---- 0.22 NP100 - 0.14 CGA 72903 C7H6F3N - ---- 0.22 NI170/NP40 0.25 0.2 3-carboxy-5-ethoxy-1,2,4-thiadiazole C3H2N2O3S NR ---- 0.22 TI6 0.32 0.21 demeton-O oxygen analog C8H19O4PS - ---- 0.22 HX9/NI18/NP60 0.14 0.1 3,4-dichlorophenylurea C7H6Cl2N2O - NR NR 6-15-50 - 0.22 - - butylate C11H23NOS - ---- 0.22 NP0.5 - 0.14 CGA 150829 C5H14N4O V ---- 0.23 TR0.6 0.21 0.18 methyl 2,3,6-trichlorobenzoate C8H5Cl3O2 - ---- 0.23 NI3 - - disul-Na C8H7Cl2O5S?Na - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–57 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.24 NI0.2 0.15 0.22 2,3,5,6-tetrachloroanisole C7H4Cl4O - C - 6 1 0.24 HX0.3/NI0.25 0.13 0.16 pentachlorobenzene C6HCl5 C C C 6 1 0.25 NI100 - - picloram* C6H3Cl3N2O2 - ---- 0.25 HN(WB)1/NI(WB)23/ 0.5 0.16 cymoxanil C7H10N4O3 V NR NR 6-15-50 1-2-3 NP(WB)10 0.25 HN(WB)0.5/NI(WB)4/ 0.92 0.28 oxamyl oxime metabolite C5H10N2O2S C NR NR 6-15-50 1-2-3 NP(WB)4 0.25 FP(WB)0.9/TI25 1.11 0.39 omethoate C5H12NO4PS C NR NR 6-15-50 1-2-3 0.26 NP20 - 0.13 CGA 236432 C9H9F3N2O2 - ---- 0.26 NI0.5 0.51 0.23 RPA 203328, methylated C10H9F3O4S - ---- 0.26 NI1000/NP(WB)0.5 - 0.21 tebuthiuron C9H16N4OS - ---- 0.26 FP0.5/TI1 - 0.26 thionazin C8H13N2O3PS C P NR 15+50 - 0.26 NI3500 - - diethyl phthalate C12H14O4 - P P 15+50 - 0.27 NI200 - 0.31 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 - NR NR 15-50 1-2-3 methylcarbamate* 0.28 FP(WB)2 - 0.36 demeton-O* C8H19O3PS2 C NR - 6-15 - 0.28 HX(WB)1.6/NI2 - - dichlorprop methyl ester C10H10Cl2O3 - ---- 0.28 NP3 - 0.29 G-27550 C8H12N2O C ---- 0.28 FP(WB)8 0.49 0.32 metasystox thiol C6H15O3PS2 C ---- 0.29 - 0.25 diphenylamine C12H11N C S - 6+15 - 0.29 TR0.5 0.26 0.24 tecnazene C6HCl4NO2 C C C 6 1 0.3 TR6 0.38 0.25 2,4-D methyl ester C9H8Cl2O3 - ---- 0.3 NI0.4 - - bromoxynil methyl ether C8H5BR2ON - ---- 0.3 HN(WB)6/NI1 - - bromofenoxim methyl ether C14H9Br2O6N3 - ---- 0.3 HN(WB)1/HX(WB)20/ - 0.2 triflusulfuron methyl ester C17H19F3N6O6S V NR NR 6-15-50 1-2-3 NI(WB)500/NP(WB)13 0.3 HX2/NI0.4/NP8 - - 2,4-dichloro-6-nitrobenzenamine C6H4Cl2N2O2 - R - 15 2 0.3 NI400/TI2 0.37 0.29 phorate oxygen analog C7H17O3PS2 C NR NR 6-15-50 1-2-3 0.3 FS2/NP15 - - cycloate C11H21NOS C V # S 15+50 3 0.3 HX12/NI20 0.8 0.53 desethyl simazine C5H8ClN5 - NR NR 50 1-2-3 0.3 - 0.23 tributyl phosphate C12H27O4P - R - 50 - 0.31 FP6 0.49 0.32 metasystox thiono* C6H15O3PS2 - ---- 0.31 FP(WB)0.7/TI15 1.6 0.5 monocrotophos C7H14NO5P C NR NR 6-15-50 1-2-3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–58 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.31 FP(WB)0.6/TI10 0.96 0.43 dicrotophos C8H16NO5P C NR - 6-15-50 - 0.32 NI(WB)0.6/NP(WB)5 0.44 0.36 3, 5, 6-trichloro-2-pyridinol methyl C6H4Cl3NO - ---- ester 0.32 NI0.4 - - fenac methyl ester C9H7Cl3O2 - ---- 0.32 - - chlorothalonil trichloro impurity C8HCl3N2 R R # NR 6-15-50 2+3 0.32 - - bendiocarb C11H13NO4 C ---- 0.32 HX2 - - 2-chloroethyl caprate C8H15ClO2 - C C 15 2 0.32 HN(WB)1.5 - 0.41 phenmedipham C16H16N2O4 - ---- 0.32 HX2 0.43 0.25 chlorpropham C10H12ClNO2 C C C 15 2 0.33 FP0.5/HX0.3/NI0.5 0.23 0.24 chlorethoxyfos C6H11Cl4O3PS V C - 6 1 0.33 FP0.7/TI0.8 0.31 0.25 ethoprop C8H19O2PS2 C P # S # 50 1-2-3 0.34 HX4/HX(WB)7/NI1 0.27 0.19 ethalfluralin C13H14F3N3O4 C C C 6 2 0.34 - 0.25 2,4,5-trichloro-alpha-methylbenzene C8H7OCl3 R R - 15 - methanol 0.34 - 0.36 dioxabenzofos C8H9O3PS C P - 15 - 0.34 TI0.8 - 0.29 sulfotep C8H20O5P2S2 C C P 6+15 2 0.34 NI(WB)16/NP(WB)13 0.37 0.26 propachlor C11H14ClNO C NR NR 6-15-50 1-2-3 0.34 TR1 0.27 0.17 trifluralin C13H16F3N3O4 C C C 6 2 0.34 NP11 - 0.32 naled C4H7Br2Cl2O4P C NR NR 6-15-50 1-2-3 0.35 HN(WB)17/NI(WB)34/ 2.85 0.4 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 NP(WB)600 0.35 HN(WB)30 - - DNOC methyl ether C8H8N2O5 - ---- 0.35 HN(WB)0.5/NI320/NP15 0.7 0.41 methabenzthiazuron C10H11N3OS C NR NR 6-15-50 1-2-3 0.35 NP8 0.6 0.38 2,3,5-trimethacarb C11H15NO2 C S # NR 50 1-2-3 0.36 NI0.5/NI(WB)0.7/NP(WB)7 0.36 0.39 triclopyr methyl ester C8H6Cl3NO3 - ---- 0.37 FP(WB)0.5 0.27 0.29 cadusafos C10H23O2PS2 C NR NR 6-15-50 1-2-3 0.37 HX(WB)1.5/NI(WB)2 0.28 0.18 benfluralin C13H16F3N3O4 C C C 6 2 0.37 FP1/NI(WB)24/TI1 0.38 0.32 phorate C7H17O2PS3 C V # V # 6 1 0.38 NI13/NP50 0.63 0.26 3-methyl-4-nitrophenol C7H7O3N V NR NR 6-15-50 1-2-3 0.38 NI(WB)1 0.44 0.36 sulfallate C8H14ClNS2 C C C 6+15 2 0.39 NI(WB)20 1.16 0.54 4-chlorobenzylmethyl sulfoxide C8H9ClOS - NR NR 6-15-50 1-2-3 0.39 1.3 0.52 2,6-dichlorobenzamide C7H5NOCl2 C NR NR 6-15-50 1-2-3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–59 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.39 - - carbofuran C12H15NO3 C ---- 0.39 NP1 0.53 0.38 fonofos oxygen analog C10H15O2PS V NR NR 6-15-50 1-2-3 0.4 NP(V)20 - 0.47 CGA 37734 C10H13NO2 C NR NR 6-15-50 1-2-3 0.4 HX500/NI300 - 0.71 dazomet C5H10N2S2 S NR - 6-15-50 1-2-3 0.4 TR0.4 0.48 0.35 BHC, alpha- C6H6Cl6 C C C 6 1 0.4 FP(WB)0.7/NI(WB)6/NP1 1.6 0.62 dimethoate C5H12NO3PS2 C NR NR 6-15-50 1-2-3 0.41 FS0.5 2.71 0.81 dimethipin C6H10O4S2 C NR NR 6-15-50 1-2-3 0.41 NI(WB)0.4 1.91 0.66 4-chlorobenzylmethyl sulfone C8H9ClO2S - NR NR 6-15-50 1-2-3 0.41 NI10/NI(WB)3/TI1 0.51 0.4 thiometon C6H15O2PS3 C NR NR 6-15-50 - 0.41 FP(WB)0.8/TI2 0.56 0.41 demeton-S C8H19O3PS2 C NR - 6-15-50 - 0.41 NI(WB)90 0.83 0.5 simazine C7H12ClN5 C NR NR 50 1-2-3 0.42 HN(WB)5/NI(WB)5/ 0.97 0.49 PPG-947, methylated* C18H13ClF3NO7 - ---- NP(WB)65 0.42 TR10 0.74 0.33 2,4-D isopropyl ester* C11H12Cl2O3 - ---- 0.42 HN(WB)3/HX(WB)42/ - 0.9 pyrazon metabolite B C6H4ClN3O - NR NR 6-15-50 1-2-3 NI(WB)35/NP(WB)14 0.42 FP0.5/NI1000 - 0.39 terbufos oxygen analog C9H21O3PS2 C - NR 6-15-50 1-2-3 0.42 0.26 0.33 di-allate C10H17ClNOS C C - 6 - 0.42 HX4 0.75 0.45 chlorbufam C11H10ClNO2 C - 15 2+3 0.42 NP100 - 0.42 melamine C3H6N6 NR ---- 0.42 TR0.5 0.96 0.45 dicloran C6H4Cl2N2O2 C S P 15+50 2+3 0.43 HN(WB)0.4/NI(WB)26/ 1.34 0.6 6-chloro-2,3-dihydro-3,3,7-methyl- C9H13ClN2O2 - NR NR 6-15-50 1-2-3 NP(WB)3 5H-oxazolo(3,2-a)pyrimidin-5-one 0.43 FP100 - 0.62 fenthion oxygen analog sulfoxide C10H15O5PS C NR NR 6-15-50 1-2-3 0.43 TI58/TR200 0.74 0.44 atrazine C8H14ClN5 C S # NR 50 1-2-3 0.43 TR2 1.62 0.56 BHC, beta- C6H6Cl6 C C C 6 1 0.44 NP8 2.49 0.64 prosulfuron* C15H16F3N5O4S - NR NR 6-15-50 1-2-3 0.44 HN(WB)0.2/NP(WB)0.5 - 0.82 isocarbamid C8H15N3O2 C ---- 0.44 NI1000/NP300 0.29 0.45 desmedipham C16H16N2O4 - ---- 0.44 HX0.8/NI0.8 1.03 - chloramben methyl ester C8H7Cl2NO2 - ---- 0.45 NI8/NP35 2.25 0.71 methidathion sulfoxide C5H8N2O4S2 - NR NR 6-15-50 1-2-3 0.45 HX(WB)0.8/NI0.6 0.44 - silvex methyl ester C10H9Cl3O3 - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–60 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.45 HX1.5/HX2/NI110 0.59 0.46 clomazone C12H14ClNO2 C - 50 3 0.45 NP25 0.78 0.5 3,4,5-trimethacarb C11H15NO2 C NR NR 50 1-2-3 0.45 HX0.5/NI0.25 0.25 0.33 hexachlorobenzene C6Cl6 C C P 6 1 0.45 FP1 - - tris(beta-chloroethyl) phosphate C6H12Cl3O4P C ---- 0.46 NP2 - 0.49 CGA 51702 C9H9F3N2O - ---- 0.46 NI1.5/NP50 0.6 0.39 furilazole C11H13Cl2NO3 C S - 50 3 0.46 HX0.4/TR0.4 0.3 0.34 pentachlorophenyl methyl ether C7H3Cl5O C C C 6 1 0.46 0.49 0.31 oxydemeton-methyl C6H15O4PS2 C ---- 0.47 0.42 0.53 terbumeton C10H19N5O C ---- 0.47 NI(WB)87/NP(WB)6 0.71 0.48 terbuthylazine C9H16N5Cl C P - 15+50 - 0.47 FP(WB)0.7/NI(WB)2/NP1 - 0.59 cyanophos C9H10O3NSP C ---- 0.47 NI100/TI10 - 0.5 dioxathion C12H26O6P2S4 V NR - 6-15-50 2 0.48 FP1.5 - 0.42 propetamphos C10H20NO4PS C C # - 15+50 2+3 0.48 HX4 0.91 0.48 monolinuron C9H11ClN2O2 C ---- 0.48 NI40 - - silvex C9H7Cl3O3 - ---- 0.48 HX0.6/TR0.5 0.69 0.47 lindane C6H6Cl6 C C C 6 1 0.49 TR1 0.63 0.47 2,4,5-T methyl ester C9H7Cl3O3 - ---- 0.49 NI0.3 0.35 0.48 1,2,4,5-tetrachloro-3-(methylthio)= C7H4Cl4S R C - 6 1 benzene 0.5 NI75 0.79 0.44 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 0.5 NI900/NP100 0.53 0.24 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 0.5 NI1.4/NP34 0.69 0.48 4-(dichloroacetyl)-1-oxa-4-azapiro= C10H15Cl2NO2 C P - 50 3 [4.5]decane 0.5 FP1 2.02 0.5 tris(chloropropyl) phosphate C9H18Cl3O4P C NR NR 6-15-50 1-2-3 0.5 NI0.5 0.59 0.45 pentachlorobenzonitrile C7Cl5N C C P 15 2 0.5 FP2/NI40/TI2 0.44 0.41 terbufos C9H21O2PS3 C P S 6 - 0.5 NI18/NP0.6 0.53 0.47 diazinon oxygen analog C12H21N2O4P C NR NR 6-15-50 1-2-3 0.5 HX0.5/TR0.4 1.71 0.67 BHC, delta- C6H6Cl6 C C C 6+15 1 0.5 NI2200/NP23 2.33 0.66 ethylenethiourea C3H6N2S S NR NR 6-15-50 1-2-3 0.51 NI100/NP1 - - tebupirimfos oxygen analog C13H23O4N2P - NR NR 6-15-50 1-2-3 0.51 FP7/NI1000/NP(WB)3.5 0.8 0.63 etrimfos oxygen analog C10H17N2O5P C ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–61 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.51 HX1/NI2/NP7 0.84 0.4 pronamide C12H11Cl2NO C P - 15+50 - 0.51 FP(WB)1/NI3/NP0.4 0.4 0.44 diazinon C12H21N2O3PS C C C 15 3 0.51 TR0.3 0.46 0.46 quintozene C6Cl5NO2 C C C 6 1 0.52 NI(WB)1/TI166 0.93 0.44 dinitramine C11H13F3N4O4 C - P 15 - 0.52 TI2 0.56 0.44 fonofos C10H15OPS2 C C C 6 2+3 0.53 FP10 - 0.57 phosphamidon* C10H19ClNO5P C NR NR 6-15-50 1-2-3 0.53 HX3/NI1.5 0.76 0.37 fluchloralin C12H13ClF3N3O4 C C - 6 2 0.53 HX5/NI1/NP1 0.46 0.3 profluralin C14H16F3N3O4 V V - 6 - 0.53 NI(WB)110/TI30 0.65 0.41 propazine C9H16ClN5 C S NR 15+50 3 0.54 HX2.5/NI1000 - 0.66 4-chloro-6-methoxyindole C9H8NOCl - R - 15 - 0.54 NP5/NP(WB)6 1.47 0.62 fenfuram C12H11NO2 C ---- 0.54 HN(WB)1/HX5/NI(WB)6/ 2.1 0.72 terbacil C9H13ClN2O2 C NR NR 6-15 2+3 NP(WB)8 0.54 NI(WB)15 - 1.07 4-chlorophenylurea C7H7ClN2O NR NR NR 6-15-50 1-2-3 0.54 TI2 0.6 0.46 disulfoton C8H19O2PS3 C P # NR 6 1-2-3 0.55 HN(WB)17/NI(WB)34/ 3.6 0.95 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 NP(WB)600 0.55 NI30/NP0.4 0.8 0.63 isazofos C9H17ClN3O3PS C C # - 50 2+3 0.55 HN(WB)17/NI(WB)15/ 1.41 0.9 3-ketocarbofuran C12H12NO4 S NR NR 6 1 NP(WB)9 0.55 HX1/NI0.6 1.44 0.74 chlorothalonil C8Cl4N2 S C # C # 6-15-50 2+3 0.55 TI5/TR11 1.71 0.66 parathion-methyl oxygen analog C8H10NO6P - NR NR 6-15-50 1-2-3 0.55 NI(WB)3 0.86 1.04 tetraiodoethylene C2I4 - P P 6 - 0.55 NI2 0.92 - dichlone C10H4Cl2O2 P S # S # 6-15-50 2+3 0.56 NI(WB)2 0.49 0.47 methyl 3,5-dibromo-4-methoxy= C9H8Br2O3 - ---- benzoate 0.56 NI150/NP100 2.29 0.82 methidathion sulfone C5H8N2O3S2 - NR NR 6-15-50 1-2-3 0.56 NI35/NP40 1.41 0.55 metribuzin, diketo metabolite C7H12N4O2 NR NR NR 6-15-50 1-2-3 0.56 NI(WB)1 0.4 0.32 chlordene C10H6Cl6 - C C 6 1 0.56 NI0.4 0.63 0.56 2,3,5,6-tetrachloronitroanisole C7H3Cl4NO3 - C - 6 1+2 0.56 NP10 - - aminocarb C11H16N2O2 C ---- 0.57 NI0.5/NP2 1.47 0.91 metribuzin C8H14N4OS V NR NR 50 1-2-3 0.58 NP10 - 0.68 cyromazine C6H10N6 S ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–62 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.58 FP2/NI50 0.59 0.51 etrimfos C10H17N2O4PS C C C 15 2+3 0.58 FP4/TI5 - 0.52 schradan C8H24N4O3P2 C NR - 6-15-50 - 0.59 NI0.5 0.73 0.66 2,3,5,6-tetrachloroanisidine C7H5Cl4NO - C - 6 2 0.59 HX2 - - 2-chloroethyl laurate C14H27ClO2 - C C 15 2 0.6 NI200/NP200 2.65 0.9 CGA 120844 C8H9NSO3 - NR NR 6-15-50 1-2-3 0.6 FP20/FP400/FS1.5/ 1.4 0.78 ethiofencarb C10H15NO2S C NR NR 6-15-50 - HN(WB)3.5/NI950/NP(WB)4 0.6 FP(WB)1 - 0.54 iprobenfos C13H21O3PS C ---- 0.6 HX1/NI1.5 - 0.45 tri-allate C10H16Cl3NOS C C C 6 2 0.6 NI20/NP15 1.64 0.7 ethoxyquin C14H19N0 C NR NR 6-15-50 - 0.61 NI2 - - fluroxypyr, methylated* C8H7O3N2Cl2F - ---- 0.61 - 0.73 pirimicarb C11H18N4O2 C ---- 0.62 TR28 0.72 - 2,4-DB methyl ester C11H12Cl2O3 - ---- 0.62 TR5 0.62 0.49 2,4-D isobutyl ester C12H14Cl2O3 - ---- 0.63 HN1/NI1.2 - - dinoseb methyl ether C11H14N2O5 - ---- 0.63 NI16/NP1 - - tebupirimfos C13H23N2O3PS - V V 6+15 2+3 0.64 NI1/NP6 1.06 0.7 benoxacor C11H11Cl2NO2 C P C 15+50 2+3 0.64 HX1.5/NI13 1.22 0.74 cyprazine C9H14ClN5 C ---- 0.64 NP3 1.02 0.62 ronnel oxygen analog C8H8Cl3O4P C NR - 6-15-50 - 0.65 NI20 0.61 0.56 diisobutyl phthalate C16H2204 - P - 15+50 - 0.66 FS4 - 0.64 octhilinone C11H19NOS C ---- 0.66 FP1/TI10 - 1.02 phorate oxygen analog sulfone C7H17O5PS2 C NR NR 6-15-50 1-2-3 0.66 HX6/NI3/NI(WB)5 2.82 0.78 propanil C9H9Cl2NO C NR NR 6-15 3 0.67 FP10 - 0.76 phosphamidon* C10H19ClNO5P C NR NR 6-15-50 1-2-3 0.67 NI100 - - picloram* C6H3Cl3N2O2 - ---- 0.67 NP(WB)0.5 - - pyrimethanil C12H13N3 C S S # 50 3 0.67 HX8/NI5 1.44 0.69 metobromuron C9H11BrN2O2 C NR NR 6-15-50 1-2-3 0.67 HX0.5/NI0.4/NP10 0.79 0.66 pentachloroaniline C6H2Cl5N C C C 6 1 0.67 FP1/FP(WB)3.5/NI1.9/TI2 0.64 0.56 dichlofenthion C10H13Cl2O3PS C C V 6 2 0.67 TR2 0.65 - 2,4,5-T isopropyl ester C11H11Cl3O3 - ---- 0.68 TR35 0.66 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 0.68 FS25/NI4 2.89 0.93 2,3-dihydro-3,3-methyl-2-oxo-5- C11H12O5S - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–63 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries benzofuranyl methyl sulfonate 0.68 TI7 1.55 0.87 malathion oxygen analog C10H19O7PS C NR NR 6-15-50 1-2-3 0.69 TR60 0.74 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 0.69 HN(WB)1/HX(WB)2/ 2.01 0.79 vinclozolin metabolite S C10H7Cl2NO3 V P V # 15 2 NI(WB)1/NP(WB)19 0.69 HX1.5/NI1 1.15 0.64 vinclozolin C12H9Cl2NO3 C C C 15 2 0.69 - - chlorthiamid C7H5Cl2NS - ---- 0.7 NP13 - 0.58 CP 51214 C14H21NO3 C NR NR 6-15-50 1-2-3 0.7 HN(WB)0.6/NP(WB)23 - 0.8 IN-B2838 C10H15N3O3 P NR NR 6-15-50 1-2-3 0.71 FP5/TI12 2.95 0.96 demeton-O sulfone* C8H19O5PS2 C ---- 0.71 HN(WB)5/NI1 - - ioxynil methyl ether C8H5I2NO - ---- 0.71 NI30 1.11 0.71 dimethachlor C13H18ClNO2 C ---- 0.71 HN(WB)0.5/NP(WB)3 - 0.95 fuberidazole C11H8N2O C ---- 0.71 FP(WB)0.9/NI(WB)3/NP1.5 1.64 0.87 parathion-methyl C8H10NO5PS C C C 15 2 0.72 - - DDM C13H10Cl2 - ---- 0.72 NI(WB)19/NP(WB)14 0.98 - dimethenamid C12H18ClNO2S - NR NR 6-15-50 1-2-3 0.72 FP(WB)2 - 1.48 oxydemeton-methyl sulfone C6H15O5PS2 C ---- 0.72 FP1/FP(WB)1.3/HX1.5/ 0.86 0.79 chlorpyrifos-methyl C7H7Cl3NO3PS C C - 6 2 NI1/NP1 0.72 FP3 - 0.83 fenitrothion oxygen analog C9H12NO6P C ---- 0.72 TR40 - - 2,4-D n-butyl ester C12H14Cl2O3 - ---- 0.73 NI75 1.29 0.52 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 0.73 NP6 - 0.67 CP 108064, methylated C15H21NO4 - ---- 0.73 NP2 - 0.89 cymiazole C12H14N2S - ---- 0.74 HN(WB)5/HX(WB)18/ 1.2 0.66 vinclozolin metabolite B C12H11Cl2NO4 C P # C 6+15 2 NI(WB)5/NP(WB)84 0.75 HX(WB)1.2/NI1.5/TR1 2.67 - picloram methyl ester C7H5Cl3N2O2 - ---- 0.75 HX5/NI9/NP5 0.88 0.67 acetochlor C14H20NO2Cl C C # P 50 3 0.75 NI2/NP2 0.8 0.68 CGA 14128 C12H21N2O4PS C - 50 1-2-3 0.75 FP1/NI5 1.55 0.79 prothoate C9H20NO3PS2 C ---- 0.75 NP60 - 1.05 carbaryl C12H11NO2 C ---- 0.77 NI1/NP2 1.62 0.99 Tycor C9H16N4OS C S S 50 3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–64 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.77 FP200/NI40/TI50 - 0.74 prometryn C10H19N5S C P # P # 50 1-2-3 0.77 1.1 - ametryn C9H17N5S C ---- 0.78 NI300 - 1.06 phorate oxygen analog sulfoxide C7H17O4PS2 C NR NR 6-15-50 1-2-3 0.78 FP7 - 1.12 fenthion oxygen analog C10H15O4PS C NR NR 6-15-50 1-2-3 0.78 NI0.5/NP7.5 - - bromoxynil butyrate C11H9Br2NO2 - V - 15+50 2 0.79 NI2 - - fluroxypyr, methylated* C8H7O3N2Cl2F - ---- 0.8 HN(WB)1.2/HX(WB)90/ 2.1 - bromacil methyl ether C10H16BrN2O2 - ---- NI(WB)1.5/NP(WB)10 0.8 NP200 - 1.03 3-hydroxymethyl-2,5-dimethylphenyl C11H15NO3 - NR NR 6-15-50 1-2-3 methylcarbamate 0.8 NI(WB)7 1 0.72 alachlor C14H2OClNO2 C C C # 50 3 0.8 NI200/NP200 - 1.17 methiocarb sulfone C11H15NO4S S NR NR 6-15-50 1-2-3 0.8 HN(WB)2/NI(WB)2/ 4.8 1.36 bromacil C9H13BrN2O2 C NR NR 6-15-50 1-2-3 NP(WB)17 0.8 NI(WB)5/NP3 - 0.86 parathion oxygen analog C10H14NO6P C NR NR 6-15-50 1-2-3 0.81 HX(WB)1/NI0.8 0.85 0.75 tridiphane C10H7Cl5O C C - 6 1+2 0.81 HX1000/NI1000/NP7 - 0.9 metalaxyl C15H21NO4 C NR NR 6-15-50 1-2-3 0.81 HX16/NI300 0.85 - chloroxuron C15H15ClN2O2 C NR NR 6-15-50 1-2-3 0.81 NI(WB)1/TI3 0.86 0.76 ronnel C8H8Cl3O3PS C C C 6 2 0.82 TR2 0.64 0.67 chlordene, alpha- C10H6Cl6 - ---- 0.82 TR4 1.07 0.92 dichlorobenzophenone, o,p'- C13H8Cl2O - C C 15 2 0.83 TR5 - - Compound K* C10H6Cl8 - C - - 1 0.83 - - DDNU C14H10Cl2 - ---- 0.83 - - DDNS C14H12Cl2 - ---- 0.83 NI60/NP45 3.77 1.06 metribuzin, deaminated metabolite C8H13N3OS C NR NR 6-15-50 1-2-3 0.83 NI0.6 0.52 0.6 heptachlor C10H5Cl7 C C C 6 1 0.84 NI50 - - sethoxydim sulfoxide C17H29NO4S - NR NR 6-15-50 3 0.84 NI0.6 0.65 - chlordene epoxide C10H6Cl6O - C - 15 - 0.84 1.08 - terbutryn C10H19N5S C ---- 0.84 FP(WB)1/NP1 1.82 1.05 fenitrothion C9H12NO5PS C C C 15 2 0.85 TR28 2.13 0.95 linuron C9H10Cl2N2O2 V V # V 50 3 0.86 NI5 - - dicofol, o,p'-* C14H9Cl5O C V S 6+15 2 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–65 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.86 HN(WB)4/HX(WB)11/ - 1.55 6-chloro-2,3-dihydro-7-hydroxy= C9H13ClN2O3 - NR NR 6-15-50 1-2-3 NI(WB)28/NP(WB)17 methyl-3,3-methyl-5H-oxazolo= (3,2-a)pyrimidin-5-one 0.86 FS32/NI315 1.93 1.02 ethofumesate C13H18O5S C ---- 0.86 FP5 - - phoxim oxygen analog C12H15N204P C ---- 0.87 HX7/NI1100 - 1.07 4-chlorophenoxyaniline* C12H10ClNO S ---- 0.87 FP4 - 1.05 demeton-O sulfoxide C8H15O4PS2 C ---- 0.87 FP2/FP(WB)1.2/NI100/NP2 - 0.92 pirimiphos-methyl C11H20N3O3PS C C C 15 3 0.88 - - methiocarb C11H15NO2S C ---- 0.88 NI30 0.92 0.84 dibutyl phthalate C16H22O4 - C C 15+50 - 0.89 HN(WB)3/HX(WB)3/ 3.02 0.93 vinclozolin metabolite E C11H11Cl2NO2 C S NR 15+50 - NI(WB)3/NP(WB)15 0.89 NI4/TI26 4.9 1.48 cyanazine C9H13ClN6 C NR - 6-15-50 - 0.89 FP5/NI8/NP4 2.55 1.26 phorate sulfoxide C7H17O3PS3 C NR NR 6-15-50 1-2-3 0.9 NP400 - 0.45 formetanate hydrochloride C11H16ClN3O2 - ---- 0.9 NI1/NP44 1.71 1.01 dichlofluanid C9H11Cl2FN2O2S2 C C # - 15+50 2+3 0.91 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 0.91 NI(WB)7/NP1 1.49 1.05 malathion C10H19O6PS2 C C C 15+50 3 0.92 FP7/NI40 2.9 1.28 terbufos oxygen analog sulfone C9H21O5PS2 C NR NR 6-15-50 1-2-3 0.93 FP(WB)5 - 1.43 des N-isopropyl isofenphos oxygen C12H18NO5P - ---- analog 0.94 TR1 - - 2,4,5-T isobutyl ester C12H13Cl3O3 - ---- 0.94 0.97 0.66 prodiamine C13H17F3N4O4 C ---- 0.94 NI73 1 0.98 thiobencarb C12H16ClNOS C V 15 2+3 0.94 HX0.7/NI0.4 0.69 0.87 pentachlorophenyl methyl sulfide C7H3Cl5S C C C 6 1 0.95 FP27/NI6/TI8 1.51 1.08 chlorpyrifos oxygen analog C9H11Cl3NO4P C NR - 6-15-50 - 0.96 HX5/NI1 1.45 0.86 nitrofluorfen C13H7ClF3NO3 C C C 15 2 0.96 - 1.32 carbetamide C12H16N2O3 - ---- 0.96 FP2/TI4 1.46 1.18 fenthion C10H15O3PS2 C S # NR 6+15 1-2-3 0.97 HX13/NI40 1.46 - methazole C9H6Cl2N2O3 - ---- 0.97 HN(WB)5 - 0.96 difenoxuron C16H18N2O3 - ---- 0.97 NI4/TI4 3.26 1.3 phorate sulfone C7H17O4PS3 C S # S # 6-15-50 3 0.98 TR1 0.84 0.89 chlordene, beta- C10H6Cl6 - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–66 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 0.98 TR2 0.89 0.88 chlordene, gamma- C10H6Cl6 - ---- 0.98 TI340 - - desmethyl diphenamid C15H15NO - ---- 0.98 NI(WB)4/NP2 1.91 1.07 parathion C10H14NO5PS C C C 15 2 0.99 NI1 - - benazolin methyl ester C9H6O3SNCl - ---- 0.99 NI3/NP35 1.91 0.96 KWG 1323 C14H16ClN3O3 C NR NR 6-15-50 1-2-3 0.99 NI(WB)7 1.63 1.07 1-hydroxychlordene C10H6Cl6O - R - 15 - 0.99 TR3 1.25 1.08 dichlorobenzophenone, p,p'- C13H8Cl2O - C C 15 2 1 FS48/NI135 6.6 1.46 2-hydroxy-2,3-dihydro-3,3-methyl-5- C11H14O5S - ---- benzofuranyl methyl sulfonate 1 NI1.5/TI3 1 1 chlorpyrifos C9H11Cl3NO3PS C C P 6 2 1.01 FP4/FP(WB)1.6 - 1.14 pirimiphos-ethyl oxygen analog C13H24N3O4P C ---- 1.03 HX5/NI12 1.21 0.93 metolachlor C15H22ClNO2 C S # NR 50 1-2-3 1.04 NI5 - - dicofol, p,p'-* C14H9Cl5O C V P # 6+15 1+2 1.04 HN(WB)620/NI(WB)1000 - 1.13 PPG-947 C17H11ClF3NO7 - NR NR 6-15-50 1-2-3 1.05 NI220 1 - PP 890 C9H10O2ClF3 - ---- 1.05 HN(WB)170/HX(WB)980/ 1.47 0.88 acifluorfen C14H7ClF3NO3 - NR NR 6-15-50 1-2-3 NI(WB)40/NP(WB)270 1.05 HX3/NI2/NP20/NP(WB)2 1.64 1 triadimefon C14H16ClN3O2 C S # S # 50 1-2-3 1.05 HN(WB)1.4 - 1.43 pyracarbolid C13H15NO2 - ---- 1.05 TR0.8 0.58 0.76 aldrin C12H8Cl6 C C C 6 1 1.06 NI1 1.13 1 DCPA C10H6Cl4O4 C C C 15 2 1.07 NI100/NP40 - 1.8 methidathion oxygen analog C6H11N2O5PS2 - NR NR 6-15-50 1-2-3 1.07 - - 3-chloro-5-methyl-4-nitro-1H-pyrazole C4H4ClN3O2 C ---- 1.08 TR35 0.91 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 1.08 FP100/NI1000/NP40 3 1.66 fosthiazate C9H18NO3PS2 C NR NR 6-15-50 1-2-3 1.08 TI6 2.33 1.3 crufomate C12H19ClNO3P C NR NR 6-15-50 - 1.09 NP33 - 0.62 fenpropimorph C20H33NO C - 50 1-2-3 1.1 NI(WB)2 - 0.68 nitrothal-isopropyl C14H17O6N C ---- 1.1 - 1.55 diphenamid C16H17NO V NR - 6-15 - 1.1 TR1 - - 2,4,5-T n-butyl ester C12H13Cl3O3 - ---- 1.11 NI40/NP100 4.7 1.33 isoxaflutole (prop) C15H12SNO4F3 NR V # S # 50 3 1.11 FP3/NI(WB)1/TI3 1.29 1.16 bromophos C8H8BrCl2O3PS C C C 6 - RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–67 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 1.13 NI40/NP120 4.7 1.38 RPA202248 C15H12SNO4F3 NR NR NR 6-15-50 1-2-3 1.13 FP3/HX2/NI2/NP3 - 0.97 trichloronat C10H12Cl3O2PS C C - 6 - 1.14 NI2/NP3 1.24 1.01 isopropalin C15H23N3O4 C C - 6 - 1.14 FP2/TI4/TR150 1.03 1.14 pirimiphos-ethyl C13H24N3O3PS C C C 15+50 3 1.15 NI3 4.3 1.54 CGA 91305 C10H8Cl2N3O V NR NR 6-15-50 1-2-3 1.15 NI7/NP3 1.22 0.93 butralin C14H21N3O4 V C - 6+15+50 - 1.15 FP40/TI20 5.8 1.75 demeton-S sulfone C8H19O5PS2 C ---- 1.16 HN(WB)1.4 - 1.56 phenothiazine C12H9NS - ---- 1.17 HX4 - - 2-chloroethyl myristate C16H31ClO2 C V V 15 2 1.17 FP10 1.74 1.24 isofenphos oxygen analog C15H24NO5P C ---- 1.17 MC25/NI200 - - methyl 4-chloro-1H-indole-3-acetate C11H10ClNO2 R R # NR 50 1-2-3 1.18 NP(WB)2 - 1.39 cyprodinil C14H15N3 C NR NR 6-15-50 1-2-3 1.19 TR12 1.15 1.2 TDE, o,p'-, olefin C14H9Cl3 - ---- 1.2 FP2/NI5 - 1.58 terbufos sulfone C9H21O4PS3 C C # C # 6-15-50 2+3 1.2 TR2 3.49 1.85 captan C9H8Cl3NO2S C P C 50 3 1.21 FP2 2.73 1.5 des N-isopropyl isofenphos C12H18NO4PS C S - 50 - 1.21 FP10/FP(WB)1.7/ 1.58 1.29 chlorfenvinphos, alpha- C12H14Cl3O4P C - NR 6-15-50 - NI(WB)2/TI4 1.22 NI3/NP5 1.48 1.21 pendimethalin C13H19N3O4 C C P 15 2 1.23 NI(WB)1 3.01 1.94 folpet C9H4Cl3O2NS C C P 15+50 2+3 1.24 NP(WB)3 - 1.32 penconazole C13H15Cl2N3 C ---- 1.24 HX(WB)8/NI4 1.88 1.47 anilazine C9H5Cl3N4 V S P 15+50 2+3 1.25 NI2/NP8 8 1.09 MB45950 C12H4SN4F6Cl2 S P V 15+50 2+3 1.25 NI3/NP70 - 1.41 tolylfluanid C10H13ClFNOS C ---- 1.26 TR4 3.5 1.92 Sulphenone C12H9ClO2S C - 50 3 1.27 HX12/NI19 3.39 1.42 chlorbromuron C9H10BrClN2O2 V V V 50 3 1.28 HX7/NI1100 - 1.31 4-chlorophenoxyaniline* C12H10ClNO S ---- 1.28 NI(WB)70/NP(WB)90 - 2.41 hexythiazox C17H21ClN2O2S - S # NR 50 2+3 1.28 NI1000 - 1.6 3-phenoxybenzenemethanol C13H12O2 - ---- 1.28 FP(WB)1.7/NI5 2.67 1.58 mecarbam C10H20NO5PS2 C - 50 - 1.29 FP2/FP(WB)1.8/HX3/ 2 1.52 chlorfenvinphos, beta- C12H14Cl3O4P C S # - 50 1-2-3 NI(WB)2/TI4 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–68 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 1.29 HX0.7/TR1 1.22 1.15 heptachlor epoxide C10H5Cl7O C C C 6 2 1.3 NI50 8.9 - chlorsulfuron C12H12ClN5O4S - NR NR 6-15-50 - 1.31 FP(WB)2/NI5/TI3 2.05 1.83 phenthoate C12H17O4PS2 C C - 15+50 - 1.32 FP5/FP(WB)2.7 2 1.64 quinalphos C12H15N2O3PS C C - 15 - 1.33 TR1 0.94 1.05 octachlor epoxide C10H4Cl8O C C C 6 1 1.34 FP3/TI5 0.65 1.43 merphos* C12H27PS3 - C C 6+15+50 3 1.35 HN(WB)4/HX(WB)40/ 2.27 2.55 3-tert-butyl-5-chloro-6-hydroxy= C9H13ClN2O3 - NR NR 6-15-50 1-2-3 NI(WB)67/NP(WB)39 methyluracil 1.35 NI2/NP10 8.7 1.16 fipronil C12H4Cl2F6N4OS S S V 50 3 1.36 HX10/NI90/NP30/NP(WB)5 - 1.44 triadimenol C14H18ClN3O2 C NR NR 6-15-50 - 1.36 FP2/NI20 1.73 1.38 isofenphos C15H24NO4PS C C - 15+50 - 1.36 NI8 1.22 - allethrin C19H26O3 - C C # 50 3 1.37 NI12 3.04 1.49 procymidone C13H11Cl2NO2 C C P 15 - 1.37 NI2 1.22 1.12 S-bioallethrin C19H26O3 - C - 50 - 1.37 NI60/TI10 2.85 1.9 crotoxyphos C14H19O6P C NR NR 6-15-50 1-2-3 1.39 NI1000 1.89 1.54 CGA 189138 C13H8O3Cl2 - ---- 1.39 NI6 1.62 1.54 chlorbenside C13H10Cl2S C S P 6 1 1.4 NI500/NP500 - - WAK4103* C9H9N5O3Cl - NR NR 6-15-50 1-2-3 1.4 HN(WB)1.5 - 1.32 dinobuton C14H18N2O7 C ---- 1.4 FP5/FP(WB)1.6/NP3 3.33 2.28 methidathion C6H11N2O4PS3 C S P # 50 3 1.41 HN(WB)1.6/NP(WB)51 - 2.55 IN-T3936 C10H15N3O4 S NR NR 6-15-50 1-2-3 1.42 NI2800 3.7 - fenac C8H5Cl3O2 - NR NR 6-15-50 - 1.43 TR2 - - photodieldrin B C13H9Cl5O - ---- 1.44 NP(WB)4 2.23 1.19 triflumizole C15H15ClF3N3O C ---- 1.44 TR60 - - 4-(2,4-dichlorophenoxy)benzenamine C12H9Cl2NO - ---- 1.44 NI(WB)0.8/NP(WB)18/ - - zoxamide* C14H16NO2Cl3 C C - 50 3 HX(WB)5 1.45 NI(WB)4 1.36 1.45 TDE, p,p'-, olefin C14H9Cl3 C C C 6 1 1.47 - - DDMU C14H9Cl3 - ---- 1.48 NP90 - 2.04 thiabendazole C10H7N3S C NR - 6-15-50 - 1.49 TR1 1.46 1.34 chlordane, trans- C10H6Cl8 C C C 6 1 1.5 NI34 - 1.46 metazachlor C14H16ClN3O C ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–69 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 1.5 7.9 - procyazine C10H13ClN6 C ---- 1.5 NI3/NP22 4.3 2.67 TCMTB C9H6N2S3 C P P 15 - 1.5 TI7 6.7 2.39 disulfoton sulfone C8H19O4PS3 C NR - 6-15-50 - 1.51 FP3/NI3/TI4 1.42 1.45 bromophos-ethyl C10H12BrCl2O3PS C C P 6 - 1.52 NP(WB)6 - 1.59 paclobutrazol C15H20ClN3O C ---- 1.53 NI5/NP150 6.5 2.41 CGA 94689A C15H21NO5 V NR NR 6-15-50 1-2-3 1.53 TR40 0.95 - Perthane olefin C18H19Cl - C C 6 1 1.54 TR20 3.6 - 2,4-D propylene glycol butyl ether C15H2OCl2O4 - ---- ester* 1.54 NI12/NP150 6.6 2.45 CGA 94689B C15H21NO5 S NR NR 6-15-50 1-2-3 1.55 HX(WB)9/NI5 - 1.4 haloxyfop methyl ester C16H13ClF3NO4 - ---- 1.55 TR2 1.28 1.51 DDE, o,p'- C14H8Cl4 C C C 6 1 1.57 NI5/NP30 1.84 1.64 cyclanilide methyl ester C12H11Cl2NO3 - ---- 1.57 NI(WB)1 - 1.85 oxythioquinox C10H6N2OS2 C ---- 1.58 NI15/NP25 2.46 2.1 triazamate C13H22N4O3S C NR NR 6-15-50 1-2-3 1.58 FP9/TI8 2.72 1.97 Gardona C10H9Cl4O4P C NR NR 6-15-50 1-2-3 1.58 TI400 - - promecarb C12H17NO2 V ---- 1.59 NI550/NP210 - - NTN35884* C9H9N5O2Cl - NR NR 6-15-50 1-2-3 1.59 NP500/NP(WB)8 - 3.9 tricyclazole C9H7N3S C ---- 1.6 FS(WB)10/NI(WB)3 4.1 3.17 isoprothiolane C12H18O4S2 C ---- 1.6 - - MGK 264 C17H25NO2 - ---- 1.61 HX4/TR3 3.04 2.2 ovex C12H8Cl2O3S C C C 15 2 1.64 HX1/NI1.3 1.38 1.47 endosulfan I C9H6Cl6O3S C C C 15 2 1.65 - 1.65 DDMS C14H11Cl3 - R - 6 - 1.66 TR60 1.18 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 1.66 FP8/NP8 3.7 2.41 fenamiphos C13H22NO3PS C NR NR 6-15-50 1-2-3 1.66 TR1 1.54 1.48 chlordane, cis- C10H6Cl8 C C C 6 1 1.7 NP40 - 2.12 napropamide C17H20NO2 C ---- 1.73 HX9 1.83 1.46 butachlor C17H26ClNO2 C C - 50 - 1.73 HX8/NI3 - 1.88 chlorflurecol methyl ester C15H11ClO3 C ---- 1.75 TR2 1.45 1.42 nonachlor, trans- C10H5Cl9 C C C 6 1 1.76 NI30/NP(WB)12 4 2.08 imazalil C14H14Cl2N2O C NR NR 6-15-50 - RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–70 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 1.77 FP(WB)4 - - fenthion oxygen analog sulfone* C10H15O6PS2 - ---- 1.78 HX11/NI10/NP180 3.14 2 diethatyl-ethyl C16H22ClNO3 C NR NR 6-15-50 1-2-3 1.79 HX540/HX(WB)50/NI45/ 3.5 2.76 imazamethabenz methyl ester* C16H20N2O3 C ---- NP(WB)40 1.8 NP100 - 2.96 CGA 100255 C15H12NO5 S ---- 1.8 FP7/FP(WB)2.6/NI3 2.34 2.13 profenofos C11H15BrClO3PS C P P 50 3 1.82 TR12 2.08 1.79 2,4-D butoxyethyl ester* C14H18Cl2O4 - ---- 1.84 NI200/NP50 - - imidacloprid C9H10ClN5O2 - NR NR 6-15-50 1-2-3 1.85 FP4/NI3/NP3 1.74 1.82 prothiofos C11H15Cl2PO2S2 C C C 6 2 1.86 HX6/NI3 2.91 1.79 hexaconazole C14H17Cl2N3O C ---- 1.87 FS50 - - carboxin C12H13NO2S C NR NR 6-15-50 - 1.88 NI25 - 1.99 pretilachlor C17H26ClNO2 C ---- 1.88 NP1 4.1 - ethion oxygen analog C9H22O5P2S3 C ---- 1.9 HN(WB)58/HX(WB)110/ 3.16 1.86 PPG-2597 C20H17ClF3NO6 - NR NR 6-15-50 1-2-3 NI(WB)85/NP(WB)150 1.9 HN(WB)0.7/NI25/NP(WB)7 7.2 2.6 myclobutanil C15H17ClN4 C NR NR 6-15-50 1-2-3 1.9 TR2 2.46 2.19 TDE, o,p'- C14H10Cl4 - C C 6 1 1.91 HX1/NI1.5 1.87 1.84 dieldrin C12H8Cl6O C C C 15 2 1.92 NI1.5 1.59 1.86 DDE, p,p'- C14H8Cl4 C C C 6 1 1.94 HX8/NI7 - 2.45 flamprop-methyl C17H15ClFNO3 C ---- 1.95 FP3/TI5 1.64 1.88 merphos* C12H27PS3 - C C 6+15+50 3 1.95 FP3/NP3/TR4 1.65 1.88 tribufos C12H27OPS3 C C P 15+50 3 1.97 NP(WB)5 - 2.33 flusilazole C16H15F2N3Si C ---- 1.97 HX4/NI4 2.48 1.96 oxadiazon C15H18Cl2N2O3 C C P 15 - 1.99 TI45 - 3.8 fensulfothion oxygen analog sulfone C11H17O7PS2 - ---- 2 TR60 1.79 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 2 NI900/NP100 0.93 0.44 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 2 FP600/TR10000 2.77 - aramite* C15H23ClO4S C P NR 15 - 2 NI5 4 2.16 oxyfluorfen C15H11ClF3NO4 C C C 15 2 2 FS(WB)20/NI(WB)8 3.7 2.6 bupirimate C13H24N4SO3 C ---- 2 NI(WB)10/NP(WB)50 3.02 3.38 kresoxim-methyl C18H19NO4 P C C 15+50 3 2.02 HX7/NI7/NP(WB)8 3.4 2.03 diclobutrazol C15H19Cl2N3O C NR NR 6-15-50 1-2-3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–71 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 2.02 NP7 1.21 - simetryn C8H15N5S C ---- 2.03 NI(WB)1 3.8 2.71 nitrofen C12H7Cl2NO3 C C C 15 2 2.04 TR50 1.78 1.78 2,4-D isooctyl ester* C16H22Cl2O3 - ---- 2.04 HN(WB)182/HX(WB)73/ 1.61 2.69 cyproconazole C15H18ClN3O C NR NR 6-15-50 1-2-3 NI(WB)72/NP(WB)12 2.06 NI2/NP30 31 1.98 MB46136 C12H4SO2N4F6Cl2 S S V 50 2+3 2.07 NP189 - 2.92 methoprotryne C11H21N5OS C ---- 2.1 NI5 1.78 1.68 2,4-D ethyl hexyl ester* C16H22Cl2O3 - ---- 2.12 NI25 1.76 1.76 pyrethrins* C21H27O4 - C C 50 - 2.13 TR2 2.22 2.29 endrin C12H8Cl6O C C # C # 15 2 2.14 HN(WB)5/NI(WB)5/ 5 2.4 PPG-947, methylated* C18H13ClF3NO7 - ---- NP(WB)65 2.14 NI100 - - mirex, 5,10-dihydro-* C10H2Cl10 - ---- 2.14 FP600/TR10000 3.05 - aramite* C15H23ClO4S C P NR 15 - 2.15 HN(WB)3/HX(WB)10/ 5 2.4 PPG-847, methylated C15H9ClF3NO3 - ---- NI(WB)3/NP(WB)34 2.17 NI6/TI15 4.2 3.06 carbophenothion oxygen analog C11H16ClO3PS2 C NR NR 6-15-50 1-2-3 2.19 - - vamidothion sulfone C8H18NO6PS2 C ---- 2.19 NI(WB)1 4.2 2.38 binapacryl C15H18N2O6 C P P 15 - 2.21 NI2/NP50 - 2.34 chlorfenapyr (prop) C15H11BrClF3N2O P - S 50 2 2.21 HX2/NI2 3.9 2.77 endosulfan II C9H6Cl6O3S C C C 15+50 2 2.22 HX9/NI6 4.1 2.99 chlorthiophos oxygen analog C11H15Cl2O4PS C NR NR 6-15-50 1-2-3 2.23 TR150 2.01 2.42 Perthane C18H2OCl2 C C C 6 1 2.24 FP8 - 2.58 chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 2.24 NI20 - - metamitron C10H10N4O - ---- 2.26 FP54 - 4.4 famphur oxygen analog C10H16NO6PS C ---- 2.28 NI1.5 - - methyl 2,3,5-triiodobenzoate C8H5I3O2 - ---- 2.29 FP(WB)4 - 4.1 fenthion oxygen analog sulfone* C10H15O6PS2 - ---- 2.3 HX19/HX(WB)18/NI125 2.36 2.31 fluazifop butyl ester C19H20F3NO4 C C V 15 3 2.31 NI20/NP50 15 3.93 desisopropyl iprodione C10H6Cl2N3O3 P - 50 1-2-3 2.31 TR70 3.26 2.61 chlorobenzilate C16H14Cl2O3 C C # P # 15+50 3 2.33 TR8 5.8 - Dilan* C15.5H14Cl2NO2 - P P 15 - RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–72 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 2.33 TR80 2.9 2.41 chloropropylate C17H16Cl2O3 P C C 15+50 3 2.35 TR4 - - endrin aldehyde C12H8Cl6O C P C 15+50 - 2.35 HX10 - - 2-chloroethyl palmitate C18H35ClO2 - V P 15 2 2.36 FP8 - 2.77 chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 2.36 NP(WB)12 - - etaconazole* C14H15Cl2N3O2 C ---- 2.37 - - 2,4,5-T propylene glycol butyl C15H19Cl3O4 - ---- ether esters 2.38 NI(WB)2/TI5 3.24 3.14 leptophos photoproduct C13H11Cl2O2PS C ---- 2.39 FP22 - 4.7 fenthion sulfone C10H15O5PS2 C NR NR 6-15-50 1-2-3 2.4 NI120/NP50 4.3 3 imazethapyr ammonium salt C16H21N3O3 - ---- methyl ester 2.4 TI12 - 3.8 fensulfothion C11H17O4PS2 C NR NR 6-15-50 1-2-3 2.41 NI4 - - 2,8-dihydromirex C10H2Cl10 - C - 6 - 2.41 TR4 3.8 2.87 TDE, p,p'- C14H10Cl4 C C C 6 1 2.43 NP(WB)12 - 3.17 etaconazole* C14H15Cl2N3O2 C ---- 2.43 NP60 - 4.5 benodanil C13H10INO C ---- 2.45 TR340 - - diisohexyl phthalate* C20H30O4 - C - 15+50 - 2.46 HX9/NI9 - 2.81 flamprop-M-isopropyl C19H19ClFNO3 C ---- 2.47 NI100 - - mirex, 5,10-dihydro-* C10H2Cl10 - ---- 2.49 TI10 - 5 fensulfothion oxygen analog C11H17O5PS C NR - 6-15-50 - 2.5 NI1700/NP8 14 5 oxadixyl C14H18N2O4 C NR NR 6-15-50 1-2-3 2.51 HN(WB)1/HX(WB)12/ 4 4.2 pyrithiobac-sodium methyl ester C14H13ClN2O4 - ---- NI(WB)9/NP(WB)90 2.52 HX1/NI2 3.33 2.61 nonachlor, cis- C10H5Cl9 C C C 6 1 2.53 TR5 2.66 - Compound K* C10H6Cl8 - C - - 1 2.55 NI(V)250 - - hydramethylnon* C25H24F6N4 - ---- 2.55 TR4 - - endrin alcohol C12H8Cl6O - P C 15+50 2+3 2.55 TR4 2.27 2.7 DDT, o,p'- C14H9Cl5 C C C 6 1 2.56 FP8 - 3.16 chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 2.56 TR20 3.1 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 2.56 FP(WB)1.9/NI(WB)3/NP2 3.93 3.36 ethion C9H22O4P2S4 C C C 6 2 2.62 HX(WB)260 - - pyrazon metabolite A C16H18ClN3O6 - ---- RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–73 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 2.62 HX17 18.6 5.4 ofurace C14H16NO3Cl C ---- 2.62 FP(WB)3 - 5.2 triazophos C12H16N3O3PS C ---- 2.64 NI(WB)1 2.33 2.8 tetrasul C12H6Cl4S C C C 6 1 2.65 FP8/TI40 14 5 famphur C10H16NO5PS2 C NR - 6-15-50 - 2.66 TR340 - - diisohexyl phthalate* C20H30O4 - C - 15+50 - 2.67 NI7 - - 10,10-dihydromirex C10H2Cl10 - C - 6 - 2.67 HN(WB)8/HX(WB)30/ 13 8 pyrazon C10H8ClN3O C NR NR 6-15-50 1-2-3 NI(WB)26/NP(WB)56 2.72 NI500/NP500 - - WAK4103* C9H9N5O3Cl - NR NR 6-15-50 1-2-3 2.75 NI(WB)2 1.67 2.38 chlordecone C10H8Cl10O5 - S # P # 15+50 1-2-3 2.78 FP(WB)14 - 3.6 sulprofos sulfoxide* C12H19O3PS3 C ---- 2.79 FP(WB)47 - 3.5 sulprofos C12H19O2PS3 C ---- 2.8 NI9/NP7 - 3.6 fensulfothion sulfone C11H17O5PS2 C NR - 6-15-50 - 2.81 TR8 7.5 - Dilan* C15.5H14Cl2NO2 - P P 15 - 2.81 NI(WB)1 7.5 3.9 Prolan C15H13Cl2NO2 P S S 15 2 2.83 HX4/TR5 8.3 4 endosulfan sulfate C9H6Cl6O4S C C C 50 2 2.85 TR35 1.19 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 2.85 TR5 4.7 - chlornitrofen C12H6Cl3NO3 C C C 6+15 2 2.87 HX(WB)160/NI(WB)57/ - 4.6 vinclozolin metabolite F C11H13Cl2NO4 R NR NR 6-15-50 1-2-3 NP(WB)140 2.87 FP(WB)4/NI(WB)4 6.3 5.3 edifenphos C14H15O2PS2 C ---- 2.9 TR340 - - diisohexyl phthalate* C20H30O4 - C - 15+50 - 2.9 - 3.7 1,1'-(2,2-dichloroethylidene)bis(2- C16H16Cl2O2 - R - - - methoxybenzene) 2.91 TR4 3.3 - 2,4,5-T butoxyethyl ester* C14H17Cl3O4 - ---- 2.91 HN(WB)3/NP(WB)15 - - hexazinone C12H20N4O2 P NR NR 6-15-50 1-2-3 2.94 TI15/TR4 4.2 3.7 carbophenothion C11H16ClO2PS3 C C P 6 2 2.95 NI25 2.84 2.7 pyrethrins* C21H27O4 - C C 50 - 2.96 TR20 3.4 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 2.96 NI15/NP50 11.5 4.1 CL 202,347 C13H19N3O5 - ---- 2.97 NI(WB)8 3.7 4.2 methoxychlor olefin C16H14Cl2O2 C C C 6 2 3 NP300 - 1.18 NTN33823 C9H11N4Cl - NR NR 6-15-50 1-2-3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–74 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 3.03 NI170 2.74 2.88 ethephon C2H6ClO3P NR - 6+15+50 1+2+3 3.06 NI10/NI(WB)17 - - propiconazole* C15H17Cl2N3O2 C NR NR 6-15-50 1-2-3 3.06 HN(WB)1.4/NP(WB)29 - - IN-A3928 C11H18N4O2 S NR NR 6-15-50 1-2-3 3.06 NI(WB)1 7.5 4.4 Bulan C16H15Cl2NO2 C P P 15 2 3.06 NI35 5.1 4.5 butyl benzyl phthalate C19H20O4 - C P 15+50 - 3.1 NI900/NP100 14.8 7.1 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 3.1 FP3.5/NI3/NP(WB)3 8.2 4.6 cyanofenphos C15H14NO2PS C ---- 3.1 NI(WB)2/NP(WB)220 - 3.7 fenhexamid C14H17Cl2NO2 NR NR NR 6-15-50 1-2-3 3.11 NI3 - 5.4 captafol C10H9Cl4NO2S C P - 50 3 3.13 TR4 3.6 3.5 DDT, p,p'- C14H9Cl5 C C C 6 1 3.14 NI4/NP40 - - bromoxynil octanoate C15H17Br2NO2 - V # - 15+50 2 3.21 NI100 - - mirex, 5,10-dihydro-* C10H2Cl10 - ---- 3.21 NI10/NI(WB)17 5.6 4 propiconazole* C15H17Cl2N3O2 C NR NR 6-15-50 1-2-3 3.22 TR60 2.09 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 3.25 TR20 3.8 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 3.26 NP(WB)30 5.8 4.67 clodinafop-propargyl C17H13ClFNO4 V V - 50 3 3.27 TR340 - - diisohexyl phthalate* C20H30O4 - C - 15+50 - 3.28 FS(WB)17/HN(WB)3/ - 9.4 oxycarboxin C12H13NO4S R ---- NP(WB)130 3.3 TR35 2.78 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 3.3 NI(WB)0.1/NP(WB)37 - 7.5 3-desmethyl sulfentrazone C10H8Cl2F2N4O3S - NR NR 6-15-50 1-2-3 3.3 NI(WB)2 4.5 5 methoxychlor, o, p'- C16H15Cl3O2 - C - 6 - 3.32 NI100/NP10 - - tralkoxydim* C20H27NO3 V NR NR 50 1-2-3 3.34 NI50 - - sethoxydim C17H29NO3S - NR NR 6-15-50 3 3.36 NI5 7.3 4.8 nuarimol C17H12ClFN2O C NR C # 50 1-2-3 3.38 HX(WB)3/NI27 1.41 4.9 desmethyl norflurazon C11H7ClF3N3O V NR NR 6-15-50 1-2-3 3.38 HX(WB)1 - 4.2 tebuconazole C16H22ClN3O C ---- 3.38 NI5 - 2.62 2,4,5-T ethylhexyl ester C16H21Cl3O3 - ---- 3.39 TR8 8.2 - Dilan* C15.5H14Cl2NO2 - P P 15 - 3.57 HX8/NI10 4.9 4.7 diclofop-methyl C16H14Cl2O4 C C C 15 2 3.6 NI60 37.1 7.5 myclobutanil alcohol metabolite C15H17ClN40 S NR NR 6-15-50 1-2-3 3.6 TR5 10.3 - endrin ketone C12H8Cl6O - C C 50 2 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–75 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 3.7 FP20 - 10.1 azinphos-methyl oxygen analog C10H12N3O4PS C ---- 3.74 NI5 - - 8-monohydromirex C10HCl11 - C - 6 - 3.8 FP600/FP(WB)8/NI160 - 6.2 phosalone oxygen analog C12H15ClNO5PS C ---- 3.8 NI36/TI35 - 7.1 carbophenothion oxygen analog C11H16ClO5PS2 - ---- sulfone 3.8 NI(WB)1 24 6.3 nitralin C13H19N3O6S C P P 50 3 3.8 FS45/NI(WB)230 4.8 4.3 propargite C19H26O4S C C - 15 2 3.9 NI(WB)0.8/NP(WB)18/ - - zoxamide* C14H16NO2Cl3 C C - 50 3 HX(WB)5 4 NI(WB)6 - 3.9 dinocap* C18H24N2O6 C P P 15 2 4 NI1000/NP1000 15 4.2 KWG 1342 C14H18ClN3O3 - ---- 4 NI(WB)2/NP19 14.9 8.4 phosmet C11H12O4NPS2 C NR - 6-15-50 3 4.1 TR60 5.1 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 4.1 NI5 1.08 0.91 dicofol, o,p'-* C14H9Cl5O C V S 6+15 2 4.1 HX15 - - 2-chloroethyl linoleate C20H35ClO2 - V P 15 2 4.2 HX13/NI15/NP15 18 6.3 iprodione* C13H13Cl2N3O3 C S # NR 50 1-2-3 4.2 FP60/TI65 7.6 6.5 leptophos oxygen analog C13H10BrCl2O3P C ---- 4.2 TI250 - 2.87 carbophenothion oxygen analog C11H16ClO4PS2 - ---- sulfoxide 4.2 NI(WB)16 14 8.7 pyridaphenthion C14H17O4N2SP C ---- 4.26 NI7 - - 10-monohydromirex C10HCl11 - C - 6 - 4.3 NI100 - - mirex, 5,10-dihydro-* C10H2Cl10 - ---- 4.3 NI50 - - tetramethrin* C19H25NO4 C NR NR 6-15-50 1-2-3 4.3 NI(WB)6 6.9 4.4 dinocap* C18H24N2O6 C P P 15 2 4.3 NI(WB)3 8.4 6 benzoylprop-ethyl C18H17Cl2NO3 P NR NR 6-15-50 1-2-3 4.4 NI5 1.28 1.08 dicofol, p,p'-* C14H9Cl5O C V P # 6+15 1+2 4.4 TR12 6.5 - bromopropylate C17H16Br2O3 C C # C # 15+50 1-2-3 4.4 TR6 15.5 8.5 photodieldrin C12H8Cl6O - C C 15+50 2 4.5 NI50 8.5 7.2 tetramethrin* C19H25NO4 C NR NR 6-15-50 1-2-3 4.5 FP50/NP20 - 8.4 fenamiphos sulfone C13H22NO5PS C NR NR 6-15-50 1-2-3 4.5 HX50 - 5.01 norflurazon C12H9ClF3N3O V NR NR 6-15-50 - 4.5 NI0.5/TI16 10.6 6.9 EPN C14H14NO4PS C C C 15 2 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–76 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 4.6 HX8 - - fenarimol metabolite C C17H14N2OCl2 S - 6 - 4.6 HX19 - - fenarimol metabolite B C17H14N2OCl2 NR NR NR 6-15-50 - 4.7 NI500/NP500 - - WAK4103* C9H9N5O3Cl - NR NR 6-15-50 1-2-3 4.7 HN(WB)390/NI(WB)400 - - IN-T3937 C12H20N4O3 S ---- 4.7 HN(WB)73/NI(WB)230 - - - IN-T3935 C11H18N4O3 S ---- 4.7 HX20/NI6 10.3 6.9 chlorthiophos sulfoxide C11H15Cl2O4PS2 C NR NR 6-15-50 1-2-3 4.7 NI(WB)1 8.6 7.2 tetrasul sulfoxide C12H6Cl4OS - ---- 4.7 NI8800 - - oryzalin C12H8N4O6S - NR NR 6-15-50 - 4.7 NI(WB)12 53 11.3 dithianon C14H4O2N2S2 NR ---- 4.7 TR9 7.2 7.2 methoxychlor, p, p'- C16H15Cl3O2 C C C 6 2 4.8 NI(WB)6 7.7 4.8 dinocap* C18H24N2O6 C P P 15 2 4.8 NI7/NI(WB)0.2/NP30 7 5.7 fenpropathrin C22H23NO3 - V # V 15 2 4.8 FP15 9.7 6.8 piperophos C14H28NO3PS2 C ---- 4.8 NP(WB)40 6.6 6.3 cloquintocet-mexyl C18H22ClNO3 V NR - 6-15-50 1-2-3 4.9 NI8 3.8 4.5 bifenthrin C23H22ClF3O2 V C - 6+15 2 5 NI550/NP210 - - NTN35884* C9H9N5O2Cl - NR NR 6-15-50 1-2-3 5 NP50 - 7.3 fenoxycarb C17H19NO4 C ---- 5 HX16/NI4 14.9 8.8 bifenox C12H9Cl2NO5 C C P 15+50 2+3 5.1 NI(WB)6 9.5 5.6 dinocap* C18H24N2O6 C P P 15 2 5.1 FP(WB)80 - 10.6 sulprofos oxygen analog sulfone C12H19O5PS2 C ---- 5.1 FP3/TI20 - 9.2 carbophenothion sulfone C11H16ClO4PS3 C C P 6 1 5.2 FP50/NP55 - 8.1 fenamiphos sulfoxide C13H22N04PS C NR NR 6-15-50 1-2-3 5.2 TR6 - 8.3 tetradifon C12H6Cl4O2S C C C 15 2 5.2 TI30/TR50 - 11.8 azinphos-methyl C10H12N3O3PS2 C NR NR 6-15-50 1-2-3 5.3 TR35 3.28 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 5.3 HX20/NI9 18.8 9.1 chlorthiophos sulfone C11H15Cl2O5PS2 C C - 50 3 5.3 HX(WB)20/NI1000 - 7.5 iprodione metabolite isomer C13H13Cl2N3O3 C S - 50 - 5.4 NI500/NI(WB)40 4.8 6.5 phenothrin* C23H26O3 - ---- 5.4 NP20 - 5.3 carbosulfan C20H32N2O3S P ---- 5.4 FP3/TI35 - 4 carbophenothion sulfoxide C11H16ClO3PS3 - ---- 5.5 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 5.5 NP10/TR15 5.5 9.1 phosalone C12H15ClNO4PS2 C C C 50 2+3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–77 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 5.8 FP14/TI20/TR11 7.7 8.5 leptophos C13H10BrCl2O2PS C C C 6 2 5.8 NI7 2.95 5.6 mirex C10Cl12 P C P 6 1 5.9 HN(WB)10.5/HX20/NI100 - 9.8 clofentezine C14H8Cl2N4 R S - 15 2 6.1 NI100/NP10 1.48 4.5 tralkoxydim* C20H27NO3 V NR NR 50 1-2-3 6.1 FP(WB)14 - 11.7 sulprofos sulfoxide* C12H19O3PS3 C ---- 6.2 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 6.4 NI(V)200 4.5 6.1 bis(2-ethylhexyl) phthalate C24H38O4 - C C 15+50 - 6.5 - 11.5 myclobutanil dihydroxy metabolite C15H17N4O2Cl NR NR NR 6-15-50 1-2-3 6.5 TI30/TR28 - 14.3 dialifor C14H17ClNO4PS2 C C P 15 2 6.6 HX10/NI5 - 10.1 fenarimol C17H12Cl2N2O C P # C # 50 3 6.6 TR500 - - n-acetyl nitrofen C14H11Cl2NO2 - ---- 6.7 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 6.7 NI1000 - 1.59 CGA 205375 C16H13N3O2Cl2 - ---- 6.7 NI13 - - PPG-1576 C19H17ClF3NO5 - - P 50 2+3 6.9 TI58/TR200 - 14.8 azinphos-ethyl C12H16N3O3PS2 C P S 50 3 7 TR35 7.7 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 7 NI30/NP4000 - 11 tebufenozide C22H28N2O2 - NR NR 6-15-50 1-2-3 7 NI40 - 11.4 CGA 118244 C15H13Cl2N3O3 V NR NR 6-15-50 1-2-3 7.2 FP(WB)16 - 13.1 sulprofos sulfone C12H19O4PS3 C ---- 7.3 NI10 - - lactofen C19H15ClF3NO7 - - C 50 2+3 7.4 NI10 - 8 lambda-cyhalothrin C23H19ClF3NO3 C ---- 7.5 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 7.9 NI90/NP300 - - RH-6467* C19H15N4ClO S NR NR 6-15-50 1-2-3 7.9 NI20 10.8 12.6 HOE-030291 C17H16Cl2O5 - ---- 8 NI200/NP130 45 16 coumaphos oxygen analog C14H16ClO6P C NR NR 6-15-50 1-2-3 8.1 NI250 11.3 10.5 fenoxaprop ethyl ester C18H16NO5Cl S V V 50 3 8.1 FP(WB)12 - 13 pyrazophos C14H20N3O5PS C ---- 9 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 9 NI39/NP38 40 18 coumaphos C14H16ClO5PS C NR C # 6-15-50 3 9.4 - 11.8 bitertanol* C20H23N3O2 C ---- 9.4 NI75 11.1 13.8 permethrin, cis- C21H20Cl2O3 C V # C 6+15 2 9.5 FP100/NI(WB)9/TI190 - 20.2 bensulide C14H24NO4PS3 C P C 50 3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–78 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 9.7 - 12.5 bitertanol* C20H23N3O2 C ---- 9.7 TR7 - - hexachlorophene dimethyl ether C15H10Cl6O2 - NR NR 6-15 - 9.8 NI1000/NP70 - - fenbuconazole C19H17ClN4 C NR NR 6-15-50 1-2-3 10.2 TR60 13 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 10.2 NI100 13 15 permethrin, trans- C21H20Cl2O3 C V # C 6+15 2 10.4 NI90/NP300 - - RH-6467* C19H15N4ClO S NR NR 6-15-50 1-2-3 10.4 NI15/NP125 12.8 8.9 acrinathrin C26H21F6NO5 V V V# 15 2 10.4 HX50/NI12 - 15.4 prochloraz C15H16Cl3N3O2 C ---- 10.5 TR850 - - diisooctyl phthalate* C24H38O4 - C C 15+50 - 11.5 NI500/NI(WB)40 10.9 15 phenothrin* C23H26O3 - ---- 11.7 HX30/NI30 - - cyfluthrin* C22H18Cl2FNO3 C P - 15 - 12 NI50 8.9 6.1 CGA 205374 C16H11N3O2Cl2 - NR NR 6-15-50 1-2-3 12 NI50/NP170 - - RH-9130 C19H16N3ClO2 P NR NR 6-15-50 1-2-3 12 NI(V)330 - - di-n-octyl phthalate C24H38O4 - C C 15+50 - 12.4 NP(WB)14 - - flumetsulam, methylated C13H11F2N5O2S - ---- 12.5 HX30/NI30 - - cyfluthrin* C22H18Cl2FNO3 C P - 15 - 12.8 HX30/NI30 - - cyfluthrin* C22H18Cl2FNO3 C P - 15 - 13 NI(WB)2 13 16 hexachlorophene C13H6Cl6O2 - NR NR 6-15-50 - 13.6 HX70/NI80 - 25 quizalofop ethyl ester C19H17ClN2O4 C ---- 14 NI40/NP190 - - RH-9129 C19H16N3ClO2 V NR NR 6-15-50 1-2-3 14 HX9/NI22 - - alpha-cypermethrin C22H19Cl2O3N C C - - 2 14 NI(WB)90 - - azafenidin C15H13Cl2N3O2 V ---- 14.1 NI90 33 23 cypermethrin* C22H19Cl2NO3 C C C 15 2 14.7 NI40/NI(WB)15 36.9 21.4 flucythrinate* C26H23F2NO4 C C - 15 2+3 15 NI90/NP300 - - RH-6467* C19H15N4ClO S NR NR 6-15-50 1-2-3 15.1 NI90 36 25 cypermethrin* C22H19Cl2NO3 C C C 15 2 16.1 NI40/NI(WB)15 42 24 flucythrinate* C26H23F2NO4 C C - 15 2+3 16.3 HX400/NI1500 24 - fluridone C19H14F3NO - NR NR 6-15-50 - 17 NI200 - 6.2 deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 17.1 NI1300 - 21 deltamethrin* C22H19Br2NO3 C S # P 15 2 20.3 NI90 44 35 fenvalerate* C25H22ClNO3 C C C 15 2 20.7 NI500/NP500 - - WAK4103* C9H9N5O3Cl - NR NR 6-15-50 1-2-3 RRT/c Detector Responses RRT/c RRT/c Molecular OV-101 with OV-101 Column OV-225 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–79 Appendix I: PESTDATA Chemicals in Order by OV-101 Relative Retention Time (continued) Recoveries 22.5 NI90 51 40 fenvalerate* C25H22ClNO3 C C C 15 2 22.5 NI90 - - esfenvalerate C25H22ClNO3 C C C 15 2 23 NI150/NP300 57 43 PB-7, methylated C20H25ClN2O3S - ---- 25 59 38 fluvalinate* C26H22ClF3N2O3 C C - 15 2 25 NI300/NP500 87 46 PB-9 C19H25ClN2O2S V NR NR 6-15-50 1-2-3 27 NI1300 - 35 deltamethrin* C22H19Br2NO3 C S # P 15 2 27 NI30/NI(WB)1 64 44 tralomethrin C22H19Br4NO3 C V S 15 2 29 NI200 - 20 deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 29 NI1300 19.9 38 deltamethrin* C22H19Br2NO3 C S # P 15 2 31 NI200 19.7 38 deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 32 NI(V)250 4.5 - hydramethylnon* C25H24F6N4 - ---- 44 NI(V)250 53 - hydramethylnon* C25H24F6N4 - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–80 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–81 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries * Multipeak chemical. # Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a. 0.08 - - 2,4-D BEP ester* C17H24Cl2O4 - ---- 0.08 NI40 0.06 0.04 CGA 171683 C6H5F4N3O2 C - 15+50 3 0.08 0.19 0.1 2-methoxy-3,5,6-trichloropyridine C6H4Cl3NO C P# C 6+15 1+2 0.08 FP(WB)0.7 0.07 0.08 dichlorvos C4H7Cl2O4P C NR NR 6-15-50 1-2-3 0.09 NI27 0.11 0.11 diuron C9H10Cl2N2O C NR NR 6-15-50 1-2-3 0.11 - 0.09 teflubenzuron* C14H6Cl2F4N2O2 - NR NR 6-15-50 1-2-3 0.12 NI0.2 0.18 0.21 etridiazole C5H5Cl3N2OS C C P 6 2 0.13 NI0.25 0.24 0.16 pentachlorobenzene C6HCl5 C C C 6 1 0.14 0.16 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 0.14 NI12 0.17 0.1 N-(3,4-dichlorophenyl)-N'-methylurea C8H8Cl2N2O - NR NR 6-15-50 - 0.14 NI6 0.22 0.1 3,4-dichlorophenylurea C7H6Cl2N2O - NR NR 6-15-50 - 0.15 0.13 0.1 chlorimuron ethyl ester C15H15ClN4O6S P NR - - - 0.15 NI0.2 0.24 0.22 2,3,5,6-tetrachloroanisole C7H4Cl4O - C - 6 1 0.15 0.15 0.14 dimethyl phthalate C10H10O4 - P - 6+15+50 - 0.18 0.19 - dicamba methyl ester C8H6Cl2O3 - ---- 0.18 NI0.9 0.2 0.2 nitrapyrin C6H3Cl4N C C V 6 2 0.19 0.19 - chloroneb C8H8Cl2O2 C C - 6 2 0.19 - - molinate C9H17NOS - ---- 0.21 0.23 0.18 methyl 2,3,6-trichlorobenzoate C8H5Cl3O2 - ---- 0.22 NI2 0.17 0.13 3-methyl-4-nitrophenol methyl ether C8H9O3N - ---- 0.22 NI1 0.19 0.14 N, N-diallyl dichloroacetamide C8H11Cl2NO C S S 15+50 2+3 0.23 0.14 0.14 teflubenzuron* C14H6Cl2F4N2O2 - NR NR 6-15-50 1-2-3 0.23 FP0.5/NI0.3 0.33 0.24 chlorethoxyfos C6H11Cl4O3PS V C - 6 1 0.23 FS25 0.13 0.11 carboxin sulfoxide C12H13NO3S - NR NR 6-15-50 1-2-3 0.24 0.15 - hydroxy chloroneb C7H6Cl2O2 - NR - 6-15 - 0.24 - - carbofuran-3-keto-7-phenol C10H10O3 - ---- 0.25 NI100 0.22 0.2 3-carboxy-5-ethoxy-1,2,4-thiadiazole C3H2N2O3S NR ---- 0.25 FP4 0.07 0.09 methamidophos C2H8NO2PS V ---- 0.25 NI0.3 0.45 0.33 hexachlorobenzene C6Cl6 C C P 6 1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–82 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.26 0.42 0.33 di-allate C10H17ClNOS C C - 6 - 0.26 0.29 0.24 tecnazene C6HCl4NO2 C C C 6 1 0.27 FP(WB)1 0.37 0.29 cadusafos C10H23O2PS2 C NR NR 6-15-50 1-2-3 0.27 NI0.4 0.34 0.19 ethalfluralin C13H14F3N3O4 C C C 6 2 0.27 0.34 0.17 trifluralin C13H16F3N3O4 C C C 6 2 0.27 NI20/NI(WB)25 0.18 0.14 3,5-dichloroaniline C6H5Cl2N S S S 6+15 1+2 0.27 NI13700 0.21 0.24 TEPP C8H20O7P2 C ---- 0.28 NI2 0.37 0.18 benfluralin C13H16F3N3O4 C C C 6 2 0.29 NI1000 0.44 0.45 desmedipham C16H16N2O4 - ---- 0.3 0.46 0.34 pentachlorophenyl methyl ether C7H3Cl5O C C C 6 1 0.31 0.33 0.25 ethoprop C8H19O2PS2 C P # S # 50 1-2-3 0.32 0.22 0.21 demeton-O oxygen analog C8H19O4PS - ---- 0.32 NI30 0.2 0.16 3,4-dichloroaniline C6H5Cl2N V S - 15 - 0.35 NI0.3 0.49 0.48 1,2,4,5-tetrachloro-3-(methylthio)= C7H4Cl4S R C - 6 1 benzene 0.36 0.36 0.39 triclopyr methyl ester C8H6Cl3NO3 - ---- 0.37 FP0.5 0.3 0.29 phorate oxygen analog C7H17O3PS2 C NR NR 6-15-50 1-2-3 0.37 NI9/NI(WB)5 0.34 0.26 propachlor C11H14ClNO C NR NR 6-15-50 1-2-3 0.38 0.3 0.25 2,4-D methyl ester C9H8Cl2O3 - ---- 0.38 FP0.5/NI17 0.37 0.32 phorate C7H17O2PS3 C V # V # 6 1 0.4 NI0.3 0.56 0.32 chlordene C10H6Cl6 - C C 6 1 0.4 FP6/NI4.5 0.51 0.44 diazinon C12H21N2O3PS C C C 15 3 0.42 NP20 0.47 0.53 terbumeton C10H19N5O C ---- 0.43 0.32 0.25 chlorpropham C10H12ClNO2 C C C 15 2 0.44 0.32 0.36 3, 5, 6-trichloro-2-pyridinol methyl C6H4Cl3NO - ---- ester 0.44 0.45 - silvex methyl ester C10H9Cl3O3 - ---- 0.44 0.5 0.41 terbufos C9H21O2PS3 C P S 6 - 0.44 NI1 0.38 0.36 sulfallate C8H14ClNS2 C C C 6+15 2 0.46 NI1 0.53 0.3 profluralin C14H16F3N3O4 V V - 6 - 0.46 0.51 0.46 quintozene C6Cl5NO2 C C C 6 1 0.48 0.4 0.35 BHC, alpha- C6H6Cl6 C C C 6 1 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–83 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.49 0.31 0.32 metasystox thiono* C6H15O3PS2 - ---- 0.49 NI(WB)1.5 0.56 0.47 methyl 3,5-dibromo-4-methoxy= C9H8Br2O3 - ---- benzoate 0.49 0.28 0.32 metasystox thiol C6H15O3PS2 C ---- 0.49 0.46 0.31 oxydemeton-methyl C6H15O4PS2 C ---- 0.5 NI(WB)70 0.25 0.16 cymoxanil C7H10N4O3 V NR NR 6-15-50 1-2-3 0.51 NI0.5 0.26 0.23 RPA 203328, methylated C10H9F3O4S - ---- 0.51 0.41 0.4 thiometon C6H15O2PS3 C NR NR 6-15-50 - 0.52 0.83 0.6 heptachlor C10H5Cl7 C C C 6 1 0.53 NI600 0.5 0.24 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 0.53 NI60 0.5 0.47 diazinon oxygen analog C12H21N2O4P C NR NR 6-15-50 1-2-3 0.53 0.39 0.38 fonofos oxygen analog C10H15O2PS V NR NR 6-15-50 1-2-3 0.56 0.52 0.44 fonofos C10H15OPS2 C C C 6 2+3 0.56 0.41 0.41 demeton-S C8H19O3PS2 C NR - 6-15-50 - 0.58 1.05 0.76 aldrin C12H8Cl6 C C C 6 1 0.59 NI150 0.45 0.46 clomazone C12H14ClNO2 C - 50 3 0.59 NI30 0.58 0.51 etrimfos C10H17N2O4PS C C C 15 2+3 0.59 0.5 0.45 pentachlorobenzonitrile C7Cl5N C C P 15 2 0.6 NI1.6 0.46 0.39 furilazole C11H13Cl2NO3 C S - 50 3 0.6 NP10 0.35 0.38 2,3,5-trimethacarb C11H15NO2 C S # NR 50 1-2-3 0.6 0.54 0.46 disulfoton C8H19O2PS3 C P # NR 6 1-2-3 0.61 0.65 0.56 diisobutyl phthalate C16H2204 - P - 15+50 - 0.62 - - 2,4-D isopropyl ester* C11H12Cl2O3 - ---- 0.62 0.62 0.49 2,4-D isobutyl ester C12H14Cl2O3 - ---- 0.63 0.49 0.47 2,4,5-T methyl ester C9H7Cl3O3 - ---- 0.63 NI250 0.38 0.26 3-methyl-4-nitrophenol C7H7O3N V NR NR 6-15-50 1-2-3 0.63 NI0.4 0.56 0.56 2,3,5,6-tetrachloronitroanisole C7H3Cl4NO3 - C - 6 1+2 0.64 0.82 0.67 chlordene, alpha- C10H6Cl6 - ---- 0.64 FP5 0.15 0.19 acephate C4H10NO3PS C ---- 0.64 0.67 0.56 dichlofenthion C10H13Cl2O3PS C C V 6 2 0.65 1.34 1.43 merphos* C12H27PS3 - C C 6+15+50 3 0.65 0.84 - chlordene epoxide C10H6Cl6O - C - 15 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–84 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.65 NI37 0.53 0.41 propazine C9H16ClN5 C S NR 15+50 3 0.65 0.67 - 2,4,5-T isopropyl ester C11H11Cl3O3 - ---- 0.66 0.68 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 0.69 NI1.6 0.5 0.48 4-(dichloroacetyl)-1-oxa-4-azapiro= C10H15Cl2NO2 C P - 50 3 [4.5]decane 0.69 NI0.5 0.94 0.87 pentachlorophenyl methyl sulfide C7H3Cl5S C C C 6 1 0.69 0.48 0.47 lindane C6H6Cl6 C C C 6 1 0.7 NI2550 0.35 0.41 methabenzthiazuron C10H11N3OS C NR NR 6-15-50 1-2-3 0.71 NI43 0.47 0.48 terbuthylazine C9H16N5Cl C P - 15+50 - 0.72 0.62 - 2,4-DB methyl ester C11H12Cl2O3 - ---- 0.73 NI0.5 0.59 0.66 2,3,5,6-tetrachloroanisidine C7H5Cl4NO - C - 6 2 0.74 0.69 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 0.74 0.42 0.33 2,4-D isopropyl ester* C11H12Cl2O3 - ---- 0.74 0.43 0.44 atrazine C8H14ClN5 C S # NR 50 1-2-3 0.75 0.42 0.45 chlorbufam C11H10ClNO2 C - 15 2+3 0.76 0.53 0.37 fluchloralin C12H13ClF3N3O4 C C - 6 2 0.78 NP200 0.45 0.5 3,4,5-trimethacarb C11H15NO2 C NR NR 50 1-2-3 0.79 NI160 0.5 0.44 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 0.79 NI0.5 0.67 0.66 pentachloroaniline C6H2Cl5N C C C 6 1 0.8 0.51 0.63 etrimfos oxygen analog C10H17N2O5P C ---- 0.8 NI20 0.55 0.63 isazofos C9H17ClN3O3PS C C # - 50 2+3 0.8 NI2 0.75 0.68 CGA 14128 C12H21N2O4PS C - 50 1-2-3 0.8 NI80 0.3 0.53 desethyl simazine C5H8ClN5 - NR NR 50 1-2-3 0.83 NI130 0.41 0.5 simazine C7H12ClN5 C NR NR 50 1-2-3 0.84 0.98 0.89 chlordene, beta- C10H6Cl6 - ---- 0.84 NI3 0.51 0.4 pronamide C12H11Cl2NO C P - 15+50 - 0.85 NI1 0.81 0.75 tridiphane C10H7Cl5O C C - 6 1+2 0.85 0.81 - chloroxuron C15H15ClN2O2 C NR NR 6-15-50 1-2-3 0.86 0.72 0.79 chlorpyrifos-methyl C7H7Cl3NO3PS C C - 6 2 0.86 NI20 0.2 0.61 desdiethyl simazine C3H4ClN5 - NR NR 6-15-50 1-2-3 0.86 0.55 1.04 tetraiodoethylene C2I4 - P P 6 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–85 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.86 NI2 0.81 0.76 ronnel C8H8Cl3O3PS C C C 6 2 0.88 NI5 0.75 0.67 acetochlor C14H20NO2Cl C C # P 50 3 0.89 NI1 0.98 0.88 chlordene, gamma- C10H6Cl6 - ---- 0.91 1.08 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 0.91 NI180 0.48 0.48 monolinuron C9H11ClN2O2 C ---- 0.92 NI(WB)13 0.25 0.28 oxamyl oxime metabolite C5H10N2O2S C NR NR 6-15-50 1-2-3 0.92 0.55 - dichlone C10H4Cl2O2 P S # S # 6-15-50 2+3 0.92 0.88 0.84 dibutyl phthalate C16H22O4 - C C 15+50 - 0.93 NI600 2 0.44 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 0.93 NI1 0.52 0.44 dinitramine C11H13F3N4O4 C - P 15 - 0.94 1.33 1.05 octachlor epoxide C10H4Cl8O C C C 6 1 0.95 1.53 - Perthane olefin C18H19Cl - C C 6 1 0.96 0.31 0.43 dicrotophos C8H16NO5P C NR - 6-15-50 - 0.96 0.42 0.45 dicloran C6H4Cl2N2O2 C S P 15+50 2+3 0.97 NI(WB)6 0.42 0.49 PPG-947, methylated* C18H13ClF3NO7 - ---- 0.97 NP50 0.94 0.66 prodiamine C13H17F3N4O4 C ---- 0.98 0.72 - dimethenamid C12H18ClNO2S - NR NR 6-15-50 1-2-3 1 NI150 1.05 - PP 890 C9H10O2ClF3 - ---- 1 0.94 0.98 thiobencarb C12H16ClNOS C V 15 2+3 1 NI6 0.8 0.72 alachlor C14H2OClNO2 C C C # 50 3 1 1 1 chlorpyrifos C9H11Cl3NO3PS C C P 6 2 1.02 0.64 0.62 ronnel oxygen analog C8H8Cl3O4P C NR - 6-15-50 - 1.03 1.14 1.14 pirimiphos-ethyl C13H24N3O3PS C C C 15+50 3 1.03 0.44 - chloramben methyl ester C8H7Cl2NO2 - ---- 1.06 NI2 0.64 0.7 benoxacor C11H11Cl2NO2 C P C 15+50 2+3 1.07 0.82 0.92 dichlorobenzophenone, o,p'- C13H8Cl2O - C C 15 2 1.08 4.1 0.91 dicofol, o,p'-* C14H9Cl5O C V S 6+15 2 1.08 0.84 - terbutryn C10H19N5S C ---- 1.1 0.77 - ametryn C9H17N5S C ---- 1.11 NI20 0.71 0.71 dimethachlor C13H18ClNO2 C ---- 1.11 FP5 0.25 0.39 omethoate C5H12NO4PS C NR NR 6-15-50 1-2-3 1.13 NI1 1.06 1 DCPA C10H6Cl4O4 C C C 15 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–86 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 1.15 0.69 0.64 vinclozolin C12H9Cl2NO3 C C C 15 2 1.15 1.19 1.2 TDE, o,p'-, olefin C14H9Cl3 - ---- 1.16 NI(WB)55 0.39 0.54 4-chlorobenzylmethyl sulfoxide C8H9ClOS - NR NR 6-15-50 1-2-3 1.18 1.66 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 1.19 2.85 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 1.2 NI(WB)8 0.74 0.66 vinclozolin metabolite B C12H11Cl2NO4 C P # C 6+15 2 1.21 NI9 1.03 0.93 metolachlor C15H22ClNO2 C S # NR 50 1-2-3 1.21 2.02 - simetryn C8H15N5S C ---- 1.22 NI8 1.15 0.93 butralin C14H21N3O4 V C - 6+15+50 - 1.22 NI2 1.37 1.12 S-bioallethrin C19H26O3 - C - 50 - 1.22 0.64 0.74 cyprazine C9H14ClN5 C ---- 1.22 1.29 1.15 heptachlor epoxide C10H5Cl7O C C C 6 2 1.22 1.36 - allethrin C19H26O3 - C C # 50 3 1.24 NI2 1.14 1.01 isopropalin C15H23N3O4 C C - 6 - 1.25 0.99 1.08 dichlorobenzophenone, p,p'- C13H8Cl2O - C C 15 2 1.28 4.4 1.08 dicofol, p,p'-* C14H9Cl5O C V P # 6+15 1+2 1.28 1.55 1.51 DDE, o,p'- C14H8Cl4 C C C 6 1 1.29 NI160 0.73 0.52 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 1.29 NI6 1.11 1.16 bromophos C8H8BrCl2O3PS C C C 6 - 1.3 0.39 0.52 2,6-dichlorobenzamide C7H5NOCl2 C NR NR 6-15-50 1-2-3 1.34 NI(WB)51 0.43 0.6 6-chloro-2,3-dihydro-3,3,7-methyl- C9H13ClN2O2 - NR NR 6-15-50 1-2-3 5H-oxazolo(3,2-a)pyrimidin-5-one 1.36 NI3 1.45 1.45 TDE, p,p'-, olefin C14H9Cl3 C C C 6 1 1.38 1.64 1.47 endosulfan I C9H6Cl6O3S C C C 15 2 1.4 0.6 0.78 ethiofencarb C10H15NO2S C NR NR 6-15-50 - 1.41 NI200 3.38 4.9 desmethyl norflurazon C11H7ClF3N3O V NR NR 6-15-50 1-2-3 1.41 NI15 0.56 0.55 metribuzin, diketo metabolite C7H12N4O2 NR NR NR 6-15-50 1-2-3 1.41 NI(WB)80 0.55 0.9 3-ketocarbofuran C12H12NO4 S NR NR 6 1 1.42 - - 2,4-D propylene glycol butyl ether C15H2OCl2O4 - ---- ester* 1.42 1.51 1.45 bromophos-ethyl C10H12BrCl2O3PS C C P 6 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–87 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 1.44 0.67 0.69 metobromuron C9H11BrN2O2 C NR NR 6-15-50 1-2-3 1.44 0.55 0.74 chlorothalonil C8Cl4N2 S C # C # 6-15-50 2+3 1.45 NI1.5 0.96 0.86 nitrofluorfen C13H7ClF3NO3 C C C 15 2 1.45 1.75 1.42 nonachlor, trans- C10H5Cl9 C C C 6 1 1.46 0.97 - methazole C9H6Cl2N2O3 - ---- 1.46 1.49 1.34 chlordane, trans- C10H6Cl8 C C C 6 1 1.46 0.96 1.18 fenthion C10H15O3PS2 C S # NR 6+15 1-2-3 1.47 NI(WB)300 1.05 0.88 acifluorfen C14H7ClF3NO3 - NR NR 6-15-50 1-2-3 1.47 0.54 0.62 fenfuram C12H11NO2 C ---- 1.47 NI0.7 0.57 0.91 metribuzin C8H14N4OS V NR NR 50 1-2-3 1.48 NI100 6.1 4.5 tralkoxydim* C20H27NO3 V NR NR 50 1-2-3 1.48 NI3 1.22 1.21 pendimethalin C13H19N3O4 C C P 15 2 1.49 NI44 0.91 1.05 malathion C10H19O6PS2 C C C 15+50 3 1.51 - - 2,4-D ethyl hexyl ester* C16H22Cl2O3 - ---- 1.51 0.95 1.08 chlorpyrifos oxygen analog C9H11Cl3NO4P C NR - 6-15-50 - 1.54 1.66 1.48 chlordane, cis- C10H6Cl8 C C C 6 1 1.55 0.75 0.79 prothoate C9H20NO3PS2 C ---- 1.55 0.68 0.87 malathion oxygen analog C10H19O7PS C NR NR 6-15-50 1-2-3 1.58 NI5 1.21 1.29 chlorfenvinphos, alpha- C12H14Cl3O4P C - NR 6-15-50 - 1.59 1.92 1.86 DDE, p,p'- C14H8Cl4 C C C 6 1 1.6 FP3 0.31 0.5 monocrotophos C7H14NO5P C NR NR 6-15-50 1-2-3 1.6 0.4 0.62 dimethoate C5H12NO3PS2 C NR NR 6-15-50 1-2-3 1.61 2.04 2.69 cyproconazole C15H18ClN3O C NR NR 6-15-50 1-2-3 1.62 NI1 0.77 0.99 Tycor C9H16N4OS C S S 50 3 1.62 0.43 0.56 BHC, beta- C6H6Cl6 C C C 6 1 1.62 1.39 1.54 chlorbenside C13H10Cl2S C S P 6 1 1.63 NI1 0.99 1.07 1-hydroxychlordene C10H6Cl6O - R - 15 - 1.64 1.95 1.88 merphos* C12H27PS3 - C C 6+15+50 3 1.64 NI3/NP20 1.05 1 triadimefon C14H16ClN3O2 C S # S # 50 1-2-3 1.64 FP1/NI11 0.71 0.87 parathion-methyl C8H10NO5PS C C C 15 2 1.64 NI30 0.6 0.7 ethoxyquin C14H19N0 C NR NR 6-15-50 - 1.65 1.95 1.88 tribufos C12H27OPS3 C C P 15+50 3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–88 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 1.67 - 1.44 2,4-D butoxyethyl ester* C14H18Cl2O4 - ---- 1.67 NI6 2.75 2.38 chlordecone C10H8Cl10O5 - S # P # 15+50 1-2-3 1.71 0.9 1.01 dichlofluanid C9H11Cl2FN2O2S2 C C # - 15+50 2+3 1.71 0.55 0.66 parathion-methyl oxygen analog C8H10NO6P - NR NR 6-15-50 1-2-3 1.71 0.5 0.67 BHC, delta- C6H6Cl6 C C C 6+15 1 1.73 1.36 1.38 isofenphos C15H24NO4PS C C - 15+50 - 1.74 NI1 1.85 1.82 prothiofos C11H15Cl2PO2S2 C C C 6 2 1.74 FP5 1.17 1.24 isofenphos oxygen analog C15H24NO5P C ---- 1.76 2.12 1.76 pyrethrins* C21H27O4 - C C 50 - 1.78 2.04 1.78 2,4-D isooctyl ester* C16H22Cl2O3 - ---- 1.78 2.1 1.68 2,4-D ethyl hexyl ester* C16H22Cl2O3 - ---- 1.79 2 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 1.82 0.84 1.05 fenitrothion C9H12NO5PS C C C 15 2 1.83 NI14 1.73 1.46 butachlor C17H26ClNO2 C C - 50 - 1.84 NI6 1.57 1.64 cyclanilide methyl ester C12H11Cl2NO3 - ---- 1.87 1.91 1.84 dieldrin C12H8Cl6O C C C 15 2 1.88 1.24 1.47 anilazine C9H5Cl3N4 V S P 15+50 2+3 1.89 NI1000 1.39 1.54 CGA 189138 C13H8O3Cl2 - ---- 1.91 NI3/NP65 0.99 0.96 KWG 1323 C14H16ClN3O3 C NR NR 6-15-50 1-2-3 1.91 NI(WB)2 0.41 0.66 4-chlorobenzylmethyl sulfone C8H9ClO2S - NR NR 6-15-50 1-2-3 1.91 FP2/NI6 0.98 1.07 parathion C10H14NO5PS C C C 15 2 1.93 FS56/NI638 0.86 1.02 ethofumesate C13H18O5S C ---- 2 FP4/NI5 1.29 1.52 chlorfenvinphos, beta- C12H14Cl3O4P C S # - 50 1-2-3 2 1.32 1.64 quinalphos C12H15N2O3PS C C - 15 - 2.01 NI(WB)2 0.69 0.79 vinclozolin metabolite S C10H7Cl2NO3 V P V # 15 2 2.01 2.23 2.42 Perthane C18H2OCl2 C C C 6 1 2.02 0.5 0.5 tris(chloropropyl) phosphate C9H18Cl3O4P C NR NR 6-15-50 1-2-3 2.03 NI1.5 - - fenson C12H10O3ClS - ---- 2.05 1.31 1.83 phenthoate C12H17O4PS2 C C - 15+50 - 2.08 1.82 1.79 2,4-D butoxyethyl ester* C14H18Cl2O4 - ---- 2.09 3.22 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 2.1 NI(WB)3.8 0.8 - bromacil methyl ether C10H16BrN2O2 - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–89 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 2.1 NI(WB)7 0.54 0.72 terbacil C9H13ClN2O2 C NR NR 6-15 2+3 2.13 0.85 0.95 linuron C9H10Cl2N2O2 V V # V 50 3 2.22 2.13 2.29 endrin C12H8Cl6O C C # C # 15 2 2.23 1.44 1.19 triflumizole C15H15ClF3N3O C ---- 2.25 NI30 0.45 0.71 methidathion sulfoxide C5H8N2O4S2 - NR NR 6-15-50 1-2-3 2.27 NI(WB)630 1.35 2.55 3-tert-butyl-5-chloro-6-hydroxy= C9H13ClN2O3 - NR NR 6-15-50 1-2-3 methyluracil 2.27 2.55 2.7 DDT, o,p'- C14H9Cl5 C C C 6 1 2.29 NI400 0.56 0.82 methidathion sulfone C5H8N2O3S2 - NR NR 6-15-50 1-2-3 2.33 NI3 2.64 2.8 tetrasul C12H6Cl4S C C C 6 1 2.33 1.08 1.3 crufomate C12H19ClNO3P C NR NR 6-15-50 - 2.33 NI6250 0.5 0.66 ethylenethiourea C3H6N2S S NR NR 6-15-50 1-2-3 2.34 1.8 2.13 profenofos C11H15BrClO3PS C P P 50 3 2.36 NI3000 2.3 2.31 fluazifop butyl ester C19H20F3NO4 C C V 15 3 2.46 1.58 2.1 triazamate C13H22N4O3S C NR NR 6-15-50 1-2-3 2.46 1.9 2.19 TDE, o,p'- C14H10Cl4 - C C 6 1 2.48 1.97 1.96 oxadiazon C15H18Cl2N2O3 C C P 15 - 2.49 NI20 0.44 0.64 prosulfuron* C15H16F3N5O4S - NR NR 6-15-50 1-2-3 2.55 0.89 1.26 phorate sulfoxide C7H17O3PS3 C NR NR 6-15-50 1-2-3 2.65 NI300 0.6 0.9 CGA 120844 C8H9NSO3 - NR NR 6-15-50 1-2-3 2.66 - - 2,4,5-T butoxyethyl ester* C14H17Cl3O4 - ---- 2.66 2.53 - Compound K* C10H6Cl8 - C - - 1 2.67 0.75 - picloram methyl ester C7H5Cl3N2O2 - ---- 2.67 HN4 1.28 1.58 mecarbam C10H20NO5PS2 C - 50 - 2.69 - - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 2.71 FS2 0.41 0.81 dimethipin C6H10O4S2 C NR NR 6-15-50 1-2-3 2.72 1.58 1.97 Gardona C10H9Cl4O4P C NR NR 6-15-50 1-2-3 2.73 1.21 1.5 des N-isopropyl isofenphos C12H18NO4PS C S - 50 - 2.74 3.03 2.88 ethephon C2H6ClO3P NR - 6+15+50 1+2+3 2.77 2 - aramite* C15H23ClO4S C P NR 15 - 2.78 3.3 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 2.82 NI8 0.66 0.78 propanil C9H9Cl2NO C NR NR 6-15 3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–90 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 2.84 2.95 2.7 pyrethrins* C21H27O4 - C C 50 - 2.85 NI(WB)780 0.35 0.4 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 2.85 1.37 1.9 crotoxyphos C14H19O6P C NR NR 6-15-50 1-2-3 2.89 FS63/NI10 0.68 0.93 2,3-dihydro-3,3-methyl-2-oxo-5- C11H12O5S - ---- benzofuranyl methyl sulfonate 2.9 FP5/NI1500 0.92 1.28 terbufos oxygen analog sulfone C9H21O5PS2 C NR NR 6-15-50 1-2-3 2.9 2.33 2.41 chloropropylate C17H16Cl2O3 P C C 15+50 3 2.91 1.86 1.79 hexaconazole C14H17Cl2N3O C ---- 2.95 0.71 0.96 demeton-O sulfone* C8H19O5PS2 C ---- 2.95 5.8 5.6 mirex C10Cl12 P C P 6 1 3 FP15/NI300 1.08 1.66 fosthiazate C9H18NO3PS2 C NR NR 6-15-50 1-2-3 3.01 1.23 1.94 folpet C9H4Cl3O2NS C C P 15+50 2+3 3.02 NI(WB)9 0.89 0.93 vinclozolin metabolite E C11H11Cl2NO2 C S NR 15+50 - 3.02 NI(WB)10 2 3.38 kresoxim-methyl C18H19NO4 P C C 15+50 3 3.04 NI7 1.37 1.49 procymidone C13H11Cl2NO2 C C P 15 - 3.04 NI3 1.61 2.2 ovex C12H8Cl2O3S C C C 15 2 3.05 2.14 - aramite* C15H23ClO4S C P NR 15 - 3.1 2.56 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 3.14 NI14 1.78 2 diethatyl-ethyl C16H22ClNO3 C NR NR 6-15-50 1-2-3 3.16 NI(WB)120 1.9 1.86 PPG-2597 C20H17ClF3NO6 - NR NR 6-15-50 1-2-3 3.24 NI5 2.38 3.14 leptophos photoproduct C13H11Cl2O2PS C ---- 3.26 0.97 1.3 phorate sulfone C7H17O4PS3 C S # S # 6-15-50 3 3.26 2.31 2.61 chlorobenzilate C16H14Cl2O3 C C # P # 15+50 3 3.28 5.3 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 3.3 2.91 - 2,4,5-T butoxyethyl ester* C14H17Cl3O4 - ---- 3.33 NI3 2.52 2.61 nonachlor, cis- C10H5Cl9 C C C 6 1 3.33 NI50 1.4 2.28 methidathion C6H11N2O4PS3 C S P # 50 3 3.39 1.27 1.42 chlorbromuron C9H10BrClN2O2 V V V 50 3 3.4 2.96 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 3.4 NI7 2.02 2.03 diclobutrazol C15H19Cl2N3O C NR NR 6-15-50 1-2-3 3.49 1.2 1.85 captan C9H8Cl3NO2S C P C 50 3 3.5 1.79 2.76 imazamethabenz methyl ester* C16H20N2O3 C ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–91 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 3.5 1.26 1.92 Sulphenone C12H9ClO2S C - 50 3 3.6 NI(WB)780 0.55 0.95 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 3.6 1.54 - 2,4-D propylene glycol butyl ether C15H2OCl2O4 - ---- ester* 3.6 3.13 3.5 DDT, p,p'- C14H9Cl5 C C C 6 1 3.7 2 2.6 bupirimate C13H24N4SO3 C ---- 3.7 NP6 1.66 2.41 fenamiphos C13H22NO3PS C NR NR 6-15-50 1-2-3 3.7 NI9 2.97 4.2 methoxychlor olefin C16H14Cl2O2 C C C 6 2 3.7 1.42 - fenac C8H5Cl3O2 - NR NR 6-15-50 - 3.77 NI60 0.83 1.06 metribuzin, deaminated metabolite C8H13N3OS C NR NR 6-15-50 1-2-3 3.8 3.25 - 2,4,5-T isooctyl ester* C16H21Cl3O3 - ---- 3.8 4.9 4.5 bifenthrin C23H22ClF3O2 V C - 6+15 2 3.8 NI3 2.03 2.71 nitrofen C12H7Cl2NO3 C C C 15 2 3.8 2.41 2.87 TDE, p,p'- C14H10Cl4 C C C 6 1 3.9 2.21 2.77 endosulfan II C9H6Cl6O3S C C C 15+50 2 3.93 FP2/NI8 2.56 3.36 ethion C9H22O4P2S4 C C C 6 2 4 NI(WB)13 2.51 4.2 pyrithiobac-sodium methyl ester C14H13ClN2O4 - ---- 4 2 2.16 oxyfluorfen C15H11ClF3NO4 C C C 15 2 4 1.76 2.08 imazalil C14H14Cl2N2O C NR NR 6-15-50 - 4.1 FP6 2.22 2.99 chlorthiophos oxygen analog C11H15Cl2O4PS C NR NR 6-15-50 1-2-3 4.1 1.6 3.17 isoprothiolane C12H18O4S2 C ---- 4.1 1.88 - ethion oxygen analog C9H22O5P2S3 C ---- 4.2 2.17 3.06 carbophenothion oxygen analog C11H16ClO3PS2 C NR NR 6-15-50 1-2-3 4.2 2.94 3.7 carbophenothion C11H16ClO2PS3 C C P 6 2 4.2 2.19 2.38 binapacryl C15H18N2O6 C P P 15 - 4.3 NI160 2.4 3 imazethapyr ammonium salt methyl C16H21N3O3 - ---- ester 4.3 1.15 1.54 CGA 91305 C10H8Cl2N3O V NR NR 6-15-50 1-2-3 4.3 NI12 1.5 2.67 TCMTB C9H6N2S3 C P P 15 - 4.5 32 - hydramethylnon* C25H24F6N4 - ---- 4.5 NI23 3.3 5 methoxychlor, o, p'- C16H15Cl3O2 - C - 6 - 4.5 6.4 6.1 bis(2-ethylhexyl) phthalate C24H38O4 - C C 15+50 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–92 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 4.7 NI60 1.13 1.38 RPA202248 C15H12SNO4F3 NR NR NR 6-15-50 1-2-3 4.7 NI40 1.11 1.33 isoxaflutole (prop) C15H12SNO4F3 NR V # S # 50 3 4.7 2.85 - chlornitrofen C12H6Cl3NO3 C C C 6+15 2 4.8 5.4 6.5 phenothrin* C23H26O3 - ---- 4.8 - - Dilan* C15.5H14Cl2NO2 - P P 15 - 4.8 NI1300 3.8 4.3 propargite C19H26O4S C C - 15 2 4.8 NI(WB)12 0.8 1.36 bromacil C9H13BrN2O2 C NR NR 6-15-50 1-2-3 4.9 NI12 3.57 4.7 diclofop-methyl C16H14Cl2O4 C C C 15 2 4.9 0.89 1.48 cyanazine C9H13ClN6 C NR - 6-15-50 - 5 NI(WB)6 2.14 2.4 PPG-947, methylated* C18H13ClF3NO7 - ---- 5 NI(WB)4 2.15 2.4 PPG-847, methylated C15H9ClF3NO3 - ---- 5.1 4.1 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 5.1 3.06 4.5 butyl benzyl phthalate C19H20O4 - C P 15+50 - 5.3 - - Dilan* C15.5H14Cl2NO2 - P P 15 - 5.5 5.5 9.1 phosalone C12H15ClNO4PS2 C C C 50 2+3 5.6 3.21 4 propiconazole* C15H17Cl2N3O2 C NR NR 6-15-50 1-2-3 5.8 2.33 - Dilan* C15.5H14Cl2NO2 - P P 15 - 5.8 FP60 1.15 1.75 demeton-S sulfone C8H19O5PS2 C ---- 5.8 NI(WB)5 3.26 4.67 clodinafop-propargyl C17H13ClFNO4 V V - 50 3 6.3 2.87 5.3 edifenphos C14H15O2PS2 C ---- 6.5 NI5 1.53 2.41 CGA 94689A C15H21NO5 V NR NR 6-15-50 1-2-3 6.5 4.4 - bromopropylate C17H16Br2O3 C C # C # 15+50 1-2-3 6.6 FS175/NI400 1 1.46 2-hydroxy-2,3-dihydro-3,3-methyl-5- C11H14O5S - ---- benzofuranyl methyl sulfonate 6.6 NI8 1.54 2.45 CGA 94689B C15H21NO5 S NR NR 6-15-50 1-2-3 6.6 NI(WB)5 4.8 6.3 cloquintocet-mexyl C18H22ClNO3 V NR - 6-15-50 1-2-3 6.7 1.5 2.39 disulfoton sulfone C8H19O4PS3 C NR - 6-15-50 - 6.9 4.3 4.4 dinocap* C18H24N2O6 C P P 15 2 7 NI10 4.8 5.7 fenpropathrin C22H23NO3 - V # V 15 2 7.2 1.9 2.6 myclobutanil C15H17ClN4 C NR NR 6-15-50 1-2-3 7.2 4.7 7.2 methoxychlor, p, p'- C16H15Cl3O2 C C C 6 2 7.3 3.36 4.8 nuarimol C17H12ClFN2O C NR C # 50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–93 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 7.5 2.81 - Dilan* C15.5H14Cl2NO2 - P P 15 - 7.5 NI10 2.81 3.9 Prolan C15H13Cl2NO2 P S S 15 2 7.5 NI6 3.06 4.4 Bulan C16H15Cl2NO2 C P P 15 2 7.6 4.2 6.5 leptophos oxygen analog C13H10BrCl2O3P C ---- 7.7 7 - 2,4,5-T BEP ester* C17H23Cl3O3 - ---- 7.7 4.8 4.8 dinocap* C18H24N2O6 C P P 15 2 7.7 5.8 8.5 1 leptophos C13H10BrCl2O2PS C C C 6 2 7.9 1.5 - procyazine C10H13ClN6 C ---- 8 NI6 1.25 1.09 MB45950 C12H4SN4F6Cl2 S P V 15+50 2+3 8.2 3.39 - Dilan* C15.5H14Cl2NO2 - P P 15 - 8.2 3.1 4.6 cyanofenphos C15H14NO2PS C ---- 8.3 2.83 4 endosulfan sulfate C9H6Cl6O4S C C C 50 2 8.4 NI6 4.3 6 benzoylprop-ethyl C18H17Cl2NO3 P NR NR 6-15-50 1-2-3 8.5 4.5 7.2 tetramethrin* C19H25NO4 C NR NR 6-15-50 1-2-3 8.6 NI7 4.7 7.2 tetrasul sulfoxide C12H6Cl4OS - ---- 8.7 NI10 1.35 1.16 fipronil C12H4Cl2F6N4OS S S V 50 3 8.9 NI500 12 6.1 CGA 205374 C16H11N3O2Cl2 - NR NR 6-15-50 1-2-3 8.9 1.3 - chlorsulfuron C12H12ClN5O4S - NR NR 6-15-50 - 9.5 5.1 5.6 dinocap* C18H24N2O6 C P P 15 2 9.7 4.8 6.8 piperophos C14H28NO3PS2 C ---- 10.3 FP15 4.7 6.9 chlorthiophos sulfoxide C11H15Cl2O4PS2 C NR NR 6-15-50 1-2-3 10.3 3.6 - endrin ketone C12H8Cl6O - C C 50 2 10.6 4.5 6.9 EPN C14H14NO4PS C C C 15 2 10.8 NI20 7.9 12.6 HOE-030291 C17H16Cl2O5 - ---- 10.9 11.5 15 phenothrin* C23H26O3 - ---- 11.1 9.4 13.8 permethrin, cis- C21H20Cl2O3 C V # C 6+15 2 11.3 8.1 10.5 fenoxaprop ethyl ester C18H16NO5Cl S V V 50 3 11.5 NI60 2.96 4.1 CL 202,347 C13H19N3O5 - ---- 12.8 NI40 10.4 8.9 acrinathrin C26H21F6NO5 V V V # 15 2 13 10.2 - 2,4-D BEP ester* C17H24Cl2O4 - ---- 13 10.2 15 permethrin, trans- C21H20Cl2O3 C V # C 6+15 2 13 NI3700 2.67 8 pyrazon C10H8ClN3O C NR NR 6-15-50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–94 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 13 NI1200 13 16 hexachlorophene C13H6Cl6O2 - NR NR 6-15-50 - 14 NI4500 2.5 5 oxadixyl C14H18N2O4 C NR NR 6-15-50 1-2-3 14 4.2 8.7 pyridaphenthion C14H17O4N2SP C ---- 14 2.65 5 famphur C10H16NO5PS2 C NR - 6-15-50 - 14.8 NI600 3.1 7.1 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 14.9 5 8.8 bifenox C12H9Cl2NO5 C C P 15+50 2+3 14.9 FP50 4 8.4 phosmet C11H12O4NPS2 C NR - 6-15-50 3 15 2.31 3.93 desisopropyl iprodione C10H6Cl2N3O3 P - 50 1-2-3 15 NP1000 4 4.2 KWG 1342 C14H18ClN3O3 - ---- 15.5 4.4 8.5 photodieldrin C12H8Cl6O - C C 15+50 2 18 NI75 4.2 6.3 iprodione* C13H13Cl2N3O3 C S # NR 50 1-2-3 18.1 - - carbofuran-7-phenol-DNP ether C16H14N2O6 - ---- 18.6 NI44 2.62 5.4 ofurace C14H16NO3Cl C ---- 18.8 FP39 5.3 9.1 chlorthiophos sulfone C11H15Cl2O5PS2 C C - 50 3 19.7 31 38 deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 19.9 29 38 deltamethrin* C22H19Br2NO3 C S # P 15 2 24 16.3 - fluridone C19H14F3NO - NR NR 6-15-50 - 24 NI21 3.8 6.3 nitralin C13H19N3O6S C P P 50 3 29 - - cypermethrin* C22H19Cl2NO3 C C C 15 2 31 NI30 2.06 1.98 MB46136 C12H4SO2N4F6Cl2 S S V 50 2+3 33 14.1 23 cypermethrin* C22H19Cl2NO3 C C C 15 2 36 15.1 25 cypermethrin* C22H19Cl2NO3 C C C 15 2 36.9 14.7 21.4 flucythrinate* C26H23F2NO4 C C - 15 2+3 37.1 3.6 7.5 myclobutanil alcohol metabolite C15H17ClN40 S NR NR 6-15-50 1-2-3 40 NI100 9 18 coumaphos C14H16ClO5PS C NR C # 6-15-50 3 42 16.1 24 flucythrinate* C26H23F2NO4 C C - 15 2+3 44 20.3 35 fenvalerate* C25H22ClNO3 C C C 15 2 45 NI150 8 16 coumaphos oxygen analog C14H16ClO6P C NR NR 6-15-50 1-2-3 51 22.5 40 fenvalerate* C25H22ClNO3 C C C 15 2 53 44 - hydramethylnon* C25H24F6N4 - ---- 53 4.7 11.3 dithianon C14H4O2N2S2 NR ---- 56 - 35 fluvalinate* C26H22ClF3N2O3 C C - 15 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–95 Appendix I: PESTDATA Chemicals in Order by OV-225 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-225 with OV-225 Column OV-101 OV-17 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 57 NI300 23 43 PB-7, methylated C20H25ClN2O3S - ---- 59 25 38 fluvalinate* C26H22ClF3N2O3 C C - 15 2 64 27 44 tralomethrin C22H19Br4NO3 C V S 15 2 87 NI500 25 46 PB-9 C19H25ClN2O2S V NR NR 6-15-50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–96 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–97 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries * Multipeak chemical. # Recovery may vary with choice of Florisil elution system; see Tables 303-a, 304-a. 0.02 NI4 0.03 - dichlorobenzene, p- C6H4Cl2 - C C 6 1 0.02 NI0.1 - - hexachloroethane C2Cl6 - ---- 0.03 NI0.2 0.04 - dibromochloropropane C3H5Br2Cl - ---- 0.04 NI10 0.06 0.08 CGA 171683 C6H5F4N3O2 C - 15+50 3 0.04 NI0.1 - - hexachlorobutadiene C4Cl6 - V # P 6 1 0.06 NI0.8 0.12 - hexachlorocyclopentadiene C5Cl6 - ---- 0.07 NI0.1 - - 1,2,3,5-tetrachlorobenzene C6H2Cl4 - P # - 6 1 0.07 NI0.2 - - 1,2,4,5-tetrachlorobenzene C6H2Cl4 - ---- 0.07 NP(WB)1.5 - - 4-chlorobenzeneamine C6H6ClN S NR NR 6-15-50 1-2-3 0.08 FP2.5 0.07 0.08 dichlorvos C4H7Cl2O4P C NR NR 6-15-50 1-2-3 0.09 NP(WB)5 - 0.11 teflubenzuron* C14H6Cl2F4N2O2 - NR NR 6-15-50 1-2-3 0.09 FP1/FP(WB)0.6 0.07 0.25 methamidophos C2H8NO2PS V ---- 0.09 FP11 0.15 - vernolate C10H21NOS - P - 15 - 0.09 NI0.2 - - 1,2,3,4-tetrachlorobenzene C6H2Cl4 - ---- 0.1 NI(WB)1.4/NP23 0.13 0.15 chlorimuron ethyl ester C15H15ClN4O6S P NR - - - 0.1 HX1.5 0.19 0.08 2-methoxy-3,5,6-trichloropyridine C6H4Cl3NO C P # C 6+15 1+2 0.1 NI5 0.17 0.14 N-(3,4-dichlorophenyl)-N'-methylurea C8H8Cl2N2O - NR NR 6-15-50 - 0.1 NI4 0.22 0.14 3,4-dichlorophenylurea C7H6Cl2N2O - NR NR 6-15-50 - 0.1 NI0.6 0.11 - dichlobenil C7H3Cl2N C P C 15 2 0.1 NP6 0.17 - pebulate C10H21NOS C P - 15 - 0.11 NP20 0.17 - CGA 236431 C8H7F3N2O2 - ---- 0.11 FP0.4 - - chlormephos C5H12ClO2PS2 C ---- 0.11 FS30 0.13 0.23 carboxin sulfoxide C12H13NO3S - NR NR 6-15-50 1-2-3 0.11 NI12 0.11 0.09 diuron C9H10Cl2N2O C NR NR 6-15-50 1-2-3 0.12 NI0.2 - - hexachloronorbornadiene C7H2Cl6 - ---- 0.12 NP16 0.13 - propham C10H13NO2 C P P 15 - 0.13 NP8 0.26 - CGA 236432 C9H9F3N2O2 - ---- 0.13 NI1/NP2 0.17 0.22 3-methyl-4-nitrophenol methyl ether C8H9O3N - ---- 0.13 FP2 0.16 - mevinphos, (E)- C7H13O6P C NR NR 6-15-50 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–98 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 0.13 FP4 0.16 - trichlorfon C4H8Cl3O4P C NR NR 6-15-50 1-2-3 0.14 NP(WB)5 0.14 0.23 teflubenzuron* C14H6Cl2F4N2O2 - NR NR 6-15-50 1-2-3 0.14 NP50 0.22 - CGA 72903 C7H6F3N - ---- 0.14 NI1 0.19 0.22 N, N-diallyl dichloroacetamide C8H11Cl2NO C S S 15+50 2+3 0.14 NP2 - - fluometuron C10H11F3N2O - ---- 0.14 NP1 0.22 - CGA 150829 C5H14N4O V ---- 0.14 HN(WB)0.3/HX(WB)2/NI8/ 0.18 0.27 3,5-dichloroaniline C6H5Cl2N S S S 6+15 1+2 NI(WB)14/NP8/NP(WB)0.4 0.14 0.15 0.15 dimethyl phthalate C10H10O4 - P - 6+15+50 - 0.15 FP2/FP(WB)0.6 0.13 - mevinphos, (Z)- C7H13O6P C NR - 6-15-50 - 0.16 HN(WB)3/NI(WB)120/ 0.25 0.5 cymoxanil C7H10N4O3 V NR NR 6-15-50 1-2-3 NP(WB)7 0.16 NI0.3 0.24 0.13 pentachlorobenzene C6HCl5 C C C 6 1 0.16 NI13/NP8 0.2 0.32 3,4-dichloroaniline C6H5Cl2N V S - 15 - 0.17 NI0.7 0.34 0.27 trifluralin C13H16F3N3O4 C C C 6 2 0.18 FP(WB)2 - - metasystox thiono* C6H15O3PS2 - ---- 0.18 HX25 - - metoxuron C10H13ClN2O2 V NR NR 6-15-50 1-2-3 0.18 NI0.3 0.23 0.21 methyl 2,3,6-trichlorobenzoate C8H5Cl3O2 - ---- 0.18 HX(WB)1 0.37 0.28 benfluralin C13H16F3N3O4 C C C 6 2 0.19 HX6 0.34 0.27 ethalfluralin C13H14F3N3O4 C C C 6 2 0.19 FP(WB)0.6 0.15 0.64 acephate C4H10NO3PS C ---- 0.2 FP2 - - demeton-O* C8H19O3PS2 C NR - 6-15 - 0.2 NI160/NP30 0.22 0.25 3-carboxy-5-ethoxy-1,2,4-thiadiazole C3H2N2O3S NR ---- 0.2 - - 4-chlorobiphenyl C12H9Cl - ---- 0.2 HN(WB)1/HX(WB)35/ 0.3 - triflusulfuron methyl ester C17H19F3N6O6S V NR NR 6-15-50 1-2-3 NP(WB)11 0.2 - - epoxyhexachloronorbornene C7H2Cl6O - ---- 0.2 HX(WB)0.6 0.2 0.18 nitrapyrin C6H3Cl4N C C V 6 2 0.21 FP20 0.26 - tebuthiuron C9H16N4OS - ---- 0.21 FP25 0.22 0.32 demeton-O oxygen analog C8H19O4PS - ---- 0.21 HX(WB)0.8/NI0.4/NP0.5 0.18 0.12 etridiazole C5H5Cl3N2OS C C P 6 2 0.22 NI150 0.18 - 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 - NR NR 15-50 1-2-3 methylcarbamate* Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–99 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.22 NI0.2 - - octachlorocyclopentane C5Cl8 - ---- 0.22 HX(WB)0.3 0.24 0.15 2,3,5,6-tetrachloroanisole C7H4Cl4O - C - 6 1 0.23 NI0.4 0.26 0.51 RPA 203328, methylated C10H9F3O4S - ---- 0.23 NI0.2 - - heptachloronorbornene C7H3Cl7 - ---- 0.23 0.3 - tributyl phosphate C12H27O4P - R - 50 - 0.24 FP150 0.5 0.53 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 0.24 FP0.5/HX0.3/NI0.3 0.33 0.23 chlorethoxyfos C6H11Cl4O3PS V C - 6 1 0.24 NI0.3 0.29 0.26 tecnazene C6HCl4NO2 C C C 6 1 0.24 FP(WB)70/NI10000/ 0.21 0.27 TEPP C8H20O7P2 C ---- NP(WB)70 0.25 0.3 0.38 2,4-D methyl ester C9H8Cl2O3 - ---- 0.25 0.34 - 2,4,5-trichloro-alpha-methylbenzene C8H7OCl3 R R - 15 - methanol 0.25 FP1 0.33 0.31 ethoprop C8H19O2PS2 C P # S # 50 1-2-3 0.25 0.29 - diphenylamine C12H11N C S - 6+15 - 0.25 NI80 0.32 0.43 chlorpropham C10H12ClNO2 C C C 15 2 0.26 NI5/NP20 0.38 0.63 3-methyl-4-nitrophenol C7H7O3N V NR NR 6-15-50 1-2-3 0.26 NI5/NI(WB)5 0.34 0.37 propachlor C11H14ClNO C NR NR 6-15-50 1-2-3 0.26 FP0.5 0.26 - thionazin C8H13N2O3PS C P NR 15+50 - 0.27 0.2 - 1,2,4-triazole C2H3N3 V NR NR 6-15-50 1-2-3 0.28 FP3 - - demeton-O sulfone* C8H19O5PS2 C ---- 0.28 HN(WB)0.4/NI(WB)3/ 0.25 0.92 oxamyl oxime metabolite C5H10N2O2S C NR NR 6-15-50 1-2-3 NP(WB)3 0.29 FP(WB)0.4/NI(WB)12/ 0.37 0.27 cadusafos C10H23O2PS2 C NR NR 6-15-50 1-2-3 NP(WB)0.5 0.29 FP0.5 0.34 - sulfotep C8H20O5P2S2 C C P 6+15 2 0.29 NP3 0.28 - G-27550 C8H12N2O C ---- 0.29 FP1 0.3 0.37 phorate oxygen analog C7H17O3PS2 C NR NR 6-15-50 1-2-3 0.3 NI0.8/NP9 0.53 0.46 profluralin C14H16F3N3O4 V V - 6 - 0.31 NI150 0.27 - 4-hydroxymethyl-3,5-dimethylphenyl C11H15NO3 - NR NR 15-50 1-2-3 methylcarbamate* 0.31 FP(WB)4 0.46 0.49 oxydemeton-methyl C6H15O4PS2 C ---- 0.32 FP(WB)2 0.31 0.49 metasystox thiono* C6H15O3PS2 - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–100 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 0.32 NI0.4 0.56 0.4 chlordene C10H6Cl6 - C C 6 1 0.32 FP(WB)0.8 0.28 0.49 metasystox thiol C6H15O3PS2 C ---- 0.32 FP20/NI8 0.34 - naled C4H7Br2Cl2O4P C NR NR 6-15-50 1-2-3 0.32 FP0.5/NI14 0.37 0.38 phorate C7H17O2PS3 C V # V # 6 1 0.33 0.42 0.74 2,4-D isopropyl ester* C11H12Cl2O3 - ---- 0.33 0.42 0.26 di-allate C10H17ClNOS C C - 6 - 0.33 HX0.3/NI0.3 0.45 0.25 hexachlorobenzene C6Cl6 C C P 6 1 0.34 NI0.3 0.46 0.3 pentachlorophenyl methyl ether C7H3Cl5O C C C 6 1 0.35 NI0.3 0.4 0.48 BHC, alpha- C6H6Cl6 C C C 6 1 0.36 FP2 0.28 - demeton-O* C8H19O3PS2 C NR - 6-15 - 0.36 0.32 0.44 3, 5, 6-trichloro-2-pyridinol C6H4Cl3NO - ---- methyl ester 0.36 FP0.7 0.34 - dioxabenzofos C8H9O3PS C P - 15 - 0.36 NI1 0.38 0.44 sulfallate C8H14ClNS2 C C C 6+15 2 0.37 HX3/NI0.5 0.53 0.76 fluchloralin C12H13ClF3N3O4 C C - 6 2 0.38 NP4 0.35 0.6 2,3,5-trimethacarb C11H15NO2 C S # NR 50 1-2-3 0.38 FP4/FP(WB)1 0.39 0.53 fonofos oxygen analog C10H15O2PS V NR NR 6-15-50 1-2-3 0.39 0.36 0.36 triclopyr methyl ester C8H6Cl3NO3 - ---- 0.39 NI1/NP1.8 0.46 0.6 furilazole C11H13Cl2NO3 C S - 50 3 0.39 FP1/NI2500 0.42 - terbufos oxygen analog C9H21O3PS2 C - NR 6-15-50 1-2-3 0.39 FP5/FP(WB)1.1 0.25 1.11 omethoate C5H12NO4PS C NR NR 6-15-50 1-2-3 0.4 HN(WB)30 0.35 2.85 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 0.4 NI1/NP85 0.51 0.84 pronamide C12H11Cl2NO C P - 15+50 - 0.4 FP0.4/NP(WB)1 0.41 0.51 thiometon C6H15O2PS3 C NR NR 6-15-50 - 0.41 NP24 0.35 0.7 methabenzthiazuron C10H11N3OS C NR NR 6-15-50 1-2-3 0.41 NP40 0.32 - phenmedipham C16H16N2O4 - ---- 0.41 FP0.5/FP(WB)1.6/NI20 0.5 0.44 terbufos C9H21O2PS3 C P S 6 - 0.41 NI43 0.53 0.65 propazine C9H16ClN5 C S NR 15+50 3 0.41 FP0.8/FP(WB)0.8 0.41 0.56 demeton-S C8H19O3PS2 C NR - 6-15-50 - 0.42 FP0.5 0.48 - propetamphos C10H20NO4PS C C # - 15+50 2+3 0.42 NP9 0.42 - melamine C3H6N6 NR ---- 0.43 FP1/FP(WB)0.8 0.31 0.96 dicrotophos C8H16NO5P C NR - 6-15-50 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–101 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.44 NI150 0.5 0.79 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 0.44 FP150 2 0.93 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 0.44 NI1 0.52 0.93 dinitramine C11H13F3N4O4 C - P 15 - 0.44 NI20 0.43 0.74 atrazine C8H14ClN5 C S # NR 50 1-2-3 0.44 FP0.7 0.52 0.56 fonofos C10H15OPS2 C C C 6 2+3 0.44 FP0.7/FP(WB)0.9/NI4/ 0.51 0.4 diazinon C12H21N2O3PS C C C 15 3 NP0.25 0.45 NP430 0.9 - formetanate hydrochloride C11H16ClN3O2 - ---- 0.45 NI3 0.5 0.59 pentachlorobenzonitrile C7Cl5N C C P 15 2 0.45 NI1000/NP218 0.44 0.29 desmedipham C16H16N2O4 - ---- 0.45 0.6 - tri-allate C10H16Cl3NOS C C C 6 2 0.45 HN(WB)0.4 0.42 0.75 chlorbufam C11H10ClNO2 C - 15 2+3 0.45 NI0.4 0.42 0.96 dicloran C6H4Cl2N2O2 C S P 15+50 2+3 0.46 HX2/NP11 0.45 0.59 clomazone C12H14ClNO2 C - 50 3 0.46 FP1 0.54 0.6 disulfoton C8H19O2PS3 C P # NR 6 1-2-3 0.46 NI0.5 0.51 0.46 quintozene C6Cl5NO2 C C C 6 1 0.47 NI(WB)1 0.56 0.49 methyl 3,5-dibromo-4-methoxy= C9H8Br2O3 - ---- benzoate 0.47 0.49 0.63 2,4,5-T methyl ester C9H7Cl3O3 - ---- 0.47 NP100 0.4 - CGA 37734 C10H13NO2 C NR NR 6-15-50 1-2-3 0.47 NI30/NP0.6 0.5 0.53 diazinon oxygen analog C12H21N2O4P C NR NR 6-15-50 1-2-3 0.47 NI0.4 0.48 0.69 lindane C6H6Cl6 C C C 6 1 0.48 NI1.1/NP1.2 0.5 0.69 4-(dichloroacetyl)-1-oxa-4-azapiro= C10H15Cl2NO2 C P - 50 3 [4.5]decane 0.48 HX(WB)0.3 0.49 0.35 1,2,4,5-tetrachloro-3-(methylthio)= C7H4Cl4S R C - 6 1 benzene 0.48 NI250 0.47 0.71 terbuthylazine C9H16N5Cl C P - 15+50 - 0.48 HX18 0.48 0.91 monolinuron C9H11ClN2O2 C ---- 0.49 HN(WB)5 0.42 0.97 PPG-947, methylated* C18H13ClF3NO7 - ---- 0.49 NP3 0.46 - CGA 51702 C9H9F3N2O - ---- 0.49 0.62 0.62 2,4-D isobutyl ester C12H14Cl2O3 - ---- 0.5 0.5 2.02 tris(chloropropyl) phosphate C9H18Cl3O4P C NR NR 6-15-50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–102 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 0.5 FP2/FP(WB)0.8 0.31 1.6 monocrotophos C7H14NO5P C NR NR 6-15-50 1-2-3 0.5 NP10 0.45 0.78 3,4,5-trimethacarb C11H15NO2 C NR NR 50 1-2-3 0.5 NI56/NP(WB)1.5 0.41 0.83 simazine C7H12ClN5 C NR NR 50 1-2-3 0.5 FP7/FP(WB)13 0.47 - dioxathion C12H26O6P2S4 V NR - 6-15-50 2 0.51 - - 4,4'-dichlorobiphenyl C12H8Cl2 - ---- 0.51 NI50 0.58 0.59 etrimfos C10H17N2O4PS C C C 15 2+3 0.52 NI150 0.73 1.29 metribuzin, deaminated diketo C7H11N3O2 NR NR NR 6-15-50 1-2-3 metabolite* 0.52 0.39 1.3 2,6-dichlorobenzamide C7H5NOCl2 C NR NR 6-15-50 1-2-3 0.52 FP1 0.58 - schradan C8H24N4O3P2 C NR - 6-15-50 - 0.53 NP(WB)25 0.47 0.42 terbumeton C10H19N5O C ---- 0.53 HN(WB)0.1/HX12 0.3 0.8 desethyl simazine C5H8ClN5 - NR NR 50 1-2-3 0.54 FP2 0.6 - iprobenfos C13H21O3PS C ---- 0.54 NI(WB)16 0.39 1.16 4-chlorobenzylmethyl sulfoxide C8H9ClOS - NR NR 6-15-50 1-2-3 0.55 NI6/NP20 0.56 1.41 metribuzin, diketo metabolite C7H12N4O2 NR NR NR 6-15-50 1-2-3 0.56 HX(WB)0.5 0.56 0.63 2,3,5,6-tetrachloronitroanisole C7H3Cl4NO3 - C - 6 1+2 0.56 NI1 0.43 1.62 BHC, beta- C6H6Cl6 C C C 6 1 0.56 FP0.8/HX(WB)2 0.67 0.64 dichlofenthion C10H13Cl2O3PS C C V 6 2 0.56 0.65 0.61 diisobutyl phthalate C16H2204 - P - 15+50 - 0.57 FP2 0.53 - phosphamidon* C10H19ClNO5P C NR NR 6-15-50 1-2-3 0.58 NP24 0.7 - CP 51214 C14H21NO3 C NR NR 6-15-50 1-2-3 0.59 FP(WB)0.7/NP(WB)1 0.47 - cyanophos C9H10O3NSP C ---- 0.6 HN(WB)0.4/HX(WB)4/ 0.43 1.34 6-chloro-2,3-dihydro-3,3,7-methyl- C9H13ClN2O2 - NR NR 6-15-50 1-2-3 NI(WB)36/NP(WB)2 5H-oxazolo(3,2-a)pyrimidin-5-one 0.6 NI0.4 0.83 0.52 heptachlor C10H5Cl7 C C C 6 1 0.61 HN(WB)0.1/HX25 0.2 0.86 desdiethyl simazine C3H4ClN5 - NR NR 6-15-50 1-2-3 0.62 NP50 - - CGA 27092 C8H7F3N2O - ---- 0.62 NP14 1.09 - fenpropimorph C20H33NO C - 50 1-2-3 0.62 0.54 1.47 fenfuram C12H11NO2 C ---- 0.62 FP135 0.43 - fenthion oxygen analog sulfoxide C10H15O5PS C NR NR 6-15-50 1-2-3 0.62 FP5/FP(WB)1 0.64 1.02 ronnel oxygen analog C8H8Cl3O4P C NR - 6-15-50 - 0.62 FP0.8/FP(WB)0.8/NI5 0.4 1.6 dimethoate C5H12NO3PS2 C NR NR 6-15-50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–103 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.63 0.51 0.8 etrimfos oxygen analog C10H17N2O5P C ---- 0.63 FP(WB)1/NI10/NP0.2 0.55 0.8 isazofos C9H17ClN3O3PS C C # - 50 2+3 0.64 NI120 0.44 2.49 prosulfuron* C15H16F3N5O4S - NR NR 6-15-50 1-2-3 0.64 HX1/NI2 0.69 1.15 vinclozolin C12H9Cl2NO3 C C C 15 2 0.64 0.66 - octhilinone C11H19NOS C ---- 0.66 HN(WB)6/HX(WB)9/ 0.74 1.2 vinclozolin metabolite B C12H11Cl2NO4 C P # C 6+15 2 NI(WB)10/NP(WB)19 0.66 HX0 0.54 - 4-chloro-6-methoxyindole C9H8NOCl - R - 15 - 0.66 HX(WB)0.6 0.59 0.73 2,3,5,6-tetrachloroanisidine C7H5Cl4NO - C - 6 2 0.66 NP(WB)50 0.94 0.97 prodiamine C13H17F3N4O4 C ---- 0.66 NI(WB)0.8 0.41 1.91 4-chlorobenzylmethyl sulfone C8H9ClO2S - NR NR 6-15-50 1-2-3 0.66 FP10 0.55 1.71 parathion-methyl oxygen analog C8H10NO6P - NR NR 6-15-50 1-2-3 0.66 NI0.6/NP10 0.67 0.79 pentachloroaniline C6H2Cl5N C C C 6 1 0.66 NI4500/NP64 0.5 2.33 ethylenethiourea C3H6N2S S NR NR 6-15-50 1-2-3 0.67 NP6 0.73 - CP 108064, methylated C15H21NO4 - ---- 0.67 NI0.6 0.82 0.64 chlordene, alpha- C10H6Cl6 - ---- 0.67 NI5 0.75 0.88 acetochlor C14H20NO2Cl C C # P 50 3 0.67 NI0.5 0.5 1.71 BHC, delta- C6H6Cl6 C C C 6+15 1 0.68 NP2 0.58 - cyromazine C6H10N6 S ---- 0.68 NI0.6/NP2 0.75 0.8 CGA 14128 C12H21N2O4PS C - 50 1-2-3 0.68 NP(WB)65 1.1 - nitrothal-isopropyl C14H17O6N C ---- 0.69 HX10 0.67 1.44 metobromuron C9H11BrN2O2 C NR NR 6-15-50 1-2-3 0.7 NI1/NP7 0.64 1.06 benoxacor C11H11Cl2NO2 C P C 15+50 2+3 0.7 NI12/NP15 0.6 1.64 ethoxyquin C14H19N0 C NR NR 6-15-50 - 0.71 NI8/NP10 0.45 2.25 methidathion sulfoxide C5H8N2O4S2 - NR NR 6-15-50 1-2-3 0.71 NI10 0.71 1.11 dimethachlor C13H18ClNO2 C ---- 0.71 FS(WB)80/HN(WB)0.4/ 0.4 - dazomet C5H10N2S2 S NR - 6-15-50 1-2-3 HX500/NI300 0.72 NP1000 - - 1-methyl cyromazine C7H13N6 - ---- 0.72 NI6 0.8 1 alachlor C14H2OClNO2 C C C # 50 3 0.72 HN(WB)0.6/HX(WB)5/ 0.54 2.1 terbacil C9H13ClN2O2 C NR NR 6-15 2+3 NI(WB)2/NP(WB)8 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–104 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 0.73 FP(WB)2 0.61 - pirimicarb C11H18N4O2 C ---- 0.74 0.64 1.22 cyprazine C9H14ClN5 C ---- 0.74 FP20 0.77 - prometryn C10H19N5S C P # P # 50 1-2-3 0.74 HX1/NI2 0.55 1.44 chlorothalonil C8Cl4N2 S C # C # 6-15-50 2+3 0.75 HX0.8/HX(WB)0.4 0.81 0.85 tridiphane C10H7Cl5O C C - 6 1+2 0.76 FP2 0.67 - phosphamidon* C10H19ClNO5P C NR NR 6-15-50 1-2-3 0.76 NI1 1.05 0.58 aldrin C12H8Cl6 C C C 6 1 0.76 FP1/NI1 0.81 0.86 ronnel C8H8Cl3O3PS C C C 6 2 0.78 NP133 0.6 1.4 ethiofencarb C10H15NO2S C NR NR 6-15-50 - 0.78 NI4 0.66 2.82 propanil C9H9Cl2NO C NR NR 6-15 3 0.79 HN(WB)1/HX(WB)2/ 0.69 2.01 vinclozolin metabolite S C10H7Cl2NO3 V P V # 15 2 NI(WB)1/NP(WB)7 0.79 FP(WB)1.5 0.72 0.86 chlorpyrifos-methyl C7H7Cl3NO3PS C C - 6 2 0.79 0.75 1.55 prothoate C9H20NO3PS2 C ---- 0.8 HN(WB)0.2/NP(WB)13 0.7 - IN-B2838 C10H15N3O3 P NR NR 6-15-50 1-2-3 0.81 FS1.5 0.41 2.71 dimethipin C6H10O4S2 C NR NR 6-15-50 1-2-3 0.82 NI200/NP35 0.56 2.29 methidathion sulfone C5H8N2O3S2 - NR NR 6-15-50 1-2-3 0.82 - - butylisodecyl phthalate C22H34O4 - ---- 0.82 NP7 0.44 - isocarbamid C8H15N3O2 C ---- 0.83 FP10 0.72 - fenitrothion oxygen analog C9H12NO6P C ---- 0.84 0.88 0.92 dibutyl phthalate C16H22O4 - C C 15+50 - 0.86 - - 2,4,5-T butyl esters* C12H13Cl3O3 - ---- 0.86 HX3 0.96 1.45 nitrofluorfen C13H7ClF3NO3 C C C 15 2 0.86 FP4/NI15 0.8 - parathion oxygen analog C10H14NO6P C NR NR 6-15-50 1-2-3 0.87 NI3 0.94 0.69 pentachlorophenyl methyl sulfide C7H3Cl5S C C C 6 1 0.87 FP5 0.68 1.55 malathion oxygen analog C10H19O7PS C NR NR 6-15-50 1-2-3 0.87 FP2/FP(WB)1/NI3 0.71 1.64 parathion-methyl C8H10NO5PS C C C 15 2 0.88 NI1 0.98 0.89 chlordene, gamma- C10H6Cl6 - ---- 0.88 HN(WB)48/HX(WB)390/ 1.05 1.47 acifluorfen C14H7ClF3NO3 - NR NR 6-15-50 1-2-3 NI(WB)27/NP(WB)1000 0.89 NI1 0.98 0.84 chlordene, beta- C10H6Cl6 - ---- 0.89 NP(WB)2 0.73 - cymiazole C12H14N2S - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–105 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 0.89 NP(WB)10 - - isoproturon C12H18N2O S ---- 0.9 HN(WB)3/HX(WB)23/ 0.42 - pyrazon metabolite B C6H4ClN3O - NR NR 6-15-50 1-2-3 NI(WB)23/NP(WB)44 0.9 NI100/NP300 0.6 2.65 CGA 120844 C8H9NSO3 - NR NR 6-15-50 1-2-3 0.9 NI1000/NP50 0.81 - metalaxyl C15H21NO4 C NR NR 6-15-50 1-2-3 0.9 HN(WB)15/NI(WB)80/ 0.55 1.41 3-ketocarbofuran C12H12NO4 S NR NR 6 1 NP(WB)30 0.91 HX2 4.1 1.08 dicofol, o,p'-* C14H9Cl5O C V S 6+15 2 0.91 NI0.4/NP11 0.57 1.47 metribuzin C8H14N4OS V NR NR 50 1-2-3 0.91 FP(WB)10 - - formothion C6H12NO4PS2 C NR NR 6-15-50 1-2-3 0.92 FP2/FP(WB)1.2 0.87 - pirimiphos-methyl C11H20N3O3PS C C C 15 3 0.92 NI2 0.82 1.07 dichlorobenzophenone, o,p'- C13H8Cl2O - C C 15 2 0.93 HN(WB)3/HX(WB)3/ 0.89 3.02 vinclozolin metabolite E C11H11Cl2NO2 C S NR 15+50 - NI(WB)4/NP(WB)7 0.93 FS54/NI4.5 0.68 2.89 2,3-dihydro-3,3-methyl-2-oxo-5- C11H12O5S - ---- benzofuranyl methyl sulfonate 0.93 HX7 1.03 1.21 metolachlor C15H22ClNO2 C S # NR 50 1-2-3 0.93 NI6/NP15 1.15 1.22 butralin C14H21N3O4 V C - 6+15+50 - 0.95 HN(WB)30 0.55 3.6 ethametsulfuron methyl ester* C15H18N6O6S - NR NR 6-15-50 1-2-3 0.95 NP5.5 0.71 - fuberidazole C11H8N2O C ---- 0.95 0.85 2.13 linuron C9H10Cl2N2O2 V V # V 50 3 0.96 FP3 0.71 2.95 demeton-O sulfone* C8H19O5PS2 C ---- 0.96 NI1/NP5 0.99 1.91 KWG 1323 C14H16ClN3O3 C NR NR 6-15-50 1-2-3 0.96 NP16 0.97 - difenoxuron C16H18N2O3 - ---- 0.97 1.13 - trichloronat C10H12Cl3O2PS C C - 6 - 0.98 HX3 0.94 1 thiobencarb C12H16ClNOS C V 15 2+3 0.99 NI1/NP9 0.77 1.62 Tycor C9H16N4OS C S S 50 3 1 HX5/HX5/HX(WB)3/ 1.05 1.64 triadimefon C14H16ClN3O2 C S # S # 50 1-2-3 NI(WB)2/NP2/NP(WB)3 1 FP2/NI2 1 1 chlorpyrifos C9H11Cl3NO3PS C C P 6 2 1 NI1 1.06 1.13 DCPA C10H6Cl4O4 C C C 15 2 1.01 NI3/NP15 1.14 1.24 isopropalin C15H23N3O4 C C - 6 - 1.01 0.9 1.71 dichlofluanid C9H11Cl2FN2O2S2 C C # - 15+50 2+3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–106 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 1.02 FS65/NI333 0.86 1.93 ethofumesate C13H18O5S C ---- 1.02 FP6 0.66 - phorate oxygen analog sulfone C7H17O5PS2 C NR NR 6-15-50 1-2-3 1.03 NP600 0.8 - 3-hydroxymethyl-2,5-dimethylphenyl C11H15NO3 - NR NR 6-15-50 1-2-3 methylcarbamate 1.04 NI4 0.55 0.86 tetraiodoethylene C2I4 - P P 6 - 1.05 - - 2,4,5-T butyl esters* C12H13Cl3O3 - ---- 1.05 0.87 - demeton-O sulfoxide C8H15O4PS2 C ---- 1.05 NI0.6 1.33 0.94 octachlor epoxide C10H4Cl8O C C C 6 1 1.05 NP(WB)8 - - norea C13H15N2O C ---- 1.05 FP3/FP(WB)1.1 0.84 1.82 fenitrothion C9H12NO5PS C C C 15 2 1.05 FP3/NI7 0.91 1.49 malathion C10H19O6PS2 C C C 15+50 3 1.05 0.75 - carbaryl C12H11NO2 C ---- 1.06 FP40 0.78 - phorate oxygen analog sulfoxide C7H17O4PS2 C NR NR 6-15-50 1-2-3 1.06 NI10/NP125 0.83 3.77 metribuzin, deaminated metabolite C8H13N3OS C NR NR 6-15-50 1-2-3 1.07 0.87 - 4-chlorophenoxyaniline* C12H10ClNO S ---- 1.07 NI1 0.99 1.63 1-hydroxychlordene C10H6Cl6O - R - 15 - 1.07 FP2/NI4 0.98 1.91 parathion C10H14NO5PS C C C 15 2 1.07 NI(WB)40 0.54 - 4-chlorophenylurea C7H7ClN2O NR NR NR 6-15-50 1-2-3 1.08 HX3 4.4 1.28 dicofol, p,p'-* C14H9Cl5O C V P # 6+15 1+2 1.08 0.95 1.51 chlorpyrifos oxygen analog C9H11Cl3NO4P C NR - 6-15-50 - 1.08 NI2 0.99 1.25 dichlorobenzophenone, p,p'- C13H8Cl2O - C C 15 2 1.09 NI1/NP6 1.25 8 MB45950 C12H4SN4F6Cl2 S P V 15+50 2+3 1.12 NI2 1.37 1.22 S-bioallethrin C19H26O3 - C - 50 - 1.12 FP9 0.78 - fenthion oxygen analog C10H15O4PS C NR NR 6-15-50 1-2-3 1.13 NI(WB)600 1.04 - PPG-947 C17H11ClF3NO7 - NR NR 6-15-50 1-2-3 1.14 FP(WB)2.4 1.01 - pirimiphos-ethyl oxygen analog C13H24N3O4P C ---- 1.14 FP3/NI4 1.14 1.03 pirimiphos-ethyl C13H24N3O3PS C C C 15+50 3 1.15 HX0.9/NI2 1.29 1.22 heptachlor epoxide C10H5Cl7O C C C 6 2 1.16 NI1/NP5 1.35 8.7 fipronil C12H4Cl2F6N4OS S S V 50 3 1.16 FP3/NI2 1.11 1.29 bromophos C8H8BrCl2O3PS C C C 6 - 1.17 0.8 - methiocarb sulfone C11H15NO4S S NR NR 6-15-50 1-2-3 1.18 NP1000 3 - NTN33823 C9H11N4Cl - NR NR 6-15-50 1-2-3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–107 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 1.18 FP3 0.96 1.46 fenthion C10H15O3PS2 C S # NR 6+15 1-2-3 1.19 HX13/HX(WB)2/NI(WB)3/ 1.44 2.23 triflumizole C15H15ClF3N3O C ---- NP(WB)3 1.2 NI2 1.19 1.15 TDE, o,p'-, olefin C14H9Cl3 - ---- 1.21 NI1.5/NP6 1.22 1.48 pendimethalin C13H19N3O4 C C P 15 2 1.24 FP7 1.17 1.74 isofenphos oxygen analog C15H24NO5P C ---- 1.26 FP6 0.89 2.55 phorate sulfoxide C7H17O3PS3 C NR NR 6-15-50 1-2-3 1.28 FP2/NI60 0.92 2.9 terbufos oxygen analog sulfone C9H21O5PS2 C NR NR 6-15-50 1-2-3 1.29 FP(WB)2/NI3 1.21 1.58 chlorfenvinphos, alpha- C12H14Cl3O4P C - NR 6-15-50 - 1.3 FP2 0.97 3.26 phorate sulfone C7H17O4PS3 C S # S # 6-15-50 3 1.3 FP2/NI3 1.08 2.33 crufomate C12H19ClNO3P C NR NR 6-15-50 - 1.31 1.28 - 4-chlorophenoxyaniline* C12H10ClNO S ---- 1.32 HX3/HX(WB)2/NI(WB)2/ 1.24 - penconazole C13H15Cl2N3 C ---- NP(WB)3 1.32 0.96 - carbetamide C12H16N2O3 - ---- 1.32 HN(WB)1/NP(WB)50 1.4 - dinobuton C14H18N2O7 C ---- 1.33 NI40/NP200 1.11 4.7 isoxaflutole (prop) C15H12SNO4F3 NR V # S # 50 3 1.34 NI0.6 1.49 1.46 chlordane, trans- C10H6Cl8 C C C 6 1 1.36 NP250 0.21 - 3-(3,4-dichlorophenyl)-1-methoxyurea C8H8Cl2N2O2 R NR NR 6-15-50 1.36 HN(WB)1/HX(WB)8/ 0.8 4.8 bromacil C9H13BrN2O2 C NR NR 6-15-50 1-2-3 NI(WB)6/NP(WB)5 1.38 NI40/NP250 1.13 4.7 RPA202248 C15H12SNO4F3 NR NR NR 6-15-50 1-2-3 1.38 FP2 1.36 1.73 isofenphos C15H24NO4PS C C - 15+50 - 1.39 NP(WB)10 1.18 - cyprodinil C14H15N3 C NR NR 6-15-50 1-2-3 1.4 HX(WB)6/NI4.5 1.55 - haloxyfop methyl ester C16H13ClF3NO4 - ---- 1.41 1.25 - tolylfluanid C10H13ClFNOS C ---- 1.42 HX0.4/NI0.8 1.75 1.45 nonachlor, trans- C10H5Cl9 C C C 6 1 1.42 1.27 3.39 chlorbromuron C9H10BrClN2O2 V V V 50 3 1.43 FP25 1.34 0.65 merphos* C12H27PS3 - C C 6+15+50 3 1.43 FP(WB)12 0.93 - des N-isopropyl isofenphos oxygen C12H18NO5P - ---- analog 1.43 NP6 1.05 - pyracarbolid C13H15NO2 - ---- 1.44 NI5 - 1.67 2,4-D butoxyethyl ester* C14H18Cl2O4 - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–108 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 1.44 HX7/HX(WB)4/NI(WB)50/ 1.36 - triadimenol C14H18ClN3O2 C NR NR 6-15-50 - NP(WB)6 1.45 FP(WB)0.3 1.51 1.42 bromophos-ethyl C10H12BrCl2O3PS C C P 6 - 1.45 NI4 1.45 1.36 TDE, p,p'-, olefin C14H9Cl3 C C C 6 1 1.46 FS88/NI96 1 6.6 2-hydroxy-2,3-dihydro-3,3-methyl-5- C11H14O5S - ---- benzofuranyl methyl sulfonate 1.46 HX5/NP4 1.5 - metazachlor C14H16ClN3O C ---- 1.46 HX9 1.73 1.83 butachlor C17H26ClNO2 C C - 50 - 1.47 HX1/NI2 1.64 1.38 endosulfan I C9H6Cl6O3S C C C 15 2 1.47 NP20 1.24 1.88 anilazine C9H5Cl3N4 V S P 15+50 2+3 1.48 NI5 - - 2,4-D isooctyl ester* C16H22Cl2O3 - ---- 1.48 HX6 0.89 4.9 cyanazine C9H13ClN6 C NR - 6-15-50 - 1.48 FP(WB)3 0.72 - oxydemeton-methyl sulfone C6H15O5PS2 C ---- 1.48 NI0.8 1.66 1.54 chlordane, cis- C10H6Cl8 C C C 6 1 1.49 HX1 1.37 3.04 procymidone C13H11Cl2NO2 C C P 15 - 1.5 FP3 1.21 2.73 des N-isopropyl isofenphos C12H18NO4PS C S - 50 - 1.51 NI1 1.55 1.28 DDE, o,p'- C14H8Cl4 C C C 6 1 1.52 FP4/FP(WB)2/NI3 1.29 2 chlorfenvinphos, beta- C12H14Cl3O4P C S # - 50 1-2-3 1.54 NI1000 1.39 1.89 CGA 189138 C13H8O3Cl2 - ---- 1.54 1.15 4.3 CGA 91305 C10H8Cl2N3O V NR NR 6-15-50 1-2-3 1.54 HX3/NI1 1.39 1.62 chlorbenside C13H10Cl2S C S P 6 1 1.55 HN(WB)3/HX(WB)17/ 0.86 - 6-chloro-2,3-dihydro-7-hydroxy= C9H13ClN2O3 - NR NR 6-15-50 1-2-3 NI(WB)19/NP(WB)12 methyl-3,3-methyl-5H-oxazolo= (3,2-a)pyrimidin-5-one 1.55 NP(WB)25 1.1 - diphenamid C16H17NO V NR - 6-15 - 1.56 NP4 1.16 - phenothiazine C12H9NS - ---- 1.58 FP2/NI10 1.2 - terbufos sulfone C9H21O4PS3 C C # C # 6-15-50 2+3 1.58 FP3/FP(WB)1.9 1.28 2.67 mecarbam C10H20NO5PS2 C - 50 - 1.59 NI1000 6.7 - CGA 205375 C16H13N3O2Cl2 - ---- 1.59 HX7/HX(WB)3/NI(WB)85/ 1.52 - paclobutrazol C15H20ClN3O C ---- NP(WB)5 1.6 NI1000 1.28 - 3-phenoxybenzenemethanol C13H12O2 - ---- 1.64 NI6/NP30 1.57 1.84 cyclanilide methyl ester C12H11Cl2NO3 - ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–109 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 1.64 FP3/FP(WB)3 1.32 2 quinalphos C12H15N2O3PS C C - 15 - 1.65 1.65 - DDMS C14H11Cl3 - R - 6 - 1.66 FP10/NI120/NP7 1.08 3 fosthiazate C9H18NO3PS2 C NR NR 6-15-50 1-2-3 1.68 2.1 1.78 2,4-D ethyl hexyl ester* C16H22Cl2O3 - ---- 1.75 FP5 1.15 5.8 demeton-S sulfone C8H19O5PS2 C ---- 1.76 2.12 1.76 pyrethrins* C21H27O4 - C C 50 - 1.78 NI5 2.04 1.78 2,4-D isooctyl ester* C16H22Cl2O3 - ---- 1.79 NI5 1.82 2.08 2,4-D butoxyethyl ester* C14H18Cl2O4 - ---- 1.79 NP(WB)23 1.86 2.91 hexaconazole C14H17Cl2N3O C ---- 1.8 FP125/NI200/NP40 1.07 - methidathion oxygen analog C6H11N2O5PS2 - NR NR 6-15-50 1-2-3 1.82 NI3 1.85 1.74 prothiofos C11H15Cl2PO2S2 C C C 6 2 1.83 FP2/FP(WB)2.6/NI5 1.31 2.05 phenthoate C12H17O4PS2 C C - 15+50 - 1.84 HX1.5/NI1 1.91 1.87 dieldrin C12H8Cl6O C C C 15 2 1.85 1.57 - oxythioquinox C10H6N2OS2 C ---- 1.85 NI2 1.2 3.49 captan C9H8Cl3NO2S C P C 50 3 1.86 HN(WB)120/HX(WB)66/ 1.9 3.16 PPG-2597 C20H17ClF3NO6 - NR NR 6-15-50 1-2-3 NI(WB)78 1.86 NI1 1.92 1.59 DDE, p,p'- C14H8Cl4 C C C 6 1 1.88 FP25 1.95 1.64 merphos* C12H27PS3 - C C 6+15+50 3 1.88 1.73 - chlorflurecol methyl ester C15H11ClO3 C ---- 1.88 FP3/NI3 1.95 1.65 tribufos C12H27OPS3 C C P 15+50 3 1.9 FP10/FP(WB)3 1.37 2.85 crotoxyphos C14H19O6P C NR NR 6-15-50 1-2-3 1.92 1.26 3.5 Sulphenone C12H9ClO2S C - 50 3 1.94 NI9 1.23 3.01 folpet C9H4Cl3O2NS C C P 15+50 2+3 1.96 NI2 1.97 2.48 oxadiazon C15H18Cl2N2O3 C C P 15 - 1.97 FP10/FP(WB)3 1.58 2.72 Gardona C10H9Cl4O4P C NR NR 6-15-50 1-2-3 1.98 NI2/NP10 2.06 31 MB46136 C12H4SO2N4F6Cl2 S S V 50 2+3 1.99 HX10 1.88 - pretilachlor C17H26ClNO2 C ---- 2 NI11/NP200 1.78 3.14 diethatyl-ethyl C16H22ClNO3 C NR NR 6-15-50 1-2-3 2.03 HN(WB)1.3/HX7/HX4/ 2.02 3.4 diclobutrazol C15H19Cl2N3O C NR NR 6-15-50 1-2-3 HX(WB)2/NI(WB)4/NP(WB)8 2.04 1.48 - thiabendazole C10H7N3S C NR - 6-15-50 - Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–110 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 2.08 HX19/HX(WB)2/NI(WB)5/ 1.76 4 imazalil C14H14Cl2N2O C NR NR 6-15-50 - NP(WB)10 2.1 1.58 2.46 triazamate C13H22N4O3S C NR NR 6-15-50 1-2-3 2.11 FP7 - - jodfenphos C8H8Cl2IO3PS C ---- 2.11 NP200 - - sulfanilamide C6H8O2N2S NR NR NR 6-15-50 1-2-3 2.12 1.7 - napropamide C17H20NO2 C ---- 2.13 FP5/FP(WB)2.9 1.8 2.34 profenofos C11H15BrClO3PS C P P 50 3 2.16 HX9/NI2/NP350 2 4 oxyfluorfen C15H11ClF3NO4 C C C 15 2 2.19 NI2 1.9 2.46 TDE, o,p'- C14H10Cl4 - C C 6 1 2.2 HX5 1.61 3.04 ovex C12H8Cl2O3S C C C 15 2 2.28 FP(WB)2.4/NI10 1.4 3.33 methidathion C6H11N2O4PS3 C S P # 50 3 2.29 NI2 2.13 2.22 endrin C12H8Cl6O C C # C # 15 2 2.31 HX40 2.3 2.36 fluazifop butyl ester C19H20F3NO4 C C V 15 3 2.33 HX24/HX(WB)5/NP(WB)6 1.97 - flusilazole C16H15F2N3Si C ---- 2.34 NI2/NP50 2.21 - chlorfenapyr (prop) C15H11BrClF3N2O P - S 50 2 2.38 NI22/NP(WB)100 2.19 4.2 binapacryl C15H18N2O6 C P P 15 - 2.38 HX2/NI5 2.75 1.67 chlordecone C10H8Cl10O5 - S # P # 15+50 1-2-3 2.39 FP7 1.5 6.7 disulfoton sulfone C8H19O4PS3 C NR - 6-15-50 - 2.4 HN(WB)5 2.14 5 PPG-947, methylated* C18H13ClF3NO7 - ---- 2.4 HN(WB)4/HX(WB)6.5/ 2.15 5 PPG-847, methylated C15H9ClF3NO3 - ---- NI(WB)3/NP(WB)210 2.41 NI5/NP38 1.53 6.5 CGA 94689A C15H21NO5 V NR NR 6-15-50 1-2-3 2.41 FS(WB)90/NI(WB)80/ 1.28 - hexythiazox C17H21ClN2O2S - S # NR 50 2+3 NP(WB)80 2.41 FP10/NP3 1.66 3.7 fenamiphos C13H22NO3PS C NR NR 6-15-50 1-2-3 2.41 NI15 2.33 2.9 chloropropylate C17H16Cl2O3 P C C 15+50 3 2.42 NI25 2.23 2.01 Perthane C18H2OCl2 C C C 6 1 2.44 HX60 - - imazamethabenz methyl ester* C16H20N2O3 C ---- 2.45 NI10/NP75 1.54 6.6 CGA 94689B C15H21NO5 S NR NR 6-15-50 1-2-3 2.45 1.94 - flamprop-methyl C17H15ClFNO3 C ---- 2.51 FP3 - - mephosfolan C8H16NO3PS2 C ---- 2.55 HN(WB)13/HX(WB)99/ 1.35 2.27 3-tert-butyl-5-chloro-6-hydroxy= C9H13ClN2O3 - NR NR 6-15-50 1-2-3 NI(WB)35/NP(WB)290 methyluracil Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–111 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 2.55 HN(WB)1.2/NP(WB)53 1.41 - IN-T3936 C10H15N3O4 S NR NR 6-15-50 1-2-3 2.58 FP5 2.24 - chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 2.6 HX10/HX(WB)4/NI(WB)21/ 1.9 7.2 myclobutanil C15H17ClN4 C NR NR 6-15-50 1-2-3 NP75/NP(WB)6 2.6 NP(WB)300 2 3.7 bupirimate C13H24N4SO3 C ---- 2.61 NI2 2.52 3.33 nonachlor, cis- C10H5Cl9 C C C 6 1 2.61 NI15 2.31 3.26 - chlorobenzilate C16H14Cl2O3 C C # P # 15+50 3 2.62 3.38 - 2,4,5-T ethylhexyl ester C16H21Cl3O3 - ---- 2.67 NP36 1.5 4.3 TCMTB C9H6N2S3 C P P 15 - 2.69 2.04 1.61 cyproconazole C15H18ClN3O C NR NR 6-15-50 1-2-3 2.69 FP5 - - phosfolan C7H14NO3PS2 C ---- 2.7 2.95 2.84 pyrethrins* C21H27O4 - C C 50 - 2.7 NI2 2.55 2.27 DDT, o,p'- C14H9Cl5 C C C 6 1 2.71 NI3 2.03 3.8 nitrofen C12H7Cl2NO3 C C C 15 2 2.76 HX60 1.79 3.5 imazamethabenz methyl ester* C16H20N2O3 C ---- 2.77 FP5 2.36 - chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 2.77 HX3/NI2 2.21 3.9 endosulfan II C9H6Cl6O3S C C C 15+50 2 2.8 NI5 2.64 2.33 tetrasul C12H6Cl4S C C C 6 1 2.81 2.46 - flamprop-M-isopropyl C19H19ClFNO3 C ---- 2.87 FP15 4.2 - carbophenothion oxygen analog C11H16ClO4PS2 - ---- sulfoxide 2.87 NI2 2.41 3.8 TDE, p,p'- C14H10Cl4 C C C 6 1 2.88 3.03 2.74 ethephon C2H6ClO3P NR - 6+15+50 1+2+3 2.92 NP(WB)8 2.07 - methoprotryne C11H21N5OS C ---- 2.96 NI1000/NP150 1.8 - CGA 100255 C15H12NO5 S ---- 2.99 FP10/HX11 2.22 4.1 chlorthiophos oxygen analog C11H15Cl2O4PS C NR NR 6-15-50 1-2-3 3 NI120/NP70 2.4 4.3 imazethapyr ammonium salt C16H21N3O3 - ---- methyl ester 3.06 FP15 2.17 4.2 carbophenothion oxygen analog C11H16ClO3PS2 C NR NR 6-15-50 1-2-3 3.14 NI5 2.38 3.24 leptophos photoproduct C13H11Cl2O2PS C ---- 3.16 FP5 2.56 - chlorthiophos* C11H15Cl2O3PS2 C C C 6 2 3.17 HX7 2.43 - etaconazole* C14H15Cl2N3O2 C ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–112 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 3.17 1.6 4.1 isoprothiolane C12H18O4S2 C ---- 3.36 FP4/FP(WB)2.3/NI8 2.56 3.93 ethion C9H22O4P2S4 C C C 6 2 3.38 NI(WB)15/NP(WB)40 2 3.02 kresoxim-methyl C18H19NO4 P C C 15+50 3 3.5 NI150 - - dinocap* C18H24N2O6 C P P 15 2 3.5 FP3 2.79 - sulprofos C12H19O2PS3 C ---- 3.5 NI2 3.13 3.6 DDT, p,p'- C14H9Cl5 C C C 6 1 3.6 FP(WB)29 2.78 - sulprofos sulfoxide* C12H19O3PS3 C ---- 3.6 FP100 2.8 - fensulfothion sulfone C11H17O5PS2 C NR - 6-15-50 - 3.7 2.9 - 1,1'-(2,2-dichloroethylidene)bis(2- C16H16Cl2O2 - R - - - methoxybenzene) 3.7 FP8 2.94 4.2 carbophenothion C11H16ClO2PS3 C C P 6 2 3.7 NI(WB)5 3.1 - fenhexamid C14H17Cl2NO2 NR NR NR 6-15-50 1-2-3 3.8 FP6 1.99 - fensulfothion oxygen analog sulfone C11H17O7PS2 - ---- 3.8 FP6/FP(WB)7 2.4 - fensulfothion C11H17O4PS2 C NR NR 6-15-50 1-2-3 3.9 NI150 4 - dinocap* C18H24N2O6 C P P 15 2 3.9 NP500/NP(WB)8 1.59 - tricyclazole C9H7N3S C ---- 3.9 NI6 2.81 7.5 Prolan C15H13Cl2NO2 P S S 15 2 3.93 2.31 15 desisopropyl iprodione C10H6Cl2N3O3 P - 50 1-2-3 4 HX9 3.21 5.6 propiconazole* C15H17Cl2N3O2 C NR NR 6-15-50 1-2-3 4 FP20 5.4 - carbophenothion sulfoxide C11H16ClO3PS3 - ---- 4 HX6/NI6 2.83 8.3 endosulfan sulfate C9H6Cl6O4S C C C 50 2 4.1 FP(WB)8 2.29 - fenthion oxygen analog sulfone* C10H15O6PS2 - ---- 4.1 NI20/NP100 2.96 11.5 CL 202,347 C13H19N3O5 - ---- 4.2 HN(WB)2/HX(WB)13/ 2.51 4 pyrithiobac-sodium methyl ester C14H13ClN2O4 - ---- NI(WB)18/NP(WB)85 4.2 HX(WB)3 3.38 - tebuconazole C16H22ClN3O C ---- 4.2 NI200/NP50 4 15 KWG 1342 C14H18ClN3O3 - ---- 4.2 NI10 2.97 3.7 methoxychlor olefin C16H14Cl2O2 C C C 6 2 4.3 NI2600 3.8 4.8 propargite C19H26O4S C C - 15 2 4.4 NI150 4.3 6.9 dinocap* C18H24N2O6 C P P 15 2 4.4 FP(WB)12 2.26 - famphur oxygen analog C10H16NO6PS C ---- 4.4 NI5 3.06 7.5 Bulan C16H15Cl2NO2 C P P 15 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–113 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 4.5 NI100 6.1 1.48 tralkoxydim* C20H27NO3 V NR NR 50 1-2-3 4.5 HX5/HX(WB)20 4.9 3.8 bifenthrin C23H22ClF3O2 V C - 6+15 2 4.5 2.43 - benodanil C13H10INO C ---- 4.5 3.06 5.1 butyl benzyl phthalate C19H20O4 - C P 15+50 - 4.6 HN(WB)100/HX(WB)14/ 2.87 - vinclozolin metabolite F C11H13Cl2NO4 R NR NR 6-15-50 1-2-3 NI(WB)85/NP(WB)210 4.6 3.1 8.2 cyanofenphos C15H14NO2PS C ---- 4.67 NI(WB)20 3.26 5.8 clodinafop-propargyl C17H13ClFNO4 V V - 50 3 4.7 HX10 3.57 4.9 diclofop-methyl C16H14Cl2O4 C C C 15 2 4.7 FP20 2.39 - fenthion sulfone C10H15O5PS2 C NR NR 6-15-50 1-2-3 4.8 NI150 4.8 7.7 dinocap* C18H24N2O6 C P P 15 2 4.8 HX4 3.36 7.3 nuarimol C17H12ClFN2O C NR C # 50 1-2-3 4.9 HX(WB)3 3.38 1.41 desmethyl norflurazon C11H7ClF3N3O V NR NR 6-15-50 1-2-3 5 NP14 2.5 14 oxadixyl C14H18N2O4 C NR NR 6-15-50 1-2-3 5 NI9 3.3 4.5 methoxychlor, o, p'- C16H15Cl3O2 - C - 6 - 5 FP5 2.49 - fensulfothion oxygen analog C11H17O5PS C NR - 6-15-50 - 5 FP50/FP(WB)7 2.65 14 famphur C10H16NO5PS2 C NR - 6-15-50 - 5.01 NP(WB)10 4.5 - norflurazon C12H9ClF3N3O V NR NR 6-15-50 - 5.2 HX20/NI35/NP200 - - iprodione* C13H13Cl2N3O3 C S # NR 50 1-2-3 5.2 FP5/FP(WB)5 2.62 - triazophos C12H16N3O3PS C ---- 5.3 5.4 - carbosulfan C20H32N2O3S P ---- 5.3 FP(WB)8 2.87 6.3 edifenphos C14H15O2PS2 C ---- 5.4 HX51 2.62 18.6 ofurace C14H16NO3Cl C ---- 5.4 NI5 3.11 - captafol C10H9Cl4NO2S C P - 50 3 5.6 NI150 5.1 9.5 dinocap* C18H24N2O6 C P P 15 2 5.6 NI4 5.8 2.95 mirex C10Cl12 P C P 6 1 5.7 NI13 4.8 7 fenpropathrin C22H23NO3 - V # V 15 2 6 NI8 4.3 8.4 benzoylprop-ethyl C18H17Cl2NO3 P NR NR 6-15-50 1-2-3 6.1 NI200 12 8.9 CGA 205374 C16H11N3O2Cl2 - NR NR 6-15-50 1-2-3 6.1 6.4 4.5 bis(2-ethylhexyl) phthalate C24H38O4 - C C 15+50 - 6.2 17 - deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 6.2 FP(WB)12 3.8 - phosalone oxygen analog C12H15ClNO5PS C ---- Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–114 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 6.3 HX20/NI35/NP200 4.2 18 iprodione* C13H13Cl2N3O3 C S # NR 50 1-2-3 6.3 NI7 3.8 24 nitralin C13H19N3O6S C P P 50 3 6.3 NI(WB)20 4.8 6.6 cloquintocet-mexyl C18H22ClNO3 V NR - 6-15-50 1-2-3 6.5 5.4 4.8 - phenothrin* C23H26O3 - ---- 6.5 4.2 7.6 leptophos oxygen analog C13H10BrCl2O3P C ---- 6.8 4.8 9.7 piperophos C14H28NO3PS2 C ---- 6.9 FP25/HX17 4.7 10.3 chlorthiophos sulfoxide C11H15Cl2O4PS2 C NR NR 6-15-50 1-2-3 6.9 FP50/NI9 4.5 10.6 EPN C14H14NO4PS C C C 15 2 7.1 FP150 3.1 14.8 phosmet oxygen analog* C11H12NO5PS - NR NR 6-15-50 - 7.1 FP(WB)24 3.8 - carbophenothion oxygen analog C11H16ClO5PS2 - ---- sulfone 7.2 4.5 8.5 tetramethrin* C19H25NO4 C NR NR 6-15-50 1-2-3 7.2 NI8 4.7 8.6 tetrasul sulfoxide C12H6Cl4OS - ---- 7.2 NI7 4.7 7.2 methoxychlor, p, p'- C16H15Cl3O2 C C C 6 2 7.3 NP50 5 - fenoxycarb C17H19NO4 C ---- 7.5 FS(WB)1500/NI(WB)0.1/ 3.3 - 3-desmethyl sulfentrazone C10H8Cl2F2N4O3S - NR NR 6-15-50 1-2-3 NP(WB)73 7.5 NP375 3.6 37.1 myclobutanil alcohol metabolite C15H17ClN40 S NR NR 6-15-50 1-2-3 7.5 HX80 5.3 - iprodione metabolite isomer C13H13Cl2N3O3 C S - 50 - 8 HX30 7.4 - lambda-cyhalothrin C23H19ClF3NO3 C ---- 8 HX(WB)50 2.67 13 pyrazon C10H8ClN3O C NR NR 6-15-50 1-2-3 8.1 FP(WB)28/NP45 5.2 - fenamiphos sulfoxide C13H22N04PS C NR NR 6-15-50 1-2-3 8.3 NI5 5.2 - tetradifon C12H6Cl4O2S C C C 15 2 8.4 FP(WB)20/NP60 4.5 - fenamiphos sulfone C13H22NO5PS C NR NR 6-15-50 1-2-3 8.4 FP50/NI78 4 14.9 phosmet C11H12O4NPS2 C NR - 6-15-50 3 8.5 FP(WB)15/NI12 5.8 7.7 leptophos C13H10BrCl2O2PS C C C 6 2 8.5 NI5 4.4 15.5 photodieldrin C12H8Cl6O - C C 15+50 2 8.7 4.2 14 pyridaphenthion C14H17O4N2SP C ---- 8.8 5 14.9 bifenox C12H9Cl2NO5 C C P 15+50 2+3 8.9 NI25/NP100 10.4 12.8 acrinathrin C26H21F6NO5 V V V # 15 2 9.1 FP100/HX22 5.3 18.8 chlorthiophos sulfone C11H15Cl2O5PS2 C C - 50 3 9.1 NI12 5.5 5.5 phosalone C12H15ClNO4PS2 C C C 50 2+3 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999)Form FDA 2905a (6/92) Appendix I–115 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 Recoveries 9.2 FP30 5.1 - carbophenothion sulfone C11H16ClO4PS3 C C P 6 1 9.4 HN(WB)4 3.28 - oxycarboxin C12H13NO4S R ---- 9.8 NP165 5.9 - clofentezine C14H8Cl2N4 R S - 15 2 10.1 6.6 - fenarimol C17H12Cl2N2O C P # C # 50 3 10.1 FP(WB)42 3.7 - azinphos-methyl oxygen analog C10H12N3O4PS C ---- 10.5 8.1 11.3 fenoxaprop ethyl ester C18H16NO5Cl S V V 50 3 10.6 FP40/FP(WB)28/NI20/NP40 5.1 - sulprofos oxygen analog sulfone C12H19O5PS2 C ---- 11 7 - tebufenozide C22H28N2O2 - NR NR 6-15-50 1-2-3 11.3 NP(WB)120 4.7 53 dithianon C14H4O2N2S2 NR ---- 11.4 7 - CGA 118244 C15H13Cl2N3O3 V NR NR 6-15-50 1-2-3 11.5 NI1000/NP1000 6.5 - myclobutanil dihydroxy metabolite C15H17N4O2Cl NR NR NR 6-15-50 1-2-3 11.7 FP(WB)29 6.1 - sulprofos sulfoxide* C12H19O3PS3 C ---- 11.8 NP(WB)200 9.4 - bitertanol* C20H23N3O2 C ---- 11.8 5.2 - azinphos-methyl C10H12N3O3PS2 C NR NR 6-15-50 1-2-3 12.5 NP(WB)200 9.7 - bitertanol* C20H23N3O2 C ---- 12.6 NI70 7.9 10.8 HOE-030291 C17H16Cl2O5 - ---- 13 FP25 8.1 - pyrazophos C14H20N3O5PS C ---- 13.1 FP(WB)26 7.2 - sulprofos sulfone C12H19O4PS3 C ---- 13.8 9.4 11.1 permethrin, cis- C21H20Cl2O3 C V # C 6+15 2 14.3 FP25/FP(WB)31 6.5 - dialifor C14H17ClNO4PS2 C C P 15 2 14.8 FP(WB)26/NI20 6.9 - azinphos-ethyl C12H16N3O3PS2 C P S 50 3 15 11.5 10.9 phenothrin* C23H26O3 - ---- 15 10.2 13 permethrin, trans- C21H20Cl2O3 C V # C 6+15 2 15.4 10.4 - prochloraz C15H16Cl3N3O2 C ---- 16 FP75/NI50/NP40 8 45 coumaphos oxygen analog C14H16ClO6P C NR NR 6-15-50 1-2-3 16 NI400 13 13 hexachlorophene C13H6Cl6O2 - NR NR 6-15-50 - 18 FP50/FP(WB)26/NI38/NP34 9 40 coumaphos C14H16ClO5PS C NR C # 6-15-50 3 20 29 - deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 20.2 FP100 9.5 - bensulide C14H24NO4PS3 C P C 50 3 21 17.1 - deltamethrin* C22H19Br2NO3 C S # P 15 2 21.4 14.7 36.9 flucythrinate* C26H23F2NO4 C C - 15 2+3 23 14.1 33 cypermethrin* C22H19Cl2NO3 C C C 15 2 Pesticide Analytical Manual Vol. I APPENDIX I Transmittal No. 2000-1 (10/1999) Form FDA 2905a (6/92) Appendix I–116 Appendix I: PESTDATA Chemicals in Order by OV-17 Relative Retention Time (continued) Recoveries RRT/c Detector Responses RRT/c RRT/c Molecular OV-17 with OV-17 Column OV-101 OV-225 Name Formula 302 303 304 Ethers CH 2 Cl 2 24 16.1 42 flucythrinate* C26H23F2NO4 C C - 15 2+3 25 15.1 36 cypermethrin* C22H19Cl2NO3 C C C 15 2 25 13.6 - quizalofop ethyl ester C19H17ClN2O4 C ---- 35 - 56 fluvalinate* C26H22ClF3N2O3 C C - 15 2 35 27 - deltamethrin* C22H19Br2NO3 C S # P 15 2 35 20.3 44 fenvalerate* C25H22ClNO3 C C C 15 2 38 25 59 fluvalinate* C26H22ClF3N2O3 C C - 15 2 38 31 19.7 deltamethrin, trans-* C22H19Br2NO3 - P # NR 15 2 38 29 19.9 deltamethrin* C22H19Br2NO3 C S # P 15 2 40 22.5 51 fenvalerate* C25H22ClNO3 C C C 15 2 43 NI200/NP500 23 57 PB-7, methylated C20H25ClN2O3S - ---- 44 27 64 tralomethrin C22H19Br4NO3 C V S 15 2 46 NI250/NP750 25 87 PB-9 C19H25ClN2O2S V NR NR 6-15-50 1-2-3