17 October 2011 1 芳烃课堂练习
17 October 2011 2
1,
2,
3,
4,
5,
完成下列反应式,

K M n O 4C 2 H 5H 3 C
+ ( C H 3 ) 3 C C l
C H 3
C H 3
A l C l 3
1 0 0 ℃
H 2 S O 4 △C l K M n O 4H 3 C
H N O 3
H 2 S O 4N O 2N H
H N O 3
C
O

K M n O 4( C H 3 ) 3 C
17 October 2011 3
6,
7,
8,
H 2 S O 4
H N O 3COO
17 October 2011 4
C O O HH O O C
C H 3
C H 3
C (C H 3)3
N O 2
C l
C H 3
N O 2
C O O H
C l
N O 2O 2 N N HC
O
( C H 3 ) 3 C C O O H N O 2O 2 N C
O
O
N O 2
C O O H
C 2 H 5 C O O H
1,
2,3,
4,
5,6,
7,
8,